Neutron diffraction aund inelastic scatterilug were curried out on YBa_(2)Cu_(3)O_(7-y)(r=0.5,1.0、1.25).It was coufirmed that the substitutiou of Sr for Ba in YBa_(2)Cu_(3)O_(7-y) inrcases the oxyge1n vacancies int t...Neutron diffraction aund inelastic scatterilug were curried out on YBa_(2)Cu_(3)O_(7-y)(r=0.5,1.0、1.25).It was coufirmed that the substitutiou of Sr for Ba in YBa_(2)Cu_(3)O_(7-y) inrcases the oxyge1n vacancies int the CuO chain.Moreuver.the sntbstittiou strengtlenx the coupling betw1ell the Ba O plane aldl the Cu O rhain,Moreoer. the crystiul stnlbility.Tlusse the ppossill.rnuscs of Te depression for Sr xilrtittril YBa_(2)Cu_(3)O_(7-y).展开更多
Neutron diffraction study on the structure of Bi_(2)Sr_(1.855)Ca_(1.145)Cu_(2)O_(8) was carried out.Data refinements show that the average subcell structure for Bi_(2)Sr_(1.855)Ca_(1.145)Cu_(2)O_(8) is in the best fit...Neutron diffraction study on the structure of Bi_(2)Sr_(1.855)Ca_(1.145)Cu_(2)O_(8) was carried out.Data refinements show that the average subcell structure for Bi_(2)Sr_(1.855)Ca_(1.145)Cu_(2)O_(8) is in the best fit of the space group Fmmm and the structure is described by alternate stacking of SrO-CuO_(2)-Ca-CuO_(2)-SrO slab and a double BiO layers.An oxygen layer sandwiched by the bismuth layers was conRrmed.展开更多
基金Supported by the National Natural Science Foundation of China。
文摘Neutron diffraction aund inelastic scatterilug were curried out on YBa_(2)Cu_(3)O_(7-y)(r=0.5,1.0、1.25).It was coufirmed that the substitutiou of Sr for Ba in YBa_(2)Cu_(3)O_(7-y) inrcases the oxyge1n vacancies int the CuO chain.Moreuver.the sntbstittiou strengtlenx the coupling betw1ell the Ba O plane aldl the Cu O rhain,Moreoer. the crystiul stnlbility.Tlusse the ppossill.rnuscs of Te depression for Sr xilrtittril YBa_(2)Cu_(3)O_(7-y).
基金Supported by the National Natural Science Foundation of Chinathe National Center for Research and Development on Superconductivity.
文摘Neutron diffraction study on the structure of Bi_(2)Sr_(1.855)Ca_(1.145)Cu_(2)O_(8) was carried out.Data refinements show that the average subcell structure for Bi_(2)Sr_(1.855)Ca_(1.145)Cu_(2)O_(8) is in the best fit of the space group Fmmm and the structure is described by alternate stacking of SrO-CuO_(2)-Ca-CuO_(2)-SrO slab and a double BiO layers.An oxygen layer sandwiched by the bismuth layers was conRrmed.