Molybdosphoric Acid Mixed with Titania Used as a Catalyst to Synthesize Diphenyl Carbonate via Transesterification of Dimethyl Carbonate and Phenol

The 12-molybdosphoric acid mixed with titania （MPA-TiO2） was found to be a novel and efficient catalyst for the synthesis of diphenyl carbonate （DPC） via transesterification of dimethyl carbonate （DMC） and phenol. The X-ray diffraction （XRD） and infrared （IR） techniques were employed to characterize the prepared catalysts. The effect of the weight ratio of the 12-molybdosphoric acid to titania on the transesterification was investigated. A 13.1% yield of DPC and an 11.6% yield of methyl phenyl carbonate （MPC） were obtained over MPA-TiO2 with the weight ratio of MPA to TiO2 as 5：1.

Rotary-scaling fine-tuning (RSFT) method for optimizing railway wheel profiles and its application to a locomotive

The existing multi-objective wheel profile optimization methods mainly consist of three sub-modules:(1)wheel profile generation,(2)multi-body dynamics simulation,and(3)an optimization algorithm.For the first module,a comparably conservative rotary-scaling finetuning(RSFT)method,which introduces two design variables and an empirical formula,is proposed to fine-tune the traditional wheel profiles for improving their engineering applicability.For the second module,for the TRAXX locomotives serving on the Blankenburg–Rubeland line,an optimization function representing the relationship between the wheel profile and the wheel–rail wear number is established based on Kriging surrogate model(KSM).For the third module,a method combining the regression capability of KSM with the iterative computing power of particle swarm optimization(PSO)is proposed to quickly and reliably implement the task of optimizing wheel profiles.Finally,with the RSFT–KSM–PSO method,we propose two wear-resistant wheel profiles for the TRAXX locomotives serving on the Blankenburg–Rubeland line,namely S1002-S and S1002-M.The S1002-S profile minimizes the total wear number by 30%,while the S1002-M profile makes the wear distribution more uniform through a proper sacrifice of the tread wear number,and the total wear number is reduced by 21%.The quasi-static and hunting stability tests further demonstrate that the profile designed by the RSFT–KSM–PSO method is promising for practical engineering applications.

Evaluation of the ventilation system in an LNG cargo tank construction platform (CTCP) by the AHP-entropy weight method

Owing to the vulnerability of Invar to moisture in the membranes of LNG tanker cargo tank construction platforms(CTCPs),an energy-efficient ventilation system is needed to maintain a suitable thermal-moisture environment and a healthy workplace.However,the optimal distribution of supply and return devices that would guarantee worker satisfaction,air quality,and energy efficiency is unclear.Therefore,we conducted numerical simulations to determine the worker satisfaction indices(temperature,relative humidity,and carbon monoxide concentration satisfactions),air quality index(contaminant-removal efficiency),and energy efficiency index(heat-removal efficiency)with supply vane angles ranging from-75°to 0°and two return vent positions(the bottom return vent and the top return vent).The analytic hierarchy process(AHP)entropy weight method was employed to determine the optimal supply vane angle and return vent position for three design targets by considering these indices simultaneously.The results indicated that,with a supply angle of-45°and a bottom return vent,worker satisfaction and air quality were prioritized.Furthermore,a high energy performance of the ventilation system was achieved with a-15°supply angle and a bottom return vent.Moreover,a comprehensive graph of supply vane angles at both return heights,which could provide a reference for optimizing the ventilation system in LNG-CTCPs,is described.