We have developed a facile strategy to fabricate model multicolor hydrogels via a straightforward mixing process of poly acrylonitrile-grafted methacrylamide(PANMAM),polymethacrylic acid(PMAA)and doped lanthanide(Eu/T...We have developed a facile strategy to fabricate model multicolor hydrogels via a straightforward mixing process of poly acrylonitrile-grafted methacrylamide(PANMAM),polymethacrylic acid(PMAA)and doped lanthanide(Eu/Tb)and zinc ions to form the interpenetrating dual-polymer gel networks.The hydrogels exhibit excellent tunability of multi-spectrum emission colors(including white light)by simply varying the stoichiometry of metal ions.Furthermore,taking the advantage of different metal ion response mechanisms,we have demonstrated the reversible acidity/alkalinity stimuli-responsive behaviors of white-light-emitting hydrogel(WLE gel).Meanwhile,the unique cross-linked network formed through hydrogen-bonding,metal-ligand coordination and ionic interaction is introduced to achieve favorable mechanical strength of hydrogels.These properties enable the possibility in obtaining fluorescent patterns on hydrogels,which are promising candidate for encrypted information with improved security.展开更多
We demonstrate a straightforward and efficient method for the creation of polymer brushes on hydrogen-terminated silicon substrates through the UV-induced photopoiymerization. The surface grafting polymerization is ap...We demonstrate a straightforward and efficient method for the creation of polymer brushes on hydrogen-terminated silicon substrates through the UV-induced photopoiymerization. The surface grafting polymerization is applicable to a series of monomers, allowing the direct formation of homogeneous polymer coatings ranging from hydrophilic poly（2-isopropenyl-2-oxazoline） （PIPOx）, amphiphilic poly（N-isopropyl acrylamide） （PNIPAM）, to hydrophobic polystyrene （PS） and poly（4- （1H,1H,2H,2H-perfiuorohexyl）oxymethylstyrene） （PPHMS） on Si（100） and Si（lll） surfaces via stable Si--C bonds. Polymerization kinetic investigation indicates a linear increase of polymer layer thickness with the polymerization time. Moreover, the as-prepared polymer brushes exhibit superior stability against basic conditions in contrast to those that were formed on silicon substrates via conventional Si--O--C bond.展开更多
基金The financial support of this work by the National Natural Science Foundation of China(No.51973026)the Jilin Provincial Education Departments(No.JJKH20201169KJ)。
文摘We have developed a facile strategy to fabricate model multicolor hydrogels via a straightforward mixing process of poly acrylonitrile-grafted methacrylamide(PANMAM),polymethacrylic acid(PMAA)and doped lanthanide(Eu/Tb)and zinc ions to form the interpenetrating dual-polymer gel networks.The hydrogels exhibit excellent tunability of multi-spectrum emission colors(including white light)by simply varying the stoichiometry of metal ions.Furthermore,taking the advantage of different metal ion response mechanisms,we have demonstrated the reversible acidity/alkalinity stimuli-responsive behaviors of white-light-emitting hydrogel(WLE gel).Meanwhile,the unique cross-linked network formed through hydrogen-bonding,metal-ligand coordination and ionic interaction is introduced to achieve favorable mechanical strength of hydrogels.These properties enable the possibility in obtaining fluorescent patterns on hydrogels,which are promising candidate for encrypted information with improved security.
基金the support of Jilin Provincial Department of Education (No. 2014511)Department of Changchun Science and Technology(No. 14KP023)Department of Science and Technology of Jiangsu Province(No. BK20151189)
文摘We demonstrate a straightforward and efficient method for the creation of polymer brushes on hydrogen-terminated silicon substrates through the UV-induced photopoiymerization. The surface grafting polymerization is applicable to a series of monomers, allowing the direct formation of homogeneous polymer coatings ranging from hydrophilic poly（2-isopropenyl-2-oxazoline） （PIPOx）, amphiphilic poly（N-isopropyl acrylamide） （PNIPAM）, to hydrophobic polystyrene （PS） and poly（4- （1H,1H,2H,2H-perfiuorohexyl）oxymethylstyrene） （PPHMS） on Si（100） and Si（lll） surfaces via stable Si--C bonds. Polymerization kinetic investigation indicates a linear increase of polymer layer thickness with the polymerization time. Moreover, the as-prepared polymer brushes exhibit superior stability against basic conditions in contrast to those that were formed on silicon substrates via conventional Si--O--C bond.
