Recently,a report from Elite Readers suggested that a strange phenomenon of ’square-shaped waves’ had occurred at the beaches of the Isle of Rhe in the Bay of Biscay.Based on the hydrological and geological data of ...Recently,a report from Elite Readers suggested that a strange phenomenon of ’square-shaped waves’ had occurred at the beaches of the Isle of Rhe in the Bay of Biscay.Based on the hydrological and geological data of the Bay of Biscay,we find that the special phenomenon is closely related to a solitary wave that can be described by the shallow water wave equation.We discuss the formation mechanisms of the square-shaped waves by the Kadomtsev-Petviashvili equation.The combination of exact solutions and actual condition provides the simulated initial state.We then reproduce a square-shaped structure by a numerical method and obtain the result consistent with the observed picture from media.Our work enriches public understanding of strange water waves and has great significance for tourism development and shipping transportation.展开更多
Co68.15Fe4.35Si12.25B15.25 （at%） amorphous microwires with a smooth surface and a circular cross-section were fabricated by the glass-coated melt spinning method. Their mechanical properties were evaluated through t...Co68.15Fe4.35Si12.25B15.25 （at%） amorphous microwires with a smooth surface and a circular cross-section were fabricated by the glass-coated melt spinning method. Their mechanical properties were evaluated through tensile tests of the glass-coated amorphous mi-crowires, and their fracture reliability was estimated using two-and three-parameter Weibull analysis. X-ray diffraction and transmission electron microscopy results showed that these glass-coated Co-based microwires were mostly amorphous. The coated Co-based microwires exhibit a tensile strength of 1145 to 2457 MPa, with a mean value of 1727 MPa and a variance of 445 MPa. Weibull statistical analysis showed that the tensile two-parameter Weibull modulus of the amorphous microwires is 4.16 and the three-parameter Weibull modulus is 1.61 with a threshold value as high as 942 MPa. These results indicate that the fabricated microwires exhibit good tensile properties and fracture reliability, and thus appear to be good candidates for electronics reliability engineering applications.展开更多
The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way catalyst.Moreover,the surface structure of CZ plays an important role in catalytic activity of Pd.However,how to regulate th...The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way catalyst.Moreover,the surface structure of CZ plays an important role in catalytic activity of Pd.However,how to regulate the surface structure of CZ and clarify the structure–activity relationship is still a challenge.In this paper,a strategy is proposed to develop high activity Pd@CZ nanocatalysts by tuning Y doping sites in CZ.The precipitate-deposition method is developed to prepare the novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite with surface doping of Y(CZ-Y-S).In addition,the Pd@CZ-Y-S(Pd supported on CZ-Y-S)exhibits superior catalytic activity for HC,CO,and NO oxide,wherein,for CO and C_(3)H_(6) oxidation,the low-temperature activity of Pd@CZ-Y-S is still 20%higher than that of Pd@CZ-Y-B(Y bulk doping)and commercial Pd@CZ after 1000℃/4 h aging.The effect mechanism is further studied by density functional theory(DFT)calculation.Compared with Pd@CZ-Y-B,Pd@CZ-Y-S shows the lower CO oxide reaction energy barriers due to the weaker adsorption strength of O2.The Y surface doping strategy could provide valuable insights for the development of highly efficient Pd@CZ catalyst with extensive applications.展开更多
基金supported by the Science and Technology Foundation of Jiangsu Province(BK20151237)the Special Nano-technology of Suzhou(ZXG2013004)+2 种基金USTC-NSRL Association Fundingthe Collaborative Innovation Centre of Suzhou Nano Science and Technologythe Supercomputation Center of USTC
基金Supported by the National Natural Science Foundation of China under Grant Nos 11875220 and 11425522
文摘Recently,a report from Elite Readers suggested that a strange phenomenon of ’square-shaped waves’ had occurred at the beaches of the Isle of Rhe in the Bay of Biscay.Based on the hydrological and geological data of the Bay of Biscay,we find that the special phenomenon is closely related to a solitary wave that can be described by the shallow water wave equation.We discuss the formation mechanisms of the square-shaped waves by the Kadomtsev-Petviashvili equation.The combination of exact solutions and actual condition provides the simulated initial state.We then reproduce a square-shaped structure by a numerical method and obtain the result consistent with the observed picture from media.Our work enriches public understanding of strange water waves and has great significance for tourism development and shipping transportation.
