Modeling of Hydrogen Blending on the Leakage and Diffusion of Urban Buried Hydrogen-Enriched Natural Gas Pipeline

With the introduction of various carbon reduction policies around the world,hydrogen energy,as a kind of clean energy with zero carbon emission,has attracted much attention.The safe and economical transportation of hydrogen is of great significance to the development of hydrogen energy industries.Utilizing natural gas pipelines to transport hydrogen is considered to be an efficient and economical way.However,hydrogen has a higher risk of leakage due to its strong diffusion capacity and lower explosive limit than conventional natural gas.Therefore,it is of great significance to study the leakage and diffusion law of hydrogen-enriched natural gas(HENG)pipelines for the safe transportation of hydrogen energy.In this study,the leakage and diffusion characteristics of urban buried HENG pipelines are investigated numerically,and the dangerous degree of leakage is analyzed based on the time and area when the gas concentration reaches the lower explosive limit.The influences of hydrogen blending ratio(HBR),operating pressure,leakage hole size and direction,as well as soil type on the leakage and diffusion law of HENG are analyzed.Results show that the hydrogen mixing is not the key factor in increasing the degree of risk after gas leakage for urban buried HENG pipelines.When the HBR is 5%,10%,15% and 20%,the corresponding first dangerous time is 1053,1041,1019 and 998 s,respectively.Thiswork is expected to provide a valuable reference for the safe operation and risk prevention of HENG pipelines in the future.

Study on a Dual Embedded Discrete Fracture Model for Fluid Flow in Fractured Porous Media

Simulation of fluid flow in the fractured porous media is very important and challenging.Researchers have developed some models for fractured porous media.With the development of related research in recent years,the prospect of embedded discrete fracture model(EDFM)is more and more bright.However,since the size of the fractures in the actual reservoir varies greatly,a very fine grid should be used which leads to a huge burden to the computing resources.To address this challenge,in the present paper,an upscaling based model is proposed.In this model,the flow in large-scale fractures is directly described by the EDFM while that in the small-scale fractures is upscaled through local simulation by EDFM.The EDFM is used to simulate the large-and small-scale fractures independently two times,so the new model is called dual embedded discrete fracture model(D-EDFM).In this paper,the detailed implementation process of D-EDFM is introduced and,through test cases,it is found the proposed model is a feasible method to simulate the flow in fractured porous media.

有限容积法离散方程截断误差本质及其来源

本文从有限容积法的原理出发,指出有限容积法离散方程截断误差的本质为离散表达式与守恒型积分方程的近似程度.基于该思想,推导了有限容积法离散方程截断误差表达式,该表达式与有限差分法截差表达式有显著的不同;并指出有限容积法中涉及的截断误差主要包含3个层次,分别为由界面上值的近似、界面通量的近似和离散方程的近似带来的截断误差.有限容积法界面通量截断误差包含法向和切向两部分,有限差分法不存在界面未知值近似和切向截断误差,因而即使对于常物性二维/三维问题,两者截差表达式也不相同.与有限差分法相比,有限容积法误差来源较多,单纯提高待求变量的离散精度并不能有效地提高离散方程的整体精度.此外,通过理论推导和数值试验证明了对于规则区域正交非均分网格,计算区域采用内节点法离散的计算精度总体上优于外节点法.

Low-content and highly effective zoned Rh and Pd three-way catalysts for gasoline particulate filter potentially meeting Euro 7

The next-generation Euro 7 standard proposed much lower pollutant limits from gasoline vehicles,specifically for CO and NO_(x),which would be challenging for the three-way catalysts(TWCs)utilized commercially to eliminate these pollutants.TWCs with reductive(Rh)and oxidative(Pd)active components on gasoline particulate filters(TWC on GPF)play importantly auxiliary roles in the remediation of CO and NO_(x)downstream the close coupled TWCs to meet their emission targets.Here,a low-content Rh-based TWC(0.17 wt%)zoned with a less expensive Pd-based TWC(0.29 wt%)for GPF applications(cGPF)is reported using improved colloidal deposition method.The supporting of Rh on Y-stabilized ZrO_(2)rather than on CeO_(2)-ZrO_(2)inhibits the formation of inactive Ce rhodate species,while Pd on CeO_(2)-ZrO_(2)not only guarantees the high oxygen storage capacity(OSC)but also enhances catalytic activity.The layout of the front one-fifth in volume being 0.29 wt%Pd on Ce_(0.43)Zr_(0.5)7O_(2)and the rear four-fifths being 0.17 wt%Rh on Zr_(0.85)Y_(0.15)O_(2)prevents the possible alloying of Rh with Pd.The highly effective zoned Rh and Pd TWCs show synergistic three-way activity before and after severe hydrothermal aging at 1000℃with 10%water for24 h,which could be potential choices for close coupled GPF application to satisfy the upcoming stringent emission standards,such as Euro 7 and China 6b.

