Perylene Bisimides as efficient electron transport layers in planar heterojunction perovskite solar cells

Two perylene bisimides based non-fullerene small molecules, H-DIPBI and B-DIPBI, are applied into inverted planar heterojunction perovskite solar cells. The power conversion efficiency up to 11.6% has been achieved for device with B-DIPBI,indicating that non-fullerene acceptor can function as the electron transport layer to replace PCBM in perovskite solar cells.

Population spatialization with pixel-level attribute grading by considering scale mismatch issue in regression modeling

Population spatialization is widely used for spatially downscaling census population data to finer-scale.The core idea of modern population spatialization is to establish the association between ancillary data and population at the administrative-unit-level(AUlevel)and transfer it to generate the gridded population.However,the statistical characteristic of attributes at the pixel-level differs from that at the AU-level,thus leading to prediction bias via the cross-scale modeling(i.e.scale mismatch problem).In addition,integrating multi-source data simply as covariates may underutilize spatial semantics,and lead to incorrect population disaggregation;while neglecting the spatial autocorrelation of population generates excessively heterogeneous population distribution that contradicts to real-world situation.To address the scale mismatch in downscaling,this paper proposes a Cross-Scale Feature Construction(CSFC)method.More specifically,by grading pixel-level attributes,we construct the feature vector of pixel grade proportions to narrow the scale differences in feature representation between AU-level and pixel-level.Meanwhile,fine-grained building patch and mobile positioning data are utilized to adjust the population weighting layer generated from POI-density-based regression modeling.Spatial filtering is furtherly adopted to model the spatial autocorrelation effect of population and reduce the heterogeneity in population caused by pixel-level attribute discretization.Through the comparison with traditional feature construction method and the ablation experiments,the results demonstrate significant accuracy improvements in population spatialization and verify the effectiveness of weight correction steps.Furthermore,accuracy comparisons with WorldPop and GPW datasets quantitatively illustrate the advantages of the proposed method in fine-scale population spatialization.