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锂硫电池中的硫正极电催化认识
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作者 汪涛 董琴 +1 位作者 李存璞 魏子栋 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第2期45-57,共13页
以单质硫为正极的锂硫电池表现出极高的放电比容量(1672 mAh·g^(-1)),是极具潜力的下一代二次动力电池。然而,充放电过程中溶解的高阶多硫化锂(Li_(2)S_(n),4≤n≤8)的穿梭效应,以及硫物种缓慢的氧化还原动力学过程是锂硫电池商业... 以单质硫为正极的锂硫电池表现出极高的放电比容量(1672 mAh·g^(-1)),是极具潜力的下一代二次动力电池。然而,充放电过程中溶解的高阶多硫化锂(Li_(2)S_(n),4≤n≤8)的穿梭效应,以及硫物种缓慢的氧化还原动力学过程是锂硫电池商业应用前需要解决的关键问题。而电化学催化的引入是解决上述问题行之有效的策略。本文从电化学催化角度出发,重新讨论认识多硫化物的存在形式,并从吸附-催化、活性中间体两个方面,根据不同的反应机理、路径分析多硫化物转化机制,总结定量评价催化性能方法,以期为锂硫电池高效电催化剂的设计提供思路。 展开更多
关键词 锂硫电池 催化转化 电催化 化学吸附 硫自由基
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Seasoning Chinese cooking pans: The nanoscience behind the Kitchen God's blessing
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作者 Chenxi Gao Na Yang +4 位作者 cunpu li Xi Wang Xun Yu ling Zhang Zidong Wei 《Nano Materials Science》 EI CAS CSCD 2023年第1期86-90,共5页
The Chinese iron pan can function as a nonstick pan even without a polytetrafluoroethylene(PTFE)coating after a“Kitchen God blessing”seasoning process.We simulate this process and disclose the science behind the“Ki... The Chinese iron pan can function as a nonstick pan even without a polytetrafluoroethylene(PTFE)coating after a“Kitchen God blessing”seasoning process.We simulate this process and disclose the science behind the“Kitchen God blessing,”finding that through repeated oil-coating and heating,the reversible insertion and extraction of oxygen atoms split the surface of the iron pan,gradually producing Fe 3 O 4 nanoballs.These balls give the iron pan a conditional hydrophobicity property,meaning the pan would be hydrophilic when the ingredients contain much water and hydrophobic when they contain less water.The former enables heat to be transferred rapidly through the nanoballs while the latter slows down the heat transference and prevents the pan from sticking.This discovery provides an approach of generating nanoballs on the surface of the metal and also discloses the secret of the fantastic taste produced by cooking with a Chinese iron pan. 展开更多
关键词 Surface treatment Nanoball HYDROPHOBIC Nanoparticle synthesis
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