AIMTo determine the surgically induced astigmatism (SIA) in Straight, Frown and Inverted V shape (Chevron) incisions in manual small incision cataract surgery (SICS).
Afailure is a setback that has left scars. When it doesn't scar you, setbacks are learning experiences, but there's no doubt that suffering a setback is difficult. It only turns into an opportunity if you have the p...Afailure is a setback that has left scars. When it doesn't scar you, setbacks are learning experiences, but there's no doubt that suffering a setback is difficult. It only turns into an opportunity if you have the psychological tools that protect you from failure.展开更多
It is well known that massage therapists often develop a number of health problems relatively early on in their career. A preliminary study showed that grounding massage therapists during their work may alleviate some...It is well known that massage therapists often develop a number of health problems relatively early on in their career. A preliminary study showed that grounding massage therapists during their work may alleviate some of the health problems they encounter. A doubled-blind randomized controlled trial was designed to examine the effects of working and sleeping grounded for 4 weeks on massage therapists’ blood viscosity, stress (through HRV), inflammation (IFN-γ, IL-6, TNF-α, and hsCRP) and oxidative stress (MPO and MDA) biomarkers. The results show stress reduction as measured by heart rate, respir-atory rate and hear rate variability (HRV) and a lowering effect on blood viscosity that lasted for at least one week after ungrounding, with systolic blood viscosity becoming significantly lower at the end of the study. Inflammation markers (IFN-γ, TNF-α, and hsCRP) increased rapidly, within one week, after ungrounding. The findings suggest that grounding is beneficial for massage therapists in multiple domains relevant to health and wellbeing.展开更多
The crystal and molecular structure of 2-Amino-3-ethyl carboxamido-4-methyl-5-carboxy ethyl thiophene (C11H16N2O3S) has been investigated from single crystal X-ray diffraction data. The primary focus is to investigate...The crystal and molecular structure of 2-Amino-3-ethyl carboxamido-4-methyl-5-carboxy ethyl thiophene (C11H16N2O3S) has been investigated from single crystal X-ray diffraction data. The primary focus is to investigate the molecular geometry of this compound in the solid state along with the associated inter and intra-molecular hydrogen bonding and related weak interactions present in this molecule. This compound crystallizes in the monoclinic space group P21/c with cell parameters, a = 8.1344(3) , b = 13.7392(4) , c = 11.4704(4) , β = 100.769(2), V = 1259.36 (7) 3, D = 1.352 g·cm–3, Z = 4. The molecular geometry is stabilized by intra-molecular N-H…O=C and C-H…O interactions along with intramolecular C-H…N and C-H…O interactions which contribute towards the stability of the crystal packing.展开更多
In the current study, two novel Knoevenagel condensation products of substituted napthofuran-2-carbaldehydes were designed, synthesized and characterized. In order to study the intermolecular interactions of titl...In the current study, two novel Knoevenagel condensation products of substituted napthofuran-2-carbaldehydes were designed, synthesized and characterized. In order to study the intermolecular interactions of title compounds, single crystals were grown by slow evaporation solution growth technique at </span><span style="font-family:Verdana;">r</span><span style="font-family:Verdana;">oom temperature and crystal structure has been determined by single crystal X-ray diffraction technique. Both the molecule</span><span style="font-family:Verdana;">s</span><span style="font-family:""><span style="font-family:Verdana;"> crystallize in the monoclinic centrosymmetric space group </span><i><span style="font-family:Verdana;">P</span></i><span style="font-family:Verdana;">2</span><sub><span style="font-size:12px;font-family:Verdana;">1</span></sub><span style="font-family:Verdana;">/</span><i><span style="font-family:Verdana;">c</span></i><span style="font-family:Verdana;"> with one molecule in the asymmetric unit. In compound </span><b><span style="font-family:Verdana;">[4] </span></b><span style="font-family:Verdana;">the molecules are connected via bifurcated C-H···O=C and C-H···N=C</span></span><span style="font-family:Verdana;"> </span><span style="font-family:""><span style="font-family:Verdana;">H-bonds and van der Waals interactions forming a layered structure, whereas in compound </span><b><span style="font-family:Verdana;">[5a</span></b></span><span style="font-family:Verdana;"><b>]</b></span><span style="font-family:""><span style="font-family:Verdana;"> the molecular conformation is stabilized via intramolecular C-H···O H-bond and molecule interacts with other molecule generated via 2</span><sub><span style="font-size:12px;font-family:Verdana;">1</span></sub><span style="font-family:Verdana;">-screw </span><i><span style="font-family:Verdana;">via</span></i><span style="font-family:Verdana;"> bifurcated C-H···O=</span></span><span style="font-family:Verdana;">C along with C-H···N=C H-bonds, which are interacting with nitro- of ot</span><span style="font-family:Verdana;">her molecule generated via same symmetry operation, forming bifurcated C-H···O-N </span><span style="font-family:Verdana;">H-bonds, which helps in formation of molecular sheet-like structure.</span><span style="font-family:Verdana;">Further, in order to understand the various type</span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;"> and nature of intermolecular interactions</span><span style="font-family:Verdana;"> in the supramolecular structure Hirshfeld</span><span style="font-family:Verdana;"> surface analysis</span><span style="font-family:Verdana;"> and fingerprint plot analysis was carried out.展开更多
文摘AIMTo determine the surgically induced astigmatism (SIA) in Straight, Frown and Inverted V shape (Chevron) incisions in manual small incision cataract surgery (SICS).
