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高强度部分脱乙酰甲壳素纳米纤维/聚乙烯醇复合丝线的制备及性能 被引量:1
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作者 陈楚楚 刘硕 +5 位作者 赵迪 马洁茹 李穗奕 徐朝阳 李大纲 金永灿 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2023年第4期139-145,共7页
从废弃蟹壳中提取甲壳素,对其进行部分脱乙酰及纳米化处理得到部分脱乙酰甲壳素纳米纤维(D-ChNFs)。将D-ChNF与聚乙烯醇(PVA)混合,利用湿法纺丝工艺制备D-ChNF/PVA复合丝线,并对其微观形貌、力学性能、表面特性及结晶结构等进行表征与... 从废弃蟹壳中提取甲壳素,对其进行部分脱乙酰及纳米化处理得到部分脱乙酰甲壳素纳米纤维(D-ChNFs)。将D-ChNF与聚乙烯醇(PVA)混合,利用湿法纺丝工艺制备D-ChNF/PVA复合丝线,并对其微观形貌、力学性能、表面特性及结晶结构等进行表征与分析。结果表明,在氢氧化钠凝固浴中,D-ChNF与PVA能够经分子间氢键结合实现丝状成型,通过调控两者质量比,所得复合丝线拉伸强度可达251.0MPa、断裂伸长率约8.14%、弹性模量近13.81GPa。进一步地,将该复合丝线作为柔性基材组装构建传感器,用于实时监测人体活动。研究结果可为拓展废弃蟹壳的多领域资源化与高值化利用提供理论依据与技术支持。 展开更多
关键词 甲壳素 聚乙烯醇 纳米纤维 湿法纺丝 力学性能
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甲壳素纳米纤维的制备及在生物质材料中的应用研究进展
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作者 马洁茹 糟娅梅 +4 位作者 刘硕 张正琦 李大纲 金永灿 陈楚楚 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2023年第12期147-156,共10页
甲壳素纳米纤维(Chitinnanofiber,ChNF)基于其自身的高纵横比、高比表面积、低密度和丰富的官能团在生物质材料研究领域备受关注。甲壳素主要来源于蟹、虾等甲壳纲动物外壳、鱿鱼顶骨、蘑菇等真菌植物的细胞壁。近年来,有关甲壳素表面... 甲壳素纳米纤维(Chitinnanofiber,ChNF)基于其自身的高纵横比、高比表面积、低密度和丰富的官能团在生物质材料研究领域备受关注。甲壳素主要来源于蟹、虾等甲壳纲动物外壳、鱿鱼顶骨、蘑菇等真菌植物的细胞壁。近年来,有关甲壳素表面改性及在食品、化工等领域的应用已被综述,但甲壳素的纳米化制备及甲壳素纳米纤维功能化应用在生产工艺、综合性能等方面的总结还有待进一步完善。文中综述了生物体中甲壳素的提取方法、纳米化制备工艺及甲壳素纳米纤维功能化应用的研究进展,分别介绍了甲壳素纳米纤维制得的光学透明材料、高强度凝胶材料、高强度丝线、可降解包装材料和以甲壳素纳米纤维作为增强相的复合材料等在柔性显示、柔性传感、智慧包装、生物医药、组织工程及可降解包装等生物质材料领域的应用。最后,对甲壳素纳米纤维的制备及功能化应用的未来研究发展方向进行了展望,以期为后续研究者开发新型功能化甲壳素纳米纤维材料提供参考。 展开更多
关键词 甲壳素 纳米化 纳米纤维 增强相 生物质材料
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Evaluation of Water Transfer Capacity of Poplar with Pectinase Treated under the Solar Interface Evaporation
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作者 Wei Xiong dagang li +2 位作者 Peixing Wei lin Wang Qian Feng 《Journal of Renewable Materials》 SCIE EI 2023年第5期2265-2278,共14页
Poplar wood,which was used as the absorption material for the solar-driven interfacial evaporation,was treated for 3 days,6 days and 9 days with the pectinase,and then was simulated for photothermal evaporation test a... Poplar wood,which was used as the absorption material for the solar-driven interfacial evaporation,was treated for 3 days,6 days and 9 days with the pectinase,and then was simulated for photothermal evaporation test at one standard solar radiation intensity(1 kW⋅m^(−2)).The effects of pectinase treatment on cell passage and water migration capacity of poplars were analyzed by the mercury intrusion porosimetry,the scanning electron microscope and fractal theory.It was found that the pit membrane and the ray parenchyma cells of poplar wood were degraded and destroyed after pectinase treatment.Compared with the untreated poplar wood,the evaporation rate of three sections of the specimen was changed.Especially the evaporation rate of radial and tangential direction was significantly increased.At the same time,based on the experimental data and fractal dimension deduction,fractal characteristics could be found in that the structure of poplars treated with pectinase.The porosity decreased with the increase of the fractal dimension in a certain range.It was shown that it is feasible to evaluate solar-driven water migration capacity by using fractal theory. 展开更多