基金financially supported by the National Natural Science Foundation of China(No.51371067)supported by the Japan Society for the Promotion of Science(JSPS) fellowship and Grants-in-Aid for Scientific Research(No.25-03205)
文摘Co68.15Fe4.35Si12.25B15.25 （at%） amorphous microwires with a smooth surface and a circular cross-section were fabricated by the glass-coated melt spinning method. Their mechanical properties were evaluated through tensile tests of the glass-coated amorphous mi-crowires, and their fracture reliability was estimated using two-and three-parameter Weibull analysis. X-ray diffraction and transmission electron microscopy results showed that these glass-coated Co-based microwires were mostly amorphous. The coated Co-based microwires exhibit a tensile strength of 1145 to 2457 MPa, with a mean value of 1727 MPa and a variance of 445 MPa. Weibull statistical analysis showed that the tensile two-parameter Weibull modulus of the amorphous microwires is 4.16 and the three-parameter Weibull modulus is 1.61 with a threshold value as high as 942 MPa. These results indicate that the fabricated microwires exhibit good tensile properties and fracture reliability, and thus appear to be good candidates for electronics reliability engineering applications.
基金Ⅴ. ACKN0WLEDGMENTS
This work was supported by the National Natural Science Foundation of China （No.20473078） and The Ph.D. Programs Foundation of Ministry of Education of China （No.20020358061）.
文摘B3LYP/LanL <SUB>1</SUB > MB 和 B3LYP/LanL <SUB>2</SUB > 为与为 S， C 和 H 原子的 6-31G (d) 基础集合一起的 Ag 原子的 DZ 方法被用来优化几何学并且计算精力为(SCH <SUB>3</SUB>)<SUB > m </SUB > Ag <SUB>20</SUB>(m=1-4 ) 分别地。一个单个分子的吸附精力(SCH <SUB>3</SUB>)<SUB > Ag <SUB>20</SUB> 和分子间的调停底层的相互作用精力上的 m </SUB>(m=1-4 ) 被评估。结果表明在单个分子的吸附精力和调停底层的分子间的相互作用精力之间有一种比例的关系。结果品质上证明为精力由我们以前建议了的调停底层的相互作用的半实验的表示与密度的结果一致功能的理论。
基金This study was financially supported by the National Natural Science Foundation of China(No.52204376)Youth Foundation of Hebei Province(No.E2022103007)+2 种基金Young Elite Scientists Sponsorship Program by CAST 2021QNRC001High Tech Zone Science and Technology Project of Yanjiao(No.YJXM211211)Youth Fund Project of GRINM(No.G12620223129035).
文摘The ceria-zirconia compound oxide-supported noble metal Pd(Pd@CZ)is widely used in three-way catalyst.Moreover,the surface structure of CZ plays an important role in catalytic activity of Pd.However,how to regulate the surface structure of CZ and clarify the structure–activity relationship is still a challenge.In this paper,a strategy is proposed to develop high activity Pd@CZ nanocatalysts by tuning Y doping sites in CZ.The precipitate-deposition method is developed to prepare the novel Ce_(0.485)Zr_(0.485)Y_(0.03)O_(2) composite with surface doping of Y(CZ-Y-S).In addition,the Pd@CZ-Y-S(Pd supported on CZ-Y-S)exhibits superior catalytic activity for HC,CO,and NO oxide,wherein,for CO and C_(3)H_(6) oxidation,the low-temperature activity of Pd@CZ-Y-S is still 20%higher than that of Pd@CZ-Y-B(Y bulk doping)and commercial Pd@CZ after 1000℃/4 h aging.The effect mechanism is further studied by density functional theory(DFT)calculation.Compared with Pd@CZ-Y-B,Pd@CZ-Y-S shows the lower CO oxide reaction energy barriers due to the weaker adsorption strength of O2.The Y surface doping strategy could provide valuable insights for the development of highly efficient Pd@CZ catalyst with extensive applications.
