The orientation of stable single domain (SSD) ferrimagnetic particles in an igneous rock sample was determined by a sensitive technique utilizing gyroremanent magnetization (GRM). Components of GRM were measured in th...The orientation of stable single domain (SSD) ferrimagnetic particles in an igneous rock sample was determined by a sensitive technique utilizing gyroremanent magnetization (GRM). Components of GRM were measured in the sample upon exposure to an alternating field (AF) at various orientations in 3 orthogonal planes. The major components of GRM exhibited a sin(2θ) dependence on AF orientation in the respective perpendicular planes. This was in accordance with theory [1] and contrary to some previously reported experimental results on magnetic recording tape, which produced a distorted sin(2θ) dependence of the GRM [1]. The explanation is likely due to the SSD ferrimagnetic particles in the rock sample being more dispersed (less interacting) compared to the highly interacting SSD particles in the magnetic tape sample of the previous study. The GRM results were consistent with another remanence anisotropy method, anisotropy of isothermal remanent magnetization (AIRM). This method again measures the anisotropy of the remanence carrying ferrimagnetic particles, but the IRM is also acquired by larger multidomain (MD) particles as well as by the SSD particles. The results were also consistent with the visible rock anisotropy (petrofabric), the anisotropy of magnetic susceptibility (AMS), and the shear wave velocity anisotropy. A comparison of all the methods demonstrated that the fine SSD particles, which make up only a small proportion of the rock, were aligned in quite a similar orientation to that of the main rock forming minerals that constituted the bulk of the sample.展开更多
A paper by Mi et al. [1] suggested that certain nano-sized hematite (α-Fe2O3) particles had diamagnetic properties at room temperature. Since diamagnetic behavior is not a property normally attributed to hem...A paper by Mi et al. [1] suggested that certain nano-sized hematite (α-Fe2O3) particles had diamagnetic properties at room temperature. Since diamagnetic behavior is not a property normally attributed to hematite particles (hematite is generally regarded as a canted antiferromagnetic material at room temperature) we decided to test the validity of the suggestions in [1] by performing magnetic susceptibility and magnetic hysteresis measurements on a series of hematite nanoparticles with average sizes of 8 nm, 30 nm and 40 nm in diameter. We initially considered two possible explanations for the apparent diamagnetic behavior of the nanoparticles in [1]: either 1) the hematite nanoparticles themselves exhibited this unusual diamagnetic behavior, or 2) the diamagnetic response was simply the signal created by a diamagnetic dispersant that was overriding a weak positive magnetic susceptibility signal of the hematite nanoparticles. Our experiments strongly suggested the latter explanation that the apparent “diamagnetic” behavior seen in [1] was caused by a diamagnetic dispersant dominating the magnetic properties of the dispersed hematite nanoparticles.展开更多
This paper proposes a rapid means of identifying clay type and quantifying clay content from new template crossplots that compare magnetic susceptibility measurements with standard borehole well log data. The template...This paper proposes a rapid means of identifying clay type and quantifying clay content from new template crossplots that compare magnetic susceptibility measurements with standard borehole well log data. The templates are similar in format to standard industry charts, but have a number of advantages over the commonly used charts. Laboratory measurements of magnetic susceptibility on core samples and drill cuttings have recently shown strong correlations with key petrophysical parameters, particularly clay content and fluid permeability [1] [2]. A new template crossplot between magnetic susceptibility and borehole spectral gamma ray log data can firstly help to quickly identify the types of clay present in the formation. Additional new template crossplots between magnetic susceptibility and borehole bulk density data allow the mineral contents and porosities of binary mixtures of clay minerals and matrix minerals (such as illite clay + quartz) to be rapidly quantified. The templates can use ambient (room temperature) magnetic susceptibility data from measurements on core samples or drill cuttings in the laboratory or at the wellsite. Furthermore, the paper shows how the templates can potentially be extended to utilize borehole magnetic susceptibility data for in situ estimations of the type and content of clay. This requires accounting for the temperature dependence of the magnetic susceptibility of paramagnetic minerals (such as illite clay), which varies with depth in a borehole. Whilst borehole magnetic susceptibility measurements are rarely part of standard well logging operations, they could be a potentially useful tool for in situ clay type and content quantification, which in turn can help predict fluid permeability.展开更多
