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Ultrafast synthesis of cobalt/carbon nanocomposites by magnetic induction heating for oxygen evolution reaction
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作者 Qiming Liu Samuel McNair +7 位作者 Forrest Nichols Bingzhang Lu Bingzhe Yu dingjie pan Jamie Ko Amrinder Bhuller Frank Bridges Shaowei Chen 《Advanced Sensor and Energy Materials》 2023年第1期14-23,共10页
Metal/carbon nanocomposites have shown great potential as high-performance,low-cost electrocatalysts owing largely to their unique metal-support interactions.These nanocomposites are typically prepared by conventional... Metal/carbon nanocomposites have shown great potential as high-performance,low-cost electrocatalysts owing largely to their unique metal-support interactions.These nanocomposites are typically prepared by conventional pyrolysis that is tedious and energy-intensive.Herein,we report the ultrafast preparation of cobalt/carbon nanocomposites by magnetic induction heating(MIH)of metal organic frameworks within seconds under an inert atmosphere.The resulting samples consist of cobalt nanoparticles encapsulated within defective carbon shells,and effectively catalyze oxygen evolution reaction(OER)in alkaline media.Among the series,the sample prepared at 400 A for 10 s exhibits the best OER performance,needing a low overpotential of+308 mV to reach the current density of 10 mA cm^(−2),along with excellent stability,and even outperforms commercial RuO_(2) at high overpotentials.This is ascribed to the charge transfer between the carbon scaffold and metal nanoparticles.Operando X-ray absorption spectroscopy measurements show that the electrochemically produced CoOOH species is responsible for the high electrocatalytic performance.The results highlight the unique potential of MIH in the development of effective nanocomposite catalysts for electrochemical energy technologies. 展开更多
关键词 Magnetic induction heating Electrocatalysis Oxygen evolution reaction Cobalt/carbon nanocomposite Operando X-ray spectroscopy
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Electrochemical top-down synthesis of C-supported Pt nanoparticles with controllable shape and size:Mechanistic insights and application 被引量:2
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作者 Batyr Garlyyev Sebastian Watzele +10 位作者 Johannes Fichtner Jan Michalicka Alexander Schokel Anatoliy Senyshyn Andrea Perego dingjie pan Hany A.El-Sayed Jan M.Macak Plamen Atanassov Iryna V.Zenyuk Aliaksandr S.Bandarenka 《Nano Research》 SCIE EI CSCD 2021年第8期2762-2769,共8页
In this work,we demonstrate the power of a simple top-down electrochemical erosion approach to obtain Pt nanoparticle with controlled shapes and sizes(in the range from-2 to-10 nm).Carbon supported nanoparticles with ... In this work,we demonstrate the power of a simple top-down electrochemical erosion approach to obtain Pt nanoparticle with controlled shapes and sizes(in the range from-2 to-10 nm).Carbon supported nanoparticles with narrow size distributions have been synthesized by applying an alternating voltage to macroscopic bulk platinum structures,such as disks or wires.Without using any surfactants,the size and shape of the particles can be changed by adjusting simple parameters such as the applied potential,frequency and electrolyte composition.For instance,application of a sinusoidal AC voltage with lower frequencies results in cubic nanoparticles;whereas higher frequencies lead to predominantly spherical nanoparticles.On the other hand,the amplitude of the,sinusoidal signal was found to affect the particle size;the lower the amplitude of the applied AC signal,the smaller the resulting particle size.Pt/C catalysts prepared by this approach showed 0.76 A/mg mass activity towards the oxygen reduction reaction which is-2 times higher than the state-of-the-art commercial Pt/C catalyst(0.42 A/mg)from Tanaka.In addition to this,we discussed the mechanistic insights about the nanoparticle formation pathways. 展开更多
关键词 electrochemical synthesis PLATINUM nanoparticles oxygen reduction reaction
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