A novel and concise method for the construction ofγ-nitro ketones and 1,3-dinitro compounds with chemo-selective acyl transfer has been presented under basic conditions via one-pot reactions.These reactions feature h...A novel and concise method for the construction ofγ-nitro ketones and 1,3-dinitro compounds with chemo-selective acyl transfer has been presented under basic conditions via one-pot reactions.These reactions feature high atom-and step-economic possess,mild condition and simple operation for one-pot synthesis of aliphatic nitro compounds.This protocol provides the products in good yields.The possible reaction mechanism has also been proposed.展开更多
基金supported financially by the National Natural Science Foundation of China(21172227).
文摘A novel and concise method for the construction ofγ-nitro ketones and 1,3-dinitro compounds with chemo-selective acyl transfer has been presented under basic conditions via one-pot reactions.These reactions feature high atom-and step-economic possess,mild condition and simple operation for one-pot synthesis of aliphatic nitro compounds.This protocol provides the products in good yields.The possible reaction mechanism has also been proposed.