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调控等级孔UiO-66(Ce)中Ru纳米团簇的电子态、丰度和微环境用于高效催化双环戊二烯加氢
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作者 李如硕 汪琳梦 +7 位作者 周佩云 林璟 刘志远 陈娟 赵丹凤 黄秀兵 陶志平 王戈 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第1期150-165,共16页
催化石油加工副产物双环戊二烯(DCPD)加氢得到的四氢双环戊二烯(THDCPD)是一种高能量密度燃料,在航空航天领域具有重要应用价值.传统DCPD加氢催化剂在反应中存在使用寿命短和重复使用性差等问题.金属有机框架(MOFs)作为一种周期有序多... 催化石油加工副产物双环戊二烯(DCPD)加氢得到的四氢双环戊二烯(THDCPD)是一种高能量密度燃料,在航空航天领域具有重要应用价值.传统DCPD加氢催化剂在反应中存在使用寿命短和重复使用性差等问题.金属有机框架(MOFs)作为一种周期有序多孔材料,有望成为用于DCPD加氢的新型高效催化剂.通过引入介孔或大孔来构建等级孔MOFs(HP-MOFs),可以克服微孔对DCPD等大客体分子的扩散限制,促进底物分子向HP-MOFs内部活性位点转移.此外,加入合适的金属组分(如价格相对低廉的Ru)到HP-MOFs,可以使金属的原子利用率最大化,优化活性位点的分散性和稳定性,进一步协同提升催化性能.因此,发展HP-MOFs与金属组分间异质结构的调控方法,建立构效关系至关重要.本文采用软模板法制备了HP-UiO-66(Ce),设计和构建了介孔UiO-66(Ce)负载钌纳米簇(NCs)异质材料,并用于催化DCPD加氢反应.X射线衍射(XRD)、扫描电镜、透射电镜、氮气吸脱附和DCPD加氢结果表明,与微孔和大孔UiO-66(Ce)相比,介孔UiO-66(Ce)独特的结构在催化剂制备和DCPD加氢中显示出独特的优势:(1)具有配体缺失缺陷的Ce-oxo簇促进了Ru^(3+)的有效吸附;(2)微孔框架的约束作用实现了Ru NCs的有效固定和均匀分散,抑制了Ru NCs的团聚和流失,保证了催化剂的稳定性;(3)介孔结构为DCPD和H_(2)底物分子提供了高效的传质通道,也有利于暴露更多的活性中心,促进DCPD与H_(2)底物分子的吸附和活化.此外,通过优化合成条件,可以精确控制Ru NCs活性位点的电子结构、分布和微环境.XRD和X射线光电子能谱结果表明,Ru NCs和Meso-UiO-66(Ce)之间Ru-O-Ce强异质界面的形成导致了晶格畸变,Ru@Meso-UiO-25-200中Ru^(0)和M-O占比最多,主要来源于还原处理得到的Ru NCs和Ru-O-Ce异质界面中Ru‒O键的形成,且样品中Ru0的含量与Ru^(3+)吸附温度呈反相关趋势,与样品还原温度呈正相关趋势.密度泛函理论计算结果表明,金属Ru0作为主要活性位点,极大地促进了DCPD和H2的吸附,并激活了催化剂上吸附的DCPD的C=C键,促进了DCPD两个C=C双键的“共吸附”和连续化加氢过程.因此,介孔UiO-66(Ce)和Ru NCs异质结构的构建,在低温(60℃)下仅用35 min就实现了DCPD催化加氢得到四氢双环戊二烯(THDCPD)(100%转化率和~100%选择性),且循环使用6次后性能基本保持不变,表现出较好的活性和稳定性.综上,本文通过等级孔和异质结构的构筑,证明了介孔结构在大底物分子催化反应中的结构优越性,并进一步揭示了催化剂合成条件、结构和性能之间的关系,为理性设计新型MOFs基功能材料在催化、吸附、储能等方面的应用提供新思路. 展开更多
关键词 等级孔 UiO-66(Ce) Ru纳米簇 双环戊二烯 微环境调控
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Novel joint encoding/decoding algorithms of fountain codes for underwater acoustic communication 被引量:1
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作者 Mingshen Liang Jinjue Duan +2 位作者 danfeng zhao Jiaxi Si Xiangyu Song 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第4期772-779,共8页
Fountain codes are considered to be a promising coding technique in underwater acoustic communication(UAC) which is challenged with the unique propagation features of the underwater acoustic channel and the harsh ma... Fountain codes are considered to be a promising coding technique in underwater acoustic communication(UAC) which is challenged with the unique propagation features of the underwater acoustic channel and the harsh marine environment. And Luby transform(LT) codes are the first codes fully realizing the digital fountain concept. However, in conventional LT encoding/decoding algorithms, due to the imperfect coverage(IC) of input symbols and short cycles in the generator matrix, stopping sets would occur and terminate the decoding. Thus, the recovery probability is reduced,high coding overhead is required and decoding delay is increased.These issues would be disadvantages while applying LT codes in underwater acoustic communication. Aimed at solving those issues, novel encoding/decoding algorithms are proposed. First,a doping and non-uniform selecting(DNS) encoding algorithm is proposed to solve the IC and the generation of short cycles problems. And this can reduce the probability of stopping sets occur during decoding. Second, a hybrid on the fly Gaussian elimination and belief propagation(OFG-BP) decoding algorithm is designed to reduce the decoding delay and efficiently utilize the information of stopping sets. Comparisons via Monte Carlo simulation confirm that the proposed schemes could achieve better overall decoding performances in comparison with conventional schemes. 展开更多
关键词 underwater acoustic communication(UAC) fountain codes non-uniform encoding hybrid decoding algorithm stopping sets
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Optimized Content-Aware Image Resizing with Merging and Improved Importance Diffusion
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作者 danfeng zhao Bo Wang 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2015年第2期67-73,共7页