文摘Afailure is a setback that has left scars. When it doesn't scar you, setbacks are learning experiences, but there's no doubt that suffering a setback is difficult. It only turns into an opportunity if you have the psychological tools that protect you from failure.
文摘It is well known that massage therapists often develop a number of health problems relatively early on in their career. A preliminary study showed that grounding massage therapists during their work may alleviate some of the health problems they encounter. A doubled-blind randomized controlled trial was designed to examine the effects of working and sleeping grounded for 4 weeks on massage therapists’ blood viscosity, stress (through HRV), inflammation (IFN-γ, IL-6, TNF-α, and hsCRP) and oxidative stress (MPO and MDA) biomarkers. The results show stress reduction as measured by heart rate, respir-atory rate and hear rate variability (HRV) and a lowering effect on blood viscosity that lasted for at least one week after ungrounding, with systolic blood viscosity becoming significantly lower at the end of the study. Inflammation markers (IFN-γ, TNF-α, and hsCRP) increased rapidly, within one week, after ungrounding. The findings suggest that grounding is beneficial for massage therapists in multiple domains relevant to health and wellbeing.
文摘The crystal and molecular structure of 2-Amino-3-ethyl carboxamido-4-methyl-5-carboxy ethyl thiophene (C11H16N2O3S) has been investigated from single crystal X-ray diffraction data. The primary focus is to investigate the molecular geometry of this compound in the solid state along with the associated inter and intra-molecular hydrogen bonding and related weak interactions present in this molecule. This compound crystallizes in the monoclinic space group P21/c with cell parameters, a = 8.1344(3) , b = 13.7392(4) , c = 11.4704(4) , β = 100.769(2), V = 1259.36 (7) 3, D = 1.352 g·cm–3, Z = 4. The molecular geometry is stabilized by intra-molecular N-H…O=C and C-H…O interactions along with intramolecular C-H…N and C-H…O interactions which contribute towards the stability of the crystal packing.
文摘In the current study, two novel Knoevenagel condensation products of substituted napthofuran-2-carbaldehydes were designed, synthesized and characterized. In order to study the intermolecular interactions of title compounds, single crystals were grown by slow evaporation solution growth technique at </span><span style="font-family:Verdana;">r</span><span style="font-family:Verdana;">oom temperature and crystal structure has been determined by single crystal X-ray diffraction technique. Both the molecule</span><span style="font-family:Verdana;">s</span><span style="font-family:""><span style="font-family:Verdana;"> crystallize in the monoclinic centrosymmetric space group </span><i><span style="font-family:Verdana;">P</span></i><span style="font-family:Verdana;">2</span><sub><span style="font-size:12px;font-family:Verdana;">1</span></sub><span style="font-family:Verdana;">/</span><i><span style="font-family:Verdana;">c</span></i><span style="font-family:Verdana;"> with one molecule in the asymmetric unit. In compound </span><b><span style="font-family:Verdana;">[4] </span></b><span style="font-family:Verdana;">the molecules are connected via bifurcated C-H···O=C and C-H···N=C</span></span><span style="font-family:Verdana;"> </span><span style="font-family:""><span style="font-family:Verdana;">H-bonds and van der Waals interactions forming a layered structure, whereas in compound </span><b><span style="font-family:Verdana;">[5a</span></b></span><span style="font-family:Verdana;"><b>]</b></span><span style="font-family:""><span style="font-family:Verdana;"> the molecular conformation is stabilized via intramolecular C-H···O H-bond and molecule interacts with other molecule generated via 2</span><sub><span style="font-size:12px;font-family:Verdana;">1</span></sub><span style="font-family:Verdana;">-screw </span><i><span style="font-family:Verdana;">via</span></i><span style="font-family:Verdana;"> bifurcated C-H···O=</span></span><span style="font-family:Verdana;">C along with C-H···N=C H-bonds, which are interacting with nitro- of ot</span><span style="font-family:Verdana;">her molecule generated via same symmetry operation, forming bifurcated C-H···O-N </span><span style="font-family:Verdana;">H-bonds, which helps in formation of molecular sheet-like structure.</span><span style="font-family:Verdana;">Further, in order to understand the various type</span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;"> and nature of intermolecular interactions</span><span style="font-family:Verdana;"> in the supramolecular structure Hirshfeld</span><span style="font-family:Verdana;"> surface analysis</span><span style="font-family:Verdana;"> and fingerprint plot analysis was carried out.