The monoclinic phase of Y2O3（B-RES） has been synthesized using a Kawai-type multi-anvil apparatus under 20 GPa at 1800℃. Samples of the cubic Y2O3（C-RES） and monoclinic Y2O3 phases were characterized by synchrotr...The monoclinic phase of Y2O3（B-RES） has been synthesized using a Kawai-type multi-anvil apparatus under 20 GPa at 1800℃. Samples of the cubic Y2O3（C-RES） and monoclinic Y2O3 phases were characterized by synchrotron radiation X-ray diffraction, X-ray absorption near edge structure and Raman spectroscopy. Crystal structures of the cubic and monoclinic phases have been examined using Rietveld refinement of the X-ray diffraction data. The cubic-to-monoclinic transition of Y2O3 was reconstructive and irreversible. The X-ray diffraction results were further confirmed by simulation of the X-ray absorption spectra.展开更多
基金Supported by the National Natural Science foundation of China（Nos.U 1232204, 41473056）.
文摘The monoclinic phase of Y2O3（B-RES） has been synthesized using a Kawai-type multi-anvil apparatus under 20 GPa at 1800℃. Samples of the cubic Y2O3（C-RES） and monoclinic Y2O3 phases were characterized by synchrotron radiation X-ray diffraction, X-ray absorption near edge structure and Raman spectroscopy. Crystal structures of the cubic and monoclinic phases have been examined using Rietveld refinement of the X-ray diffraction data. The cubic-to-monoclinic transition of Y2O3 was reconstructive and irreversible. The X-ray diffraction results were further confirmed by simulation of the X-ray absorption spectra.