Chinese SPRIGT realizes high temperature stability in the range of 5–25 K

The unit of thermodynamic temperature,the kelvin,is one of the seven base units of International System of Units.High accuracy measurements of thermodynamic temperature in the lowtemperature range,namely below the neon triple point at24.5561 K,are of strategic significance for the development of

Pd-Ni nanoparticles supported on titanium oxide as effective catalysts for Suzuki-Miyaura coupling reactions

We have successfully prepared a series of Pd- Ni/TiO2 catalysts by a one-step impregnation-reduction method. Among these catalysts with different compositions of Ni and Pd, the one with the Ni：Pd ratio of 2.95 showed the best activity. Small monodispersed Pd-Ni bimetallic nanoparticles were loaded on the surface of titanium oxide nanopowder as confirmed with TEM and EDS mapping. The XPS analysis demonstrated that Pd exists as 31% Pd（II） species and 69% Pd（0） species and all nickel is Ni（II）. The prepared Pd-Ni/TiO2 exhibited enhanced catalytic activity compared to an equal amount of Pd/TiO2 for Suzuki-Miyaura reactions together with excellent applicability and reusability.

A high-stability quasi-spherical resonator in SPRIGT for microwave frequency measurements at low temperatures

To meet the de ma nds of high stability and sustainable temperature measurements over time,TIPC-CAS in China and LNE-Cnam in France have jointly developed single-pressure refractive-index gas thermometiy(SPR1GT),which is expected to be an alternative primary thermometiy because of its 0.25 mK accuracy and high measurement speeds.

LncRNA-m18as1 competitively binds with miR-18a-5p to regulate follicle-stimulating hormone secretion through the Smad2/3 pathway in rat primary pituitary cells

Long noncoding RNAs(lncRNAs)are expressed in different species and different tissues,and perform different functions,but little is known about their involvement in the synthesis or secretion of follicle-stimulating hormone(FSH).In general,we have revealed lnc RNA-micro RNA(mi RNA)-messenger RNA(m RNA)interactions that may play important roles in rat primary pituitary cells.In this study,a new lncRNA was identified for the first time.First,we analyzed the gene expression of lncRNA-m18as1 in different tissues and different stages by reverse transcription-quantitative polymerase chain reaction(RT-qPCR)and observed the localization of lncRNA-m18as1 with fluorescence in situ hybridization,which indicated that this lncRNA was distributed mainly in the cytoplasm.Next,we used RT-qPCR and enzyme-linked immunosorbent assay(ELISA)to analyze the regulation of FSH synthesis and secretion after overexpression or knockdown of lncRNA-m18as1 and found that lncRNA-m18as1 was positively correlated with FSH synthesis and secretion.In addition,mothers against decapentaplegic homolog 2(Smad2)was highly expressed in our sequencing results.We also screened miR-18a-5p from our sequencing results as a miRNA that may bind to lncRNA-m18as1 and Smad2.We used RNA immunoprecipitation-qPCR(RIP-qPCR)and/or dual luciferase assays to confirm that lncRNA-m18as1 interacted with miR-18a-5p and miR-18a-5p interacted with Smad2.Fluorescence in situ hybridization(FISH)showed that lncRNA-m18as1 and miR-18a-5p were localized mainly in the cytoplasm.Finally,we determined the relationship among lncRNA-m18as1,miR-18a-5p,and the Smad2/3 pathway.Overall,we found that lncRNA-m18as1 acts as a molecular sponge of miR-18a-5p to regulate the synthesis and secretion of FSH through the Smad2/3 pathway.

Ultra-stable pressure is realized for Chinese single pressure refractive index gas thermometry in the range 30–90 kPa

The unit of thermodynamic temperature,the kelvin,is one of the seven base units of International System of Units.The international temperature scaIe of 1990 (ITS-90)is a practical temperature scale used worldwide to approximate thermodynamic tempera- ture T by ITS-90 temperature T90.The primary thermometry calibration facilities based on thermodynamic temperature standards are the foundation of ITS 90 and temperature measurement in a country.China has developed primary thermometry in the temperature region down to the neon triple point 24.5561 K estimated by ITS-90,but it has not yet set up any primary thermometry at lower temperatures.