Two new triterpenoid saponins were isolated from the roots ofRhaponticum uniflorum. Their structures were elucidated as 3-O- [β-D-glucopyranosyl]-ilexolic acid-28-O-[β-D-glucopyranosyl] ester 1 and 3-O-[β-D-glucopy...Two new triterpenoid saponins were isolated from the roots ofRhaponticum uniflorum. Their structures were elucidated as 3-O- [β-D-glucopyranosyl]-ilexolic acid-28-O-[β-D-glucopyranosyl] ester 1 and 3-O-[β-D-glucopyranosyl]-urs-12, 19 （29）-dien-oic acid-28-O-[β-b-glucopyranosyl] ester 2 mainly by 1D, 2D NMR techniques and chemical methods.展开更多
s: The convenient synthesis of (-)-5αH.7β 10α-eudesmane-3. 11-dielle 1 has been achieved in four steps starting from R-(-)-carvone. The key step is the reductive deoxygenation of α,β-unsaturated tosylhydrazone to...s: The convenient synthesis of (-)-5αH.7β 10α-eudesmane-3. 11-dielle 1 has been achieved in four steps starting from R-(-)-carvone. The key step is the reductive deoxygenation of α,β-unsaturated tosylhydrazone together with the migration of the double bond.展开更多
基金supported by the Education Bureau of Fujian Province(No.JS06025)National Natural Sciences Foundation of China(No.29772010)
文摘Two new triterpenoid saponins were isolated from the roots ofRhaponticum uniflorum. Their structures were elucidated as 3-O- [β-D-glucopyranosyl]-ilexolic acid-28-O-[β-D-glucopyranosyl] ester 1 and 3-O-[β-D-glucopyranosyl]-urs-12, 19 （29）-dien-oic acid-28-O-[β-b-glucopyranosyl] ester 2 mainly by 1D, 2D NMR techniques and chemical methods.
文摘s: The convenient synthesis of (-)-5αH.7β 10α-eudesmane-3. 11-dielle 1 has been achieved in four steps starting from R-(-)-carvone. The key step is the reductive deoxygenation of α,β-unsaturated tosylhydrazone together with the migration of the double bond.
