By using the home-made femtosecond laser system and the time-of-flight mass spectrometer, the decay dynamics of excited carbon disulfide (CS2) and ammonia (NH3) are investigated in real time by pump-probe mul-tiphoton...By using the home-made femtosecond laser system and the time-of-flight mass spectrometer, the decay dynamics of excited carbon disulfide (CS2) and ammonia (NH3) are investigated in real time by pump-probe mul-tiphoton ionization detection. The estimated lifetime constantof the NH3 A1A2 state (51±4 fs) agreed quite well with the literature report. For the first time, the decay lifetime constants of the NH3 E’1A’1, state (937±93 fs), the CS2 a3A2 state (153±10 fs), and the CS2 Rydberg state[3/2](3IIg) (948±23 fs) are obtained.展开更多
基金This work was supported by the NationalKey Basic Research Special Foundation of China (Grant No. G1999075300) the National Natural Science Foundation of China (Grant Nos. 29833080, 20003012 and 29973044).
文摘By using the home-made femtosecond laser system and the time-of-flight mass spectrometer, the decay dynamics of excited carbon disulfide (CS2) and ammonia (NH3) are investigated in real time by pump-probe mul-tiphoton ionization detection. The estimated lifetime constantof the NH3 A1A2 state (51±4 fs) agreed quite well with the literature report. For the first time, the decay lifetime constants of the NH3 E’1A’1, state (937±93 fs), the CS2 a3A2 state (153±10 fs), and the CS2 Rydberg state[3/2](3IIg) (948±23 fs) are obtained.