关键词 PECTINASE poplar wood solar-driven water migration PERMEABILITY fractal dimension
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聚乙烯醇增强p(AA-co-CTS)规整吸附介质的制备及对Sb(Ⅴ)的吸附性能 被引量:5
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作者 李大刚 陈晓玲 +2 位作者 陈崇城 李云龙 林松柏 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2020年第2期161-168,共8页
以复配过硫酸钾-抗坏血酸为氧化还原引发剂,丙烯酸(AA)、壳聚糖(CTS)为功能性单体,以聚乙烯醇(PVA)为互穿线型高分子,利用溶剂结晶成孔技术和低温引发聚合制备了具有高强度、规整型吸附介质PVA-p(AA-co-CTS),探究了其对Sb(Ⅴ)的吸附性... 以复配过硫酸钾-抗坏血酸为氧化还原引发剂,丙烯酸(AA)、壳聚糖(CTS)为功能性单体,以聚乙烯醇(PVA)为互穿线型高分子,利用溶剂结晶成孔技术和低温引发聚合制备了具有高强度、规整型吸附介质PVA-p(AA-co-CTS),探究了其对Sb(Ⅴ)的吸附性能。聚合体系最佳配方:AA与CTS总质量分数为7%,其中CTS与AA的质量比为0.18~0.2,PVA的质量分数为1.5%~2.0%,PVA-p(AA-co-CTS)介质整体成型于反应器中,孔隙连续,孔径范围为100~800μm,湿样抗压缩强度为0.48 MPa;孔隙内表面富含的-OH、-NH2及-COOH基团对Sb(Ⅴ)有强吸附能力。最佳吸附工艺为流量6 mL/min,温度293.15 K,初始浓度200 mg/L,最大吸附量76.77 mg/g。当操作温度在293.15 K时,Thomas拟合方程R2=0.9995,KTh=1.7595 mL/(mg·min)。富含功能基团规整型吸附介质通过低温结晶聚合一步成功制备,可取代传统散装吸附树脂、离子交换树脂用于Sb(Ⅴ)的吸附分离。 展开更多
关键词 吸附 连续床 共聚物 介质 Sb(Ⅴ)
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Performance Analysis and Framework Optimization of Open Source Cloud Storage System 被引量:1
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作者 Lei li dagang li +2 位作者 Zhiliang Su lianwen Jin Ganbo Huang 《China Communications》 SCIE CSCD 2016年第6期110-122,共13页
More and more embedded devices, such as mobile phones, tablet PCs and laptops, are used in every field, so huge files need to be stored or backed up into cloud storage. Optimizing the performance of cloud storage is v... More and more embedded devices, such as mobile phones, tablet PCs and laptops, are used in every field, so huge files need to be stored or backed up into cloud storage. Optimizing the performance of cloud storage is very important for Internet development. This paper presents the performance evaluation of the open source distributed storage system, a highly available, distributed, eventually consistent object/blob store from Open Stack cloud computing components. This paper mainly focuses on the mechanism of cloud storage as well as the optimization methods to process different sized files. This work provides two major contributions through comprehensive performance evaluations. First, it provides different configurations for Open Stack Swift system and an analysis of how every component affects the performance. Second, it presents the detailed optimization methods to improve the performance in processing different sized files. The experimental results show that our method improves the performance and the structure. We give the methods to optimize the object-based cloud storage system to deploy the readily available storage system. 展开更多
