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金属有机框架(MOF)材料及其在新型缓控释肥料中的应用 被引量:1
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作者 杜昌文 周健民 《华中农业大学学报》 CAS CSCD 北大核心 2022年第2期20-29,共10页
缓控释肥料养分的释放因能更好地与作物需求相匹配而使得养分利用率高,是提升养分利用率的重要手段之一,而金属有机框架(metal organic frameworks,MOF)为新型缓控释肥料的研发提供了新的思路。MOF是一种基于分子设计的新型团簇功能多... 缓控释肥料养分的释放因能更好地与作物需求相匹配而使得养分利用率高,是提升养分利用率的重要手段之一,而金属有机框架(metal organic frameworks,MOF)为新型缓控释肥料的研发提供了新的思路。MOF是一种基于分子设计的新型团簇功能多孔化合物,具有比表面积大、孔隙率高、构型多样及结构可调控等优点,在化学、材料、医学、生物传感等领域得到广泛应用,现在也开始应用于农业。本文根据MOF的组成结构、功能特点和合成方法,探讨了MOF应用于新型缓控释肥料的特点和进展,进而阐述了MOF类新型缓控释肥料未来的发展方向,可根据作物对养分的需求从分子层面定向设计引入特定营养元素,为缓控释肥料的研制提供新的技术支撑。 展开更多
关键词 养分利用 缓控释肥料 金属有机框架(MOF) 环境影响 养分负载与释放
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应用^(15)N示踪技术研究控释尿素在稻田中的去向及利用率 被引量:25
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作者 李鹏飞 李小坤 +6 位作者 侯文峰 任涛 丛日环 杜昌文 邢烈火 王少华 鲁剑巍 《中国农业科学》 CAS CSCD 北大核心 2018年第20期3961-3971,共11页
【目的】在氮、磷、钾肥合理供应下,比较控释尿素和普通尿素中氮素在土壤-植物系统中的转化特点,挖掘控释尿素氮肥利用潜力和减少氮素损失的作用,定量研究控释尿素在稻田的去向和利用率,为高效施用控释肥料提供依据。【方法】通过田间... 【目的】在氮、磷、钾肥合理供应下,比较控释尿素和普通尿素中氮素在土壤-植物系统中的转化特点,挖掘控释尿素氮肥利用潜力和减少氮素损失的作用,定量研究控释尿素在稻田的去向和利用率,为高效施用控释肥料提供依据。【方法】通过田间微区试验,设置不施氮肥(CK)、^(15)N标记的粉末状普通尿素(U)和控释尿素(CRU)3个处理,研究不同生育时期水稻对肥料氮的吸收、分配和转运及肥料氮在稻田的去向和利用率。【结果】随生育期的推进,水稻植株茎和鞘的干物质量及^(15)N积累量逐渐增加,开花期达到最大值。开花期,与U处理相比,CRU处理水稻植株茎的干物质量提高13.8%,鞘的干物质量无明显变化,茎和鞘的^(15)N积累量分别提高62.5%和25.5%,随后由于营养器官干物质和^(15)N向籽粒的不断转移而降低。随着叶片的衰老脱落,叶的干物质量及^(15)N积累量从抽穗期开始逐渐下降,成熟期达到最小值。而穗的干物质量及^(15)N积累量从孕穗期开始不断增加,到成熟期达到最大值。成熟期,与U处理相比,CRU处理水稻茎、鞘、穗和地上部的干物质量及^(15)N积累量分别增加17.3%、13.2%、3.5%、3.7%和25.0%、20.0%、15.8%、13.3%,叶的干物质量及^(15)N积累量分别降低14.6%和15.2%。开花期到成熟期,CRU处理的水稻干物质及^(15)N转运量、转运率、对籽粒的贡献率分别为286.78 g·m^(-2)、32.3%、30.8%和2.69 g·m^(-2)、67.2%、83.8%,与U处理相比略有增加,但统计上差异不显著。但灌浆期到成熟期,CRU处理养分供应充足,促进了水稻籽粒的灌浆速率,促进了籽粒中干物质的积累及氮素的同化和营养器官中养分向籽粒的迅速转运。等氮量下,与U处理相比,CRU处理水稻产量和植株吸氮量略有增加,但差异不显著;施用CRU提高水稻植株^(15)N吸收量13.3%,提高水稻^(15)N利用率3.2个百分点,增加水稻植株氮素来自^(15)N肥料的百分比(Ndff)2.9个百分点,增加^(15)N土壤残留率0.9个百分点,提高^(15)N总回收率4.0个百分点,减少^(15)N损失率4.0个百分点。无论施用控释尿素还是普通尿素,土壤氮素均是水稻生长发育所需氮素的主要来源,水稻生育期吸收氮素来自土壤的氮素约占70%以上。肥料氮在土壤中的残留量随土层深度的增加而显著下降,水稻收获后,肥料^(15)N主要残留在0—20 cm土层中,约占总残留量的78%。其次是20—40 cm和40—60 cm土层,这两层土壤中肥料^(15)N残留量相近,约占总残留量的19%左右。而在60 cm土层以下,仍有微量的肥料^(15)N残留,占总残留量的4%以下。【结论】施用控释尿素可以增加水稻各生育期的干物质量和氮素吸收量,增加花后(尤其是灌浆期到成熟期)干物质和氮素的转运,在稳产的情况下,既提高了肥料氮利用率,也减少了肥料氮的损失。 展开更多
关键词 控释尿素 15N示踪技术 氮素去向 氮肥利用率 稻田
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基于中红外光声光谱的纸质文献破损定级的研究
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作者 马赵扬 杜昌文 《新世纪图书馆》 CSSCI 2019年第7期70-73,共4页
本文通过红外光声光谱扫描,建立不同破损级别纸张的预测模型,以达到快速检测纸张破损程度的目的。研究发现不同破损级别的纸张有明显的聚类特点,利用概率神经网络建立纸张破损级别模型的预测准确率达到62%。未来在优化模型的同时,拟增... 本文通过红外光声光谱扫描,建立不同破损级别纸张的预测模型,以达到快速检测纸张破损程度的目的。研究发现不同破损级别的纸张有明显的聚类特点,利用概率神经网络建立纸张破损级别模型的预测准确率达到62%。未来在优化模型的同时,拟增加纸张各组分的定量研究,建立纸张破损程度与纸张物质变化的相关关系并达到实时监测的目的。 展开更多
关键词 纸张破损定级 红外光声光谱 概率神经网络
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CHINESE HIGH-TECH AG IN CAMBODIA New collaboration on harvesting rice and cotton
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作者 du changwen 《China Report ASEAN》 2019年第8期44-45,共2页
