Equipped with highest-energy density anode,lithium metal batteries are of great interests for the nextgeneration energy storage systems.However,the existing problems like uneven Li deposition,large volume expansion an...Equipped with highest-energy density anode,lithium metal batteries are of great interests for the nextgeneration energy storage systems.However,the existing problems like uneven Li deposition,large volume expansion and short cycling lifespan severely retard the implementation of Li metal anodes.Herein,we report an in-situ formed Cu_(x)O nanofiber network synthesized by facile and scalable calcination process and employ as stable lithium metal anode.The CuO/Cu_(2)O ratio in the lithiophilic Cu_(x)O network can be adjusted through an optimal annealing time,thus guiding the homogeneous distribution of Li atoms and regulating the repeated plating/stripping processes.As a result,Li@Cu_(x)O 3D scaffold displays an ultralow overpotential of 7.7 mV,long cycling life for more than 1000 h in symmetric cell,and exceptional stability for LiFePO_(4)//Li full cells.This work provides guidelines for the design and fabrication of lithiophilic 3D matrixes and advances the practical use of lithium metal batteries.展开更多
To address the flow imbalance rapidly of the asymmetric Electro-Hydrostatic Actuator(EHA),this paper presents a novel architecture of asymmetric EHA with the Digital Distribution(EHA-DD).It also improves the flow nonl...To address the flow imbalance rapidly of the asymmetric Electro-Hydrostatic Actuator(EHA),this paper presents a novel architecture of asymmetric EHA with the Digital Distribution(EHA-DD).It also improves the flow nonlinearity and control accuracy of the pump,especially in the low-speed condition.The digital distribution with two High-Speed on–off Valves(HSVs)not only balances flow instead of the check valves,but also replaces the pump at the low-speed to control output flow by adjusting the PWM signal.The pump and HSVs are the crucial components to control flow output.Firstly,the flow calculation models of the pump and the duty ratio inversed model of the HSV are obtained through experimental tests and the identification method.To get the control input signal for the required flow,the pump speed and PWM duty ratio for the HSVs are inversed to compensate for flow output.Further,a multimode digital flow distribution control method based on pump speed,mainly including the pump-controlled mode for large flow demand and valve-controlled mode for little flow demand,is proposed to control the accurate flow output actively.The step extension experiments based on the flow calculation models are conducted on the EHA-DD prototype under elastic,opposite varying load.The results demonstrate that the EHADD realizes little position error by accurate flow control,and it is also beneficial to improve the service life of the pump.展开更多
基金supported by the Guangdong Basic and Applied Basic Research Foundation(2019A1515012111)the Science and Technology Innovation Commission of Shenzhen(JCYJ20180507181858539 and JCYJ20190808173815205)+1 种基金the National Key R&D Program of China(2019YFB2204500)the Shenzhen Science and Technology Program(KQTD20180412181422399)。
文摘Equipped with highest-energy density anode,lithium metal batteries are of great interests for the nextgeneration energy storage systems.However,the existing problems like uneven Li deposition,large volume expansion and short cycling lifespan severely retard the implementation of Li metal anodes.Herein,we report an in-situ formed Cu_(x)O nanofiber network synthesized by facile and scalable calcination process and employ as stable lithium metal anode.The CuO/Cu_(2)O ratio in the lithiophilic Cu_(x)O network can be adjusted through an optimal annealing time,thus guiding the homogeneous distribution of Li atoms and regulating the repeated plating/stripping processes.As a result,Li@Cu_(x)O 3D scaffold displays an ultralow overpotential of 7.7 mV,long cycling life for more than 1000 h in symmetric cell,and exceptional stability for LiFePO_(4)//Li full cells.This work provides guidelines for the design and fabrication of lithiophilic 3D matrixes and advances the practical use of lithium metal batteries.
基金co-supported by the National Natural Science Foundation of China(Nos.51890811 and 51975507)the Innovation Funding for Postgraduates in Hebei Province(No.CXZZSS2019042)。
文摘To address the flow imbalance rapidly of the asymmetric Electro-Hydrostatic Actuator(EHA),this paper presents a novel architecture of asymmetric EHA with the Digital Distribution(EHA-DD).It also improves the flow nonlinearity and control accuracy of the pump,especially in the low-speed condition.The digital distribution with two High-Speed on–off Valves(HSVs)not only balances flow instead of the check valves,but also replaces the pump at the low-speed to control output flow by adjusting the PWM signal.The pump and HSVs are the crucial components to control flow output.Firstly,the flow calculation models of the pump and the duty ratio inversed model of the HSV are obtained through experimental tests and the identification method.To get the control input signal for the required flow,the pump speed and PWM duty ratio for the HSVs are inversed to compensate for flow output.Further,a multimode digital flow distribution control method based on pump speed,mainly including the pump-controlled mode for large flow demand and valve-controlled mode for little flow demand,is proposed to control the accurate flow output actively.The step extension experiments based on the flow calculation models are conducted on the EHA-DD prototype under elastic,opposite varying load.The results demonstrate that the EHADD realizes little position error by accurate flow control,and it is also beneficial to improve the service life of the pump.