文摘The orientation of stable single domain (SSD) ferrimagnetic particles in an igneous rock sample was determined by a sensitive technique utilizing gyroremanent magnetization (GRM). Components of GRM were measured in the sample upon exposure to an alternating field (AF) at various orientations in 3 orthogonal planes. The major components of GRM exhibited a sin(2θ) dependence on AF orientation in the respective perpendicular planes. This was in accordance with theory [1] and contrary to some previously reported experimental results on magnetic recording tape, which produced a distorted sin(2θ) dependence of the GRM [1]. The explanation is likely due to the SSD ferrimagnetic particles in the rock sample being more dispersed (less interacting) compared to the highly interacting SSD particles in the magnetic tape sample of the previous study. The GRM results were consistent with another remanence anisotropy method, anisotropy of isothermal remanent magnetization (AIRM). This method again measures the anisotropy of the remanence carrying ferrimagnetic particles, but the IRM is also acquired by larger multidomain (MD) particles as well as by the SSD particles. The results were also consistent with the visible rock anisotropy (petrofabric), the anisotropy of magnetic susceptibility (AMS), and the shear wave velocity anisotropy. A comparison of all the methods demonstrated that the fine SSD particles, which make up only a small proportion of the rock, were aligned in quite a similar orientation to that of the main rock forming minerals that constituted the bulk of the sample.
文摘A paper by Mi et al. [1] suggested that certain nano-sized hematite (α-Fe2O3) particles had diamagnetic properties at room temperature. Since diamagnetic behavior is not a property normally attributed to hematite particles (hematite is generally regarded as a canted antiferromagnetic material at room temperature) we decided to test the validity of the suggestions in [1] by performing magnetic susceptibility and magnetic hysteresis measurements on a series of hematite nanoparticles with average sizes of 8 nm, 30 nm and 40 nm in diameter. We initially considered two possible explanations for the apparent diamagnetic behavior of the nanoparticles in [1]: either 1) the hematite nanoparticles themselves exhibited this unusual diamagnetic behavior, or 2) the diamagnetic response was simply the signal created by a diamagnetic dispersant that was overriding a weak positive magnetic susceptibility signal of the hematite nanoparticles. Our experiments strongly suggested the latter explanation that the apparent “diamagnetic” behavior seen in [1] was caused by a diamagnetic dispersant dominating the magnetic properties of the dispersed hematite nanoparticles.
文摘This paper proposes a rapid means of identifying clay type and quantifying clay content from new template crossplots that compare magnetic susceptibility measurements with standard borehole well log data. The templates are similar in format to standard industry charts, but have a number of advantages over the commonly used charts. Laboratory measurements of magnetic susceptibility on core samples and drill cuttings have recently shown strong correlations with key petrophysical parameters, particularly clay content and fluid permeability [1] [2]. A new template crossplot between magnetic susceptibility and borehole spectral gamma ray log data can firstly help to quickly identify the types of clay present in the formation. Additional new template crossplots between magnetic susceptibility and borehole bulk density data allow the mineral contents and porosities of binary mixtures of clay minerals and matrix minerals (such as illite clay + quartz) to be rapidly quantified. The templates can use ambient (room temperature) magnetic susceptibility data from measurements on core samples or drill cuttings in the laboratory or at the wellsite. Furthermore, the paper shows how the templates can potentially be extended to utilize borehole magnetic susceptibility data for in situ estimations of the type and content of clay. This requires accounting for the temperature dependence of the magnetic susceptibility of paramagnetic minerals (such as illite clay), which varies with depth in a borehole. Whilst borehole magnetic susceptibility measurements are rarely part of standard well logging operations, they could be a potentially useful tool for in situ clay type and content quantification, which in turn can help predict fluid permeability.
