Metal-organic frameworks(MOFs)derived composites are extremely potential electromagnetic wave(EMW)absorbers.However,the permittivity of absorbers directly derived from MOFs with solid structure is usually relatively l...Metal-organic frameworks(MOFs)derived composites are extremely potential electromagnetic wave(EMW)absorbers.However,the permittivity of absorbers directly derived from MOFs with solid structure is usually relatively low,inevitably limiting their further applications.Cation substitution can primely overcome the problem by regulating the morphology and atomic space occupation to enhance multiple loss mechanisms and impedance matching characteristics.However,universal mechanisms of the effect on EMW absorption performance influenced by cation substitution are still comparatively inadequate,which prospectively requires further exploration.Herein,a series of imidazolic MOFs were fabricated by ultrasonic symbiosis method and tailored by subsequent cation substitution strategy to prepare target porous composites.At a low filling rate and thin thickness,the as-obtained samples reach the optimal reflection loss and effective absorption bandwidth values of–49.81 dB and 7.63 GHz,respectively.The intercoupling between multiple atoms lays a significant foundation for abundant heterogeneous interfaces and defect vacancies,which effectively ameliorate the attenuation mechanisms.Meanwhile,the porous structure introduced by cation substitution reduces the bulk density to enhance the impedance matching and multiple reflections simultaneously.This study provides a helpful idea to exceedingly improve the EMW absorbing performance of imidazolic MOFs-derived composites by cation substitution.展开更多
基于多期RTK-GPS(Real Time Kinematic-Global Position System)高精度测量数据,通过冰面高程变化开展北极Austre Lovénbreen冰川物质变化研究。首先基于冰面GPS测点开展多种空间插值方法的比对,兼顾冰面DEM(Digital Elevation Mod...基于多期RTK-GPS(Real Time Kinematic-Global Position System)高精度测量数据,通过冰面高程变化开展北极Austre Lovénbreen冰川物质变化研究。首先基于冰面GPS测点开展多种空间插值方法的比对,兼顾冰面DEM(Digital Elevation Model)的平滑特性以及插值结果的准确性,优选自然邻域法作为冰面地形的插值算法;继而利用2013—2015年3期RTK-GPS数据,通过冰面地形内插和测线交叉点比对两种方式开展了Austre Lovénbreen冰川表面高程变化的分析,结果表明交叉点方法的精度更高,而地形内插法在测线之间的空白区域存在较大误差。最后通过冰雪密度估计将高程变化转化为水当量,计算相应时段的冰川物质平衡:积累区密度取500 kg·m^-3,消融区密度取900 kg·m^-3,得到2013—2014年和2014—2015年的物质平衡分别为–0.277m w.e.和0.065m w.e.。该物质平衡结果相较于传统的冰面物质平衡而言存在一定的差异,主要源于测量时段的不一致,以及可能存在的冰川内部物质变化。此外,将RTK-GPS交叉点高程的年际变化与所在高程进行联合分析,发现冰川物质变化与冰川高程分布既有较强的相关性,部分区域也存在一些差异。总体而言,冰川物质年变化的海拔梯度为2.67‰,在海拔越低的区域冰川消融得越快,随海拔上升消融减慢,在高海拔或冰川边缘区域还存在少量物质积累。展开更多
基金supported by the Natural Science Foundation of Sichuan Province(No.2023NSFSC0435)Sichuan Agricultural University College Student Innovation Training Program Project Funding(No.202210626019)Sichuan Agricultural University double support(035–2221993150).
文摘Metal-organic frameworks(MOFs)derived composites are extremely potential electromagnetic wave(EMW)absorbers.However,the permittivity of absorbers directly derived from MOFs with solid structure is usually relatively low,inevitably limiting their further applications.Cation substitution can primely overcome the problem by regulating the morphology and atomic space occupation to enhance multiple loss mechanisms and impedance matching characteristics.However,universal mechanisms of the effect on EMW absorption performance influenced by cation substitution are still comparatively inadequate,which prospectively requires further exploration.Herein,a series of imidazolic MOFs were fabricated by ultrasonic symbiosis method and tailored by subsequent cation substitution strategy to prepare target porous composites.At a low filling rate and thin thickness,the as-obtained samples reach the optimal reflection loss and effective absorption bandwidth values of–49.81 dB and 7.63 GHz,respectively.The intercoupling between multiple atoms lays a significant foundation for abundant heterogeneous interfaces and defect vacancies,which effectively ameliorate the attenuation mechanisms.Meanwhile,the porous structure introduced by cation substitution reduces the bulk density to enhance the impedance matching and multiple reflections simultaneously.This study provides a helpful idea to exceedingly improve the EMW absorbing performance of imidazolic MOFs-derived composites by cation substitution.
