The large-scale accumulation and pollution of solid mining waste is an urgent issue.Coal gangue is a prominent type of solid waste,and shows promise for use in high value-added products due to its content of many impo...The large-scale accumulation and pollution of solid mining waste is an urgent issue.Coal gangue is a prominent type of solid waste,and shows promise for use in high value-added products due to its content of many important compounds,including SiO_(2) and Al2O3.This study proposed the preparation of highly porous ceramics from coal gangue,coal slime,and coconut palm fibers.The ceramics were produced at a sintering temperature of 950℃ with a fiber content of 6 wt%,which led to the formation of porous ceramics with a porosity of 66.93%,volume density of 1.0329 g/cm^(3),compressive strength of 1.1025 MPa,and thermal conductivity is 0.3919 K(W/mk).A finite element model of the porous ceramics was established using the Abaqus module in ANSYS software,where the stress distribution and compressive strength were simulated.Further,the relationship between porosity and compressive strength was analyzed.The thermal properties of the porous ceramics were analyzed using the Fluent module,where the simulated changes in porosity under various sintering temperatures were consistent with the experimental data.The preparation of this highly porous ceramic from solid waste coal gangue shows promise for the minimizing the impact of waste gas and wastewater pollution in the future.展开更多
Single-phase Ba(Ti_(0.2)Zr_(0.2)Sn_(0.2)Hf_(0.2)Ce_(0.2))O_(3)(BTZSHC) high-entropy ceramics(HECs) with the perovskite structure were successfully prepared via the sol-gel method.The results reveal that the as-prepare...Single-phase Ba(Ti_(0.2)Zr_(0.2)Sn_(0.2)Hf_(0.2)Ce_(0.2))O_(3)(BTZSHC) high-entropy ceramics(HECs) with the perovskite structure were successfully prepared via the sol-gel method.The results reveal that the as-prepared ceramics exhibit a single cubic phase belonging to the Pm3 m space group.The high entropy is the driving force of the formation of single-phase ceramics.A larger entropy(ΔS_(mix)) and a negative enthalpy(ΔH_(mix)) are conducive to the formation of single-phase compounds.Herein,ΔS_(mix)=0.323 R mole-1andΔH_(mix)=43.88 kJ/mol.The sluggish-diffusion effect ensures the thermal stability of high-entropy systems.Dielectric measurements reveal that the as-prepared BTZSHC high-entropy ceramics are relaxor ferroelectrics,and the degree of relaxor(γ) is 1.9.The relaxor behavior of the as-prepared ceramics can be ascribed to the relaxation and thermal evolution of their polar units(PUs).The findings of this work provide a theoretical basis and technical support for the preparation of single-phase high-entropy ceramics.展开更多
Background and aims:Nonalcoholic fatty liver disease(NAFLD)is hepatic steatosis that is require the exclusion of certain etiologies,including drug usage or alcoholic consumption.Conversely,metabolic dysfunction-associ...Background and aims:Nonalcoholic fatty liver disease(NAFLD)is hepatic steatosis that is require the exclusion of certain etiologies,including drug usage or alcoholic consumption.Conversely,metabolic dysfunction-associated fatty liver disease(MAFLD)needs not to.In this study,we aimed to examine whether MAFLD is more easily diagnosed than NAFLD in liver transplant(LT)recipients with abnormal liver function.Methods:In this cross-sectional study,LT recipients with abnormal liver function were investigated for the prevalence of MAFLD and NAFLD.Results:We recruited 57 LT recipients with abnormal liver function at a referral hospital.Among these patients,the prevalence of MAFLD and NAFLD was 37.8%and 11.1%,respectively.17 patients showed hepatic steatosis,with an average NAFLD activity score of 3.5 and a fibrosis score of 1.0.Compared with non-MAFLD patients,MAFLD patients had a significant difference in fasting blood glucose levels(p?0.009).Among 17 MAFLD patients,12 were overweight and four were diagnosed with diabetes mellitus.The majority of MAFLD diagnoses were based on body mass index(70.6%)and diabetes mellitus history(23.5%),biomarkers that are easily obtained.At 6,12,24,and 36 months after LT,MAFLD patients had higher levels of fasting blood glucose(6 months:p?0.004,12 months:p?0.038)and higher trend of body mass index value and plasma triglyceride level but no significance.Conclusions:MAFLD was more easily diagnosed in LT recipients with abnormal liver function and higher in prevalence than NAFLD.A larger sample size research is required to validate these conclusions.展开更多
基金National Natural Science Foundation of China under Grant No.(51372197)Key Innovation Team of Shaanxi Province under Grant No.(2014KCT-04)Provincial Joint Fund of Shaanxi(2021JLM-28).
