The present work investigates the effect of high praseodymium oxide(Pr6O11)content on the microstructure and phase formation of mullite(3Al_(2)O_(3)·2SiO_(2))precursor by means of the spark plasma sintering proce...The present work investigates the effect of high praseodymium oxide(Pr6O11)content on the microstructure and phase formation of mullite(3Al_(2)O_(3)·2SiO_(2))precursor by means of the spark plasma sintering process.30 wt%Pr6O11was added to a mullite precursor consisting of aluminum nitrate nonahydrate and tetraethyl orthosilicate through a high energy mixer mill in ethanol media.The spark plasma sintering was performed at a te mperature of 1200℃under 23 Pa vacuum co nditions by applying initial and final pressure of 10 and 30 MPa,respectively.XRD analysis confirms the existence of mullite,alumina,Pr6O11,Pr2O3and quartz as the only crystalline phases.FESEM images reveal an interesting deposition of hexagonal-shaped Al_(2)O_(3)particles on polished surfaces and complex oxide phases of the fiber network adhering to alumina particles in the form of tails seen on the fracture surfaces.Moreover,the bending strength of 213±21 MPa,Vickers hardness of 9.3±0.1 MPa and fracture toughness of6.21±0.12 MPa·m1/2are obtained for the prepared composite.展开更多
文摘The present work investigates the effect of high praseodymium oxide(Pr6O11)content on the microstructure and phase formation of mullite(3Al_(2)O_(3)·2SiO_(2))precursor by means of the spark plasma sintering process.30 wt%Pr6O11was added to a mullite precursor consisting of aluminum nitrate nonahydrate and tetraethyl orthosilicate through a high energy mixer mill in ethanol media.The spark plasma sintering was performed at a te mperature of 1200℃under 23 Pa vacuum co nditions by applying initial and final pressure of 10 and 30 MPa,respectively.XRD analysis confirms the existence of mullite,alumina,Pr6O11,Pr2O3and quartz as the only crystalline phases.FESEM images reveal an interesting deposition of hexagonal-shaped Al_(2)O_(3)particles on polished surfaces and complex oxide phases of the fiber network adhering to alumina particles in the form of tails seen on the fracture surfaces.Moreover,the bending strength of 213±21 MPa,Vickers hardness of 9.3±0.1 MPa and fracture toughness of6.21±0.12 MPa·m1/2are obtained for the prepared composite.
