A novel micro-hole electrode was fabricated to investigate the electron transfer reaction at the interface between two immiscible electrolyte solutions (ITIES). The electron transfer reaction between ferro/ferricyani...A novel micro-hole electrode was fabricated to investigate the electron transfer reaction at the interface between two immiscible electrolyte solutions (ITIES). The electron transfer reaction between ferro/ferricyanide in aqueous phase (W) and ferrocene in 1, 2-dichloroethane (O) phase was studied as a test experiment. The results showed that the diffusion coefficient obtained from the micro-hole electrode was consistent with that obtained at macro-interface. Due to its simplicity and the very small IR drop it will be a useful tool for the study of ITIES systems.展开更多
Here we report a novel generation/collection operation mode of scanning electrochemical microscopy,in which a theta micropipette was employed to support two adjacent water/1,2-dichloroethane interfaces separated by th...Here we report a novel generation/collection operation mode of scanning electrochemical microscopy,in which a theta micropipette was employed to support two adjacent water/1,2-dichloroethane interfaces separated by the thin central glass wall：one acts as the generator while the other as the collector.The generation current,collection current and collection efficiency were enhanced significantly when the tip approached to an insulate substrate.展开更多
文摘A novel micro-hole electrode was fabricated to investigate the electron transfer reaction at the interface between two immiscible electrolyte solutions (ITIES). The electron transfer reaction between ferro/ferricyanide in aqueous phase (W) and ferrocene in 1, 2-dichloroethane (O) phase was studied as a test experiment. The results showed that the diffusion coefficient obtained from the micro-hole electrode was consistent with that obtained at macro-interface. Due to its simplicity and the very small IR drop it will be a useful tool for the study of ITIES systems.
基金supported by the National Natural Science Foundation of China(No.20973142)the NSFC Innovation Group of Interfacial Electrochemistry(No.21021002)National Project 985 of High Education,New Faculty Starting Package of Xiamen University
文摘Here we report a novel generation/collection operation mode of scanning electrochemical microscopy,in which a theta micropipette was employed to support two adjacent water/1,2-dichloroethane interfaces separated by the thin central glass wall：one acts as the generator while the other as the collector.The generation current,collection current and collection efficiency were enhanced significantly when the tip approached to an insulate substrate.
