For characteristics of open and far from thermodynamic equilibrium in welding chemical reaction, a new kind of quantitative method, which is used to analyze direction and extent for chemical reaction of SiO2/Fe during...For characteristics of open and far from thermodynamic equilibrium in welding chemical reaction, a new kind of quantitative method, which is used to analyze direction and extent for chemical reaction of SiO2/Fe during quasi-steady state period, is introduced with the concept of non-equilibrium stationary state. The main idea is based on thermodynamic driving forces, which result in non-zero thermodynamic fluxes and lead to chemical reaction far away from thermodynamic equilibrium. There exists certain dynamic equilibrium relationship between rates of diffusion fluxes in liquid phase of reactants or products and the rate equation of chemical reaction when welding is in quasi-steady state. As result of this, a group of non-linear equations containing concentrations of all substances at interface of slag/liquid-metal may be established. Moreover the stability of this non-equilibrium stationary state is discussed using dissipative structure theory and it is concluded theoretically that this non-equilibrium stationary state for welding chemical reaction is of stability.展开更多
In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The result...In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The results indicate that AAMP can notably reduce the diffusible hydrogen,economize the precious microelements microelements and improve the technological properties.Thus the microelements will play an important role in further developing the welding materials.This paper lays emphasis on the discussion of the mechanism of reducing hydrogen by microelements Y and Te.It is considered from the results that both Y and Te belong to surface active elements and can reduce the diffusible hydrogen in weld bead because they can change the surface properlies of molten pool metal and reduce the absorption of hydrogen atom in arc space of liquid metal surface.This research has a great significance in the development and utilization of microelements in welding.展开更多
全球变暖的背景下,百年尺度上的区域气温变化规律,近年来已成为气候变化研究的热点。本文基于1901-2016年英国东英吉利(East Anglia)大学气候研究中心(Climatic Research Unit,CRU)提供的高分辨率、逐月气温数据集,采用一元线性回归法...全球变暖的背景下,百年尺度上的区域气温变化规律,近年来已成为气候变化研究的热点。本文基于1901-2016年英国东英吉利(East Anglia)大学气候研究中心(Climatic Research Unit,CRU)提供的高分辨率、逐月气温数据集,采用一元线性回归法、滑动平均法和Mann-Kendall突变检验法分析了116年来山西气温的时空分布特征。结果表明:百年来山西年平均气温和各季节气温均呈波动上升趋势,年均和各季节气温倾向率分别为0.13℃·(10a)-1(年平均)、0.16℃·(10a)-1(春季)、0.05℃·(10a)-1(夏季)、0.09℃·(10a)-1(秋季)、0.22℃·(10a)-1(冬季),其中冬季气温增幅最大,对年均温增长的贡献最大,贡献率为42.31%,夏季气温增幅最小,贡献率也最小(9.62%)。研究时段内,山西各季节气温均发生突变,春季季均温突变开始于1993年,夏季在1917年和1996年都发生了气温突变,秋季、冬季出现突变的年份分别为2001年、1984年。空间上,山西多年平均气温和季均温均以南高北低的纬度变化规律为主,同时受到地形的影响,分别形成不同气温中心,其中冬季受地形影响最小,尤其是最冷月。展开更多
Trivalen t Cr layers are studied by direct current brush- plating and pulse current brush-plating. Under the SEM,the appearence,the morphology of cross sections and normal sec- tions of the layers are observed a...Trivalen t Cr layers are studied by direct current brush- plating and pulse current brush-plating. Under the SEM,the appearence,the morphology of cross sections and normal sec- tions of the layers are observed and analysed,the hardness, bond intensities and corrosion- resis- tance are measured. Then, the election- probe and X ray diffraction instruments are used to study the bond and harden mechanism of lavers,The result of research shows that: the harden ef- fect of the layers is caused by the extra- fine grains and internal stress in the layers. And the lay- ers and basis are joined by mechanical bond,metal bond and diffuse bond. All these kinds of bonds lie on different places of interface, they make the layers and base metal unit well.展开更多
基金This project is supported by National Natural Science Foundation of China(No. 50544025)Natural Science Foundation of High Education of Jiangsu Province, China (No. 05KJB460030)
文摘For characteristics of open and far from thermodynamic equilibrium in welding chemical reaction, a new kind of quantitative method, which is used to analyze direction and extent for chemical reaction of SiO2/Fe during quasi-steady state period, is introduced with the concept of non-equilibrium stationary state. The main idea is based on thermodynamic driving forces, which result in non-zero thermodynamic fluxes and lead to chemical reaction far away from thermodynamic equilibrium. There exists certain dynamic equilibrium relationship between rates of diffusion fluxes in liquid phase of reactants or products and the rate equation of chemical reaction when welding is in quasi-steady state. As result of this, a group of non-linear equations containing concentrations of all substances at interface of slag/liquid-metal may be established. