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钾掺杂对钒酸钠纳米片储钠性能的影响 被引量:2
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作者 宋学霞 李继成 +4 位作者 李朝晖 李喜飞 丁燕怀 肖启振 雷钢铁 《化学学报》 SCIE CAS CSCD 北大核心 2019年第7期625-633,共9页
通过水热-热处理方法首次制备了K+离子掺杂的钒酸钠(Na5V12O32)正极材料,对样品进行了TEM、XRD和XPS表征,详细研究了钾掺杂量对样品的结构和储钠性能的影响规律.TEM照片显示,合成的材料具有纳米片形貌.XRD/XPS谱图分析表明,K+离子掺杂... 通过水热-热处理方法首次制备了K+离子掺杂的钒酸钠(Na5V12O32)正极材料,对样品进行了TEM、XRD和XPS表征,详细研究了钾掺杂量对样品的结构和储钠性能的影响规律.TEM照片显示,合成的材料具有纳米片形貌.XRD/XPS谱图分析表明,K+离子掺杂在钒酸钠晶体的层间.恒流充放电测结果显示,当1 mol Na5V12O32掺杂0.118 mol K^+离子时,得到的Na5K0.118V12O32样品具有最佳的电化学性能:在1.5~4.0 V范围内,经过几次活化后,其于0.1C、0.2C、0.5C、1C、3C和10C倍率下的最大放电容量分别为169、160、148、132、98和69 mAh·g^-1;3C循环1000次后容量保持率为93.0%.研究结果表明,层间掺杂的K+离子不仅扩大了Na5V12O32晶体的层间距,而且稳定了晶体的结构,从而显著改善了Na5V12O32材料的倍率性能和循环性能.研究结果证明,适量K+离子掺杂的Na5K0.118V12O32纳米片有望发展为一种新型钠离子电池正极材料. 展开更多
关键词 钠离子电池 钒酸钠 阳离子掺杂 正极材料 电化学性能
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Mechanical properties of individual core-shell-structured Sn O2@C nanofibers investigated by atomic force microscopy and finite element method
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作者 LIU Xing LI KeFeng +7 位作者 DUAN XiaoLu HUANG YuTing LI Shuai LIU YiLin XU Fu LI Zheng ZHANG Ping ding yanhuai 《Science China(Technological Sciences)》 SCIE EI CAS CSCD 2018年第8期1144-1149,共6页
Although SnO_2-based nanomaterials used to be considered as being extraordinarily versatile for application to nanosensors,microelectronic devices, lithium-ion batteries, supercapacitors and other devices, the functio... Although SnO_2-based nanomaterials used to be considered as being extraordinarily versatile for application to nanosensors,microelectronic devices, lithium-ion batteries, supercapacitors and other devices, the functionalities of SnO_2-based nanomaterials are severely limited by their intrinsic vulnerabilities. Facile electrospinning was used to prepare SnO_2 nanofibers coated with a protective carbon layer. The mechanical properties of individual core-shell-structured SnO_2@C nanofibers were investigated by atomic force microscopy and the finite element method. The elastic moduli of the carbon-coated SnO_2 nanofibers remarkably increased, suggesting that coating SnO_2 nanofibers with carbon could be an effective method of improving their mechanical properties. 展开更多
关键词 SnO2 nanofiber core-shell structure elastic modulus atomic force microscopy finite element method
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