关键词 Cloud Computing OpenStack Swift Object Storage Distribute System Storage Service Optimization
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高强度柔性木材膜的制备与性能
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作者 陈楚楚 周彤 +5 位作者 李卓衍 谢炬炫 刘利会 徐朝阳 李大纲 金永灿 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2022年第3期137-143,共7页
以轻木为原料,通过脱基质处理结合表面改性工艺(2,2,6,6-四甲基哌啶氮氧化物TEMPO氧化和乙酰化),制备了一系列高强度柔性木材膜,并系统研究了不同处理方法对木材膜力学性能、光学性能、宏/微观形貌、表面特性及结晶结构等的影响。结果表... 以轻木为原料,通过脱基质处理结合表面改性工艺(2,2,6,6-四甲基哌啶氮氧化物TEMPO氧化和乙酰化),制备了一系列高强度柔性木材膜,并系统研究了不同处理方法对木材膜力学性能、光学性能、宏/微观形貌、表面特性及结晶结构等的影响。结果表明,脱基质处理后的木材纤维骨架在干燥过程中能够形成具有致密层状结构的木材膜试样,其密度提高了近5倍。进一步经TEMPO氧化及乙酰化处理后,木材膜试样的透光性及力学性能均有显著提升,其中,TEMPO木材膜透光率约为61.8%,断裂拉伸强度为180.29 MPa;而乙酰化木材膜断裂拉伸强度达264.14 MPa,几乎是轻木的14倍。进一步将其作为柔性基材,制备了一种智能防伪标签。其研究结果可为促进木材的高值化利用提供理论依据与技术支持。 展开更多
关键词 木材 改性 力学性能 乙酰化
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An overview of aflatoxin B1 biotransformation and aflatoxin M1 secretion in lactating dairy cows 被引量:6
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作者 li Min Johanna Fink-Gremmels +6 位作者 dagang li Xiong Tong Jing Tang Xuemei Nan Zhongtang Yu Weidong Chen Gang Wang 《Animal Nutrition》 SCIE CSCD 2021年第1期42-48,共7页
Milk is considered a perfect natural food for humans and animals.However,aflatoxin B1(AFB1)contaminating the feeds fed to lactating dairy cows can introduce aflatoxin M1(AFM1),the main toxic metabolite of aflatoxins i... Milk is considered a perfect natural food for humans and animals.However,aflatoxin B1(AFB1)contaminating the feeds fed to lactating dairy cows can introduce aflatoxin M1(AFM1),the main toxic metabolite of aflatoxins into the milk,consequently posing a risk to human health.As a result of AFM1 monitoring in raw milk worldwide,it is evident that high AFM1 concentrations exist in raw milk in many countries.Thus,the incidence of AFM1 in milk from dairy cows should not be underestimated.To further optimize the intervention strategies,it is necessary to better understand the metabolism of AFB1 and its biotransformation into AFM1 and the specific secretion pathways in lactating dairy cows.The meta-bolism of AFB1 and its biotransformation into AFM1 in lactating dairy cows are drawn in this review.Furthermore,recent data provide evidence that in the mammary tissue of lactating dairy cows,aflatoxins significantly increase the activity of a protein,ATP-binding cassette super-family G member 2(ABCG2),an efflux transporter known to facilitate the excretion of various xenobiotics and veterinary drugs into milk.Further research should focus on identifying and understanding the factors that affect the expression of ABCG2 in the mammary gland of cows. 展开更多
关键词 Aflatoxin B1 BIOTRANSFORMATION Aflatoxin M1 Dairy cow Milk safety
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