A simple and effective content-aware image resizing method is proposed based on the row / column merging and improved importance diffusion,which preserves the important regions in an image as well as the global visual... A simple and effective content-aware image resizing method is proposed based on the row / column merging and improved importance diffusion,which preserves the important regions in an image as well as the global visual effect. By repeatedly merging two rows / columns into one row / column or inserting a new row /column between two rows / columns, this method realizes image-resolution reduction and expansion. The importance of the merged row / column is promoted and diffused to four rows / columns around the merged one,which is to avoid the unwanted image distortions resulted from excessively merging of un-important regions. In addition,the proposed method introduces the direction of gradient vector in the low-pass filter to reduce the interference caused by complex texture background and protect important content better. Furthermore,according to human mechanics principles,different weights are given to the row and column direction components of gradient vectors which can obtain better global visual effect. Experimented results show that the proposed method satisfied in not only visual effect but also objective evaluation. 展开更多
关键词 content-aware IMAGE resizing MERGING IMPORTANCE DIFFUSION GRADIENT VECTOR
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Low Complexity Multiuser Detection Algorithm for Multi-Beam Satellite Systems
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作者 Yang Wang danfeng zhao Xi Liao 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2015年第5期105-109,共5页
The minimum mean square error-successive interference cancellation( MMSE-SIC) multiuser detection algorithm has high complexity and long processing latency. A multiuser detection algorithm is proposed for multi-beam s... The minimum mean square error-successive interference cancellation( MMSE-SIC) multiuser detection algorithm has high complexity and long processing latency. A multiuser detection algorithm is proposed for multi-beam satellite systems in order to decrease the complexity and latency. The spot beams are grouped base on the distance between them in the proposed algorithm. Some groups are detected in parallel after a crucial group-wise interference cancellation. Furthermore, the multi-stage structure is introduced to improve the performance. Simulation results show that the proposed algorithm can achieve better performance with less complexity compared with the existing group detection algorithm. Moreover,the proposed algorithm using one stage can reduce the complexity over the fast MMSE-SIC and existing group detection algorithm by 9% and20. 9%. The processing latency is reduced significantly compared with the MMSE-SIC. 展开更多
关键词 satellite COMMUNICATIONS MULTI-BEAM SATELLITES MULTIUSER detection COMPLEXITY
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Improved iterative convergence method in Q-ary LDPC coded high order PR-CPM
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作者 danfeng zhao Yanbo Sun Rui Xue 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2016年第3期541-548,共8页
The Q-ary low-density parity-check(LDPC) coded high order partial response continuous phase modulation(PR-CPM) with double iterative loops is investigated. This scheme shows significant improvements in power and b... The Q-ary low-density parity-check(LDPC) coded high order partial response continuous phase modulation(PR-CPM) with double iterative loops is investigated. This scheme shows significant improvements in power and bandwidth efficiency, but at the expense of long iterative decoding delay and computational complexity induced by the improper match between the demodulator and the decoder. To address this issue, the convergence behavior of Q-ary LDPC coded CPM is investigated for the Q=2 and Q〉2 cases, and an optimized design method based on the extrinsic information transfer chart is proposed to improve the systematic iterative efficiency. Simulation results demonstrate that the proposed method can achieve a perfect tradeoff between iterative decoding delay and bit error rate performance to satisfy real-time applications. 展开更多
关键词 iterative detection convergence low-density paritycheck(LDPC) code continuous phase modulation(CPM) extrinsic information transfer chart
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肾癌血管新生与肿瘤干细胞的相关性探索 被引量:3
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作者 王璐 付博 +2 位作者 赵丹凤 杨光 徐万海 《中华医学杂志》 CAS CSCD 北大核心 2021年第46期3804-3808,共5页
目的探索肿瘤血管新生与肾癌干细胞的相关性。方法应用细胞原代培养方法提取分离在哈尔滨医科大学附属医院泌尿外科接受手术的肾透明细胞癌患者的肾癌干细胞(RCSCs),随后利用qRT-PCR和Western印迹方法分别检测不同微血管密度(MVD)肾癌... 目的探索肿瘤血管新生与肾癌干细胞的相关性。方法应用细胞原代培养方法提取分离在哈尔滨医科大学附属医院泌尿外科接受手术的肾透明细胞癌患者的肾癌干细胞(RCSCs),随后利用qRT-PCR和Western印迹方法分别检测不同微血管密度(MVD)肾癌组织来源的肾癌干细胞标志物CD105、Sox2基因和蛋白表达水平。利用TCGA数据库数据,分析肿瘤血管新生标志物与肿瘤干细胞调控基因相关性。结果高MVD肾癌组织来源的RCSCs中干细胞标志物CD105和Sox2基因分别升高(2.34±1.77)倍和(3.92±1.41)倍(P_(CD105)<0.01,P_(Sox2)<0.05),蛋白水平升高(5.12±3.31)倍和(4.90±3.30)倍(P_(CD105)<0.05,P_(Sox2)<0.01)。高达30%的干细胞促“干性”调控基因与血管新生基因CD31/PECAM1、KDR存在正相关关系,并且有64个基因同时与CD31/PECAM1和KDR基因存在强正相关关系(r>0.6,P<0.05)。结论肾癌高微血管密度与肾癌干细胞存在强相关性。 展开更多
关键词 肾肿瘤 肾细胞 血管新生 微血管密度 肾癌干细胞
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