Atomically bonding Na anodes with metallized ceramic electrolytes by ultrasound welding for high-energy/power solid-state sodium metal batteries

A solid-state sodium metal battery has cut a striking figure in next-generation large-scale energy storage technology on account of high safety,high energy density,and low cost.Nevertheless,the large interfacial resistance and sodium dendrite growth originating from the poor interface contact seriously hinder its practical application.Herein,a modified ultrasound welding was proposed to atomically bond Na anodes and Au-metalized Na_(3)Zr_(2)Si_(2)PO_(12) electrolytes associated with the in situ formation of Na–Au alloy interlayers.Thereupon,intimate Na_(3)Zr_(2)Si_(2)PO_(12)-Au/Na interfaces with a low interfacial resistance(~23Ωcm^(2))and a strong dendrite inhibition ability were constructed.The optimized Na symmetric battery can cycle steadily for more than 900 h at 0.3 mA cm^(-2) under a low overpotential(<50 mV)of Na electroplating/stripping and deliver a high critical current density of 0.8 mAcm^(-2) at room temperature.By incorporating the above interface into the solid-state Na metal battery,taking three-dimensional Na_(3)V_(2)(PO_(4))_(3) as the cathode,the full battery offers a high energy density of 291 Wh kg^(-1) at a high power density of 1860Wkg^(-1).A pouch-type solid-state sodium metal full battery based on a ceramic electrolyte was assembled for the first time,and it lit a 3 V LED lamp.Such a strategy of the ultrasound welding metalized solid-state electrolyte/Na interface by engineering the Na-Au interlayer would pave a new pathway to engineer a low-resistance and highly stable interface for high-energy/density solid-state sodium metal batteries.

Anesthetic Management of a Patient with Spinal Muscular Atrophy Type III Undergoing Emergent Caesarean Section: A Case Report

In this case report, we describe the anesthetic management for a 36-year-old G2P0010 at 36 weeks gestation with Spinal Muscular Atrophy Type III who underwent an emergent caesarean section due to fetal footling breech position. The patient is a wheelchair-bound quadriplegic with kyphoscoliosis and a lack of cough reflex who required nasal continuous noninvasive ventilatory support (CNVS) for chronic hypercapnic respiratory failure. Surgery was done under general anesthesia due to its emergent nature, and the patient was successfully extubated and transitioned to nasal CNVS in the operating room at the end of the case. Postoperative care was provided in the medical intensive care unit for three days without complication and the patient was discharged home uneventfully.

An Indoor Localization Approach Based on Fingerprint and Time-Difference of Arrival Fusion

In this paper,an effective target locating approach based on the fingerprint fusion posi-tioning(FFP)method is proposed which integrates the time-difference of arrival(TDOA)and the received signal strength according to the statistical variance of target position in the stationary 3D scenarios.The FFP method fuses the pedestrian dead reckoning(PDR)estimation to solve the moving target localization problem.We also introduce auxiliary parameters to estimate the target motion state.Subsequently,we can locate the static pedestrians and track the the moving target.For the case study,eight access stationary points are placed on a bookshelf and hypermarket;one target node is moving inside hypermarkets in 2D and 3D scenarios or stationary on the bookshelf.We compare the performance of our proposed method with existing localization algorithms such as k-nearest neighbor,weighted k-nearest neighbor,pure TDOA and fingerprinting combining Bayesian frameworks including the extended Kalman filter,unscented Kalman filter and particle fil-ter(PF).The proposed approach outperforms obviously the counterpart methodologies in terms of the root mean square error and the cumulative distribution function of localization errors,espe-cially in the 3D scenarios.Simulation results corroborate the effectiveness of our proposed approach.