A new acetate radical bridged dinuclear copper（ Ⅱ ） complex [（C8H9NO2）2- Cu2（CH3COO）4] has been synthesized by the reaction of Cu（OAc）2 with pyridine-3-ethyl formate and further characterized by X-ray single-...A new acetate radical bridged dinuclear copper（ Ⅱ ） complex [（C8H9NO2）2- Cu2（CH3COO）4] has been synthesized by the reaction of Cu（OAc）2 with pyridine-3-ethyl formate and further characterized by X-ray single-crystal diffraction. Crystal data for the title compound： triclinic system, space group Pí, with a = 8.1654（14）, b = 9.7010（16）, c = 9.9005（17） A, α = 83.266（2）, β = 78.887（2）, γ = 72.881（2）°, V= 733.9（2） A^3, Mr = 665.58, Z = 1, Dc = 1.506 g/cm^3, F（000） = 342,μ = 1.510 mm^-1, the final R = 0.0392 and wR = 0.1005. According to the structural determination, each unit of the title compound is composed of two Cu（ Ⅱ ） atoms, two pyridine-3-ethyl formate molecules and four acetate ions. Each Cu（Ⅱ） coordinates to oxygen atoms of acetate and nitrogen atoms of pyridine- 3-ethyl formate ligand to give a six-coordinate distorted octahedral geometry. It is worth mentioning that strong Cu-Cu bond can be observed in the title compound.展开更多
文摘A new acetate radical bridged dinuclear copper（ Ⅱ ） complex [（C8H9NO2）2- Cu2（CH3COO）4] has been synthesized by the reaction of Cu（OAc）2 with pyridine-3-ethyl formate and further characterized by X-ray single-crystal diffraction. Crystal data for the title compound： triclinic system, space group Pí, with a = 8.1654（14）, b = 9.7010（16）, c = 9.9005（17） A, α = 83.266（2）, β = 78.887（2）, γ = 72.881（2）°, V= 733.9（2） A^3, Mr = 665.58, Z = 1, Dc = 1.506 g/cm^3, F（000） = 342,μ = 1.510 mm^-1, the final R = 0.0392 and wR = 0.1005. According to the structural determination, each unit of the title compound is composed of two Cu（ Ⅱ ） atoms, two pyridine-3-ethyl formate molecules and four acetate ions. Each Cu（Ⅱ） coordinates to oxygen atoms of acetate and nitrogen atoms of pyridine- 3-ethyl formate ligand to give a six-coordinate distorted octahedral geometry. It is worth mentioning that strong Cu-Cu bond can be observed in the title compound.
