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表面施加含稀土氧化物薄膜对Fe25Cr高温氧化的“活性元素效应” 被引量:3
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作者 齐慧滨 d.g.lees 何业东 《腐蚀科学与防护技术》 CAS CSCD 1999年第4期193-201,共9页
研究了表面施加含有不同量Y2O3的Cr2O3和Al2O3薄膜对Cr2O3形成合金Fe25Cr在1000℃、104PaO2环境中高温氧化的作用.结果发现含Y氧化物薄膜明显降低了Cr2O3层的生长速度,而且含Y复合氧化物... 研究了表面施加含有不同量Y2O3的Cr2O3和Al2O3薄膜对Cr2O3形成合金Fe25Cr在1000℃、104PaO2环境中高温氧化的作用.结果发现含Y氧化物薄膜明显降低了Cr2O3层的生长速度,而且含Y复合氧化物薄膜的作用大于单一Y2O3薄膜.此时,Cr2O3层表面形貌发生了较大的变化.间接证据表明Cr2O3的生长机制由阳离子向外扩散为主转变为阴离子向内扩散为主.通过表面施加含Y的氧化物薄膜产生了全面的“活性元素效应” 展开更多
关键词 氧化物薄膜 Fe25Cr 高温氧化 活性元素效应
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Evidence for Vacancy Injection during the Oxidation of Iron
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作者 d.g.lees R.FRANCIS 《中国腐蚀与防护学报》 CAS CSCD 北大核心 2009年第4期293-295,共3页
Iron discs have been oxidised at 890℃on one side only,with the other side protected by an inert gas.The scale-metal adhesion was very good.Initially,scale-metal adhesion was maintained by the scale relaxing towards t... Iron discs have been oxidised at 890℃on one side only,with the other side protected by an inert gas.The scale-metal adhesion was very good.Initially,scale-metal adhesion was maintained by the scale relaxing towards the metal but after a time which depended upon the initial metal thickness,oxide relaxation ceased and the inert face moved towards the scale-metal interface.When the face which was normally inert was coveredwith a non-growing oxide layer,the scale-metal adhesion deteriorated.The results show that vacancies which were produced by oxidation were annihilated within the metal,that the inert face played a part and that the scale-metal interface is not a good sink for vacancies. 展开更多
关键词 金属 腐蚀 防护 铁材料
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