Northern Cambodia is home to TonléSap Lake,the largest freshwater lake in Southeast Asia.Connecting the TonléSap and Mekong rivers,this giant turquoise pool in the flat and broad plain of the TonléSap b... Northern Cambodia is home to TonléSap Lake,the largest freshwater lake in Southeast Asia.Connecting the TonléSap and Mekong rivers,this giant turquoise pool in the flat and broad plain of the TonléSap basin measures 500 kilometers long and over 110 kilometers wide.The TonléSap plain’s bountiful sunshine,water and fertile land have made it the most important agricultural production base in Cambodia.The premium rice produced in the region has won the championship of the World Rice Conference many times and is renowned as White Gold. 展开更多
关键词 measures PLAIN HARVESTING
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In Situ Measurement of Ammonia Concentration in Soil Headspace Using Fourier Transform Mid-Infrared Photoacoustic Spectroscopy 被引量:2
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作者 du changwen WANG Jiao +2 位作者 ZHOU Zijun SHEN Yazhen ZHOU Jianmin 《Pedosphere》 SCIE CAS CSCD 2015年第4期605-612,共8页
Ammonia (NH3) volatilization is one of the important pathways of nitrogen loss in alkaline soil, and the NH3 concentration in soil headspace is directly linked with the NH3 volatilization. Ammonia was characterized ... Ammonia (NH3) volatilization is one of the important pathways of nitrogen loss in alkaline soil, and the NH3 concentration in soil headspace is directly linked with the NH3 volatilization. Ammonia was characterized by Fourier transform mid-infrared photoacoustic spectroscopy (FTIR-PAS) and two typical absorption bands in the region of 850-1 200 cm-1 were observed, which could be used for the prediction of NH3 concentration in the soil headspaze. An alkaline soil from North China was involved in the soil incubation, pot and field experiments under three fertilization treatments (control without N input (CK), urea and coated urea). Ammonia concentrations in the soil headspace were determined in each experiment. In the soil incubation experiment, the NH3 emissions were initiated by the N input, reached the highest concentration on day 2, and decreased to the level as measured in CK after 8 d, with significantly higher NH3 emissions in the urea treatment compared to coated urea treatment, especially during the first 4 d. The NH3 concentration in soil headspace of the pot experiment showed the similar dynamics as that in the incubation experiment; however, the NH3 concentration in the soil headspace in the field experiment demonstrated a significantly different emission pattern with those of the incubation and pot experiments, and there was a 4-d delay for the NH3 concentration. Therefore, the NH3 concentration in the incubation and pot experiments could not be directly used to model the real NH3 emission in the field due to the differences in fertilization method and application rate as well as soil temperature and soil disturbance. It was recommended that light irrigation in the second week after fertilization and involvement of controlled release coated urea could be used to significantly decrease N loss from the perspective of NH3 volatilization. Key Words: ammonia volatilization, cantilevel-type microphone, nitrogen, principal component regression, soil incubation. 展开更多
关键词 ammonia volatilization cantilevel-type microphone NITROGEN principal component regression soil incubation
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