文摘The large-scale accumulation and pollution of solid mining waste is an urgent issue.Coal gangue is a prominent type of solid waste,and shows promise for use in high value-added products due to its content of many important compounds,including SiO_(2) and Al2O3.This study proposed the preparation of highly porous ceramics from coal gangue,coal slime,and coconut palm fibers.The ceramics were produced at a sintering temperature of 950℃ with a fiber content of 6 wt%,which led to the formation of porous ceramics with a porosity of 66.93%,volume density of 1.0329 g/cm^(3),compressive strength of 1.1025 MPa,and thermal conductivity is 0.3919 K(W/mk).A finite element model of the porous ceramics was established using the Abaqus module in ANSYS software,where the stress distribution and compressive strength were simulated.Further,the relationship between porosity and compressive strength was analyzed.The thermal properties of the porous ceramics were analyzed using the Fluent module,where the simulated changes in porosity under various sintering temperatures were consistent with the experimental data.The preparation of this highly porous ceramic from solid waste coal gangue shows promise for the minimizing the impact of waste gas and wastewater pollution in the future.
基金financially supported by the National Natural Science Foundation of China (Nos.52102144,52172099)the Provincial Joint Fund of Shaanxi (No.2021JLM-28)+1 种基金the Natural Science Basic Research Plan in Shaanxi Province of China (No.2022JM-255)the Scientific Research Plan Projects of Shaanxi Education Department (No.19JK0525)。
文摘Single-phase Ba(Ti_(0.2)Zr_(0.2)Sn_(0.2)Hf_(0.2)Ce_(0.2))O_(3)(BTZSHC) high-entropy ceramics(HECs) with the perovskite structure were successfully prepared via the sol-gel method.The results reveal that the as-prepared ceramics exhibit a single cubic phase belonging to the Pm3 m space group.The high entropy is the driving force of the formation of single-phase ceramics.A larger entropy(ΔS_(mix)) and a negative enthalpy(ΔH_(mix)) are conducive to the formation of single-phase compounds.Herein,ΔS_(mix)=0.323 R mole-1andΔH_(mix)=43.88 kJ/mol.The sluggish-diffusion effect ensures the thermal stability of high-entropy systems.Dielectric measurements reveal that the as-prepared BTZSHC high-entropy ceramics are relaxor ferroelectrics,and the degree of relaxor(γ) is 1.9.The relaxor behavior of the as-prepared ceramics can be ascribed to the relaxation and thermal evolution of their polar units(PUs).The findings of this work provide a theoretical basis and technical support for the preparation of single-phase high-entropy ceramics.
基金supported by the Beijing Funding Project[Z161100000116058]the 302 Military Hospital Project[YNKT2014006].
文摘Background and aims:Nonalcoholic fatty liver disease(NAFLD)is hepatic steatosis that is require the exclusion of certain etiologies,including drug usage or alcoholic consumption.Conversely,metabolic dysfunction-associated fatty liver disease(MAFLD)needs not to.In this study,we aimed to examine whether MAFLD is more easily diagnosed than NAFLD in liver transplant(LT)recipients with abnormal liver function.Methods:In this cross-sectional study,LT recipients with abnormal liver function were investigated for the prevalence of MAFLD and NAFLD.Results:We recruited 57 LT recipients with abnormal liver function at a referral hospital.Among these patients,the prevalence of MAFLD and NAFLD was 37.8%and 11.1%,respectively.17 patients showed hepatic steatosis,with an average NAFLD activity score of 3.5 and a fibrosis score of 1.0.Compared with non-MAFLD patients,MAFLD patients had a significant difference in fasting blood glucose levels(p?0.009).Among 17 MAFLD patients,12 were overweight and four were diagnosed with diabetes mellitus.The majority of MAFLD diagnoses were based on body mass index(70.6%)and diabetes mellitus history(23.5%),biomarkers that are easily obtained.At 6,12,24,and 36 months after LT,MAFLD patients had higher levels of fasting blood glucose(6 months:p?0.004,12 months:p?0.038)and higher trend of body mass index value and plasma triglyceride level but no significance.Conclusions:MAFLD was more easily diagnosed in LT recipients with abnormal liver function and higher in prevalence than NAFLD.A larger sample size research is required to validate these conclusions.