A study on energy changes and mechanisms of Cd sorbed on goethite was performed using the technique ofmicrocalorimetry. The data of the amount of Cd sorption (Aq) and concentration of Cd in equilibrium solution(Ce), a...A study on energy changes and mechanisms of Cd sorbed on goethite was performed using the technique ofmicrocalorimetry. The data of the amount of Cd sorption (Aq) and concentration of Cd in equilibrium solution(Ce), and the data of Aq and the heat effect (AH) caused by Cd^2+ sorption on goethite all fitted Langmuirisotherm. The amount of heat released from Cd sorption on goethite increased with the amount of Ce or Aq.The reaction process of Cd sorption on goethite may be divided into five stages and three plateaus, dependingon the variation of enthalpy change (.Hm) of Cd sorption with Aq, which implied three mechanisms ofinteraCtion between Cd and goethite. The experimental results showed that the microcalorimetry may beuseful for determination of microcalorie variation in soil.展开更多
文摘A study on energy changes and mechanisms of Cd sorbed on goethite was performed using the technique ofmicrocalorimetry. The data of the amount of Cd sorption (Aq) and concentration of Cd in equilibrium solution(Ce), and the data of Aq and the heat effect (AH) caused by Cd^2+ sorption on goethite all fitted Langmuirisotherm. The amount of heat released from Cd sorption on goethite increased with the amount of Ce or Aq.The reaction process of Cd sorption on goethite may be divided into five stages and three plateaus, dependingon the variation of enthalpy change (.Hm) of Cd sorption with Aq, which implied three mechanisms ofinteraCtion between Cd and goethite. The experimental results showed that the microcalorimetry may beuseful for determination of microcalorie variation in soil.
