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不对称C―H/C―H交叉脱氢偶联反应研究进展
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作者 李天宇 吴丹清 +2 位作者 刘佳俊 徐大振 苗志伟 《大学化学》 CAS 2023年第12期165-180,共16页
近年来交叉脱氢偶联(CDC)反应在有机合成化学领域受到广泛关注,该策略在构建碳-碳键的反应中避免了底物的预官能团化,具有很高的原子经济性,符合绿色化学的发展要求。通过不对称CDC反应可以实现立体选择性构建碳-碳键,是目前有机合成中... 近年来交叉脱氢偶联(CDC)反应在有机合成化学领域受到广泛关注,该策略在构建碳-碳键的反应中避免了底物的预官能团化,具有很高的原子经济性,符合绿色化学的发展要求。通过不对称CDC反应可以实现立体选择性构建碳-碳键,是目前有机合成中的热点研究领域。本文综述了不对称CDC反应研究进展,并对该领域未来的发展方向进行了展望。 展开更多
关键词 不对称催化 绿色化学 碳-氢键活化 碳-碳键构筑 研究进展
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Using Mirror Migration of OBS Data to Image the Deepwater Area of South China Sea
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作者 Siyou Tong Chuanxi Sun +2 位作者 Linwei Li dazhen xu Jie Wang 《Journal of Earth Science》 SCIE CAS CSCD 2018年第3期662-668,共7页
Ocean bottom seismograph (OBS) is widely used in investigating deep crustal structure, which is characterized by a large amount of data information and abundant frequency components because of its multi-component ac... Ocean bottom seismograph (OBS) is widely used in investigating deep crustal structure, which is characterized by a large amount of data information and abundant frequency components because of its multi-component acquisition. OBS is seldom used in deepwater oil and gas exploration and basin research due to the high cost. The complicated seismic wave field is caused by the complex seabed topography, basin and oil and gas structure in deepwater area, which increases the difficulty of image processing. In addition to reflection imaging, we utilize the multiple of OBS data to make accurate imaging and have achieved desirable results in a deep sea area in South China Sea in this paper. Firstly, the original P and Z components of OBS data are processed by wave field separation to obtain the upgoing wave filed and downgoing wave filed. Secondly, its image velocity filed is constructed. Finally, downgoing wave data is used to image (called mirror migration). Compared with conventional migration, the mirror migration can clearly image the seabed and provide better illumination for shallow layer below the seafloor in the case of sparse nodes, which is proved by the migration results of theoretical and real data in this paper. 展开更多
关键词 deepwater OBS data mirroring migration wave field separation.
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