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Thermo-Stability of Natural Products Based on Chlorophyll Species Embedded in Silica Xerogel
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作者 José Martínez-Mendoza Erika espericueta-gonzález +2 位作者 diana espericueta gonzález Gerardo Ortega-Zarzosa Azdrubal Lobo Guerrero 《American Journal of Analytical Chemistry》 2016年第4期356-362,共7页
This work studied the thermostability and the biostability of chlorophyll species obtained from an extract of spinach leaves embedded in a silica xerogel matrix. The analysis was done by monitoring the photosystem II ... This work studied the thermostability and the biostability of chlorophyll species obtained from an extract of spinach leaves embedded in a silica xerogel matrix. The analysis was done by monitoring the photosystem II (PSII) using fluorescence spectroscopy. Samples were prepared using the sol gel method with a molar ratio of ethanol/H<sub>2</sub>O/TEOS of 4:11.6:1. Then, silica xerogel matrix was loaded with an extract of spinach leaves, obtained in dark conditions. The measurement of the fluorescence spectra was done at selected temperatures to the corresponding non-physiological regimen. Results indicate that the PSII band position remains unchanged when heat treatment temperature increases up 200&deg;C. For temperatures above 100?C, the fluorescence intensity diminishes linearly when the temperature increases. The photosystem II embedded in silica xerogel matrix is decomposed at temperatures above 200&deg;C. 展开更多
关键词 CHLOROPHYLL Structure BIOSTABILITY SOL-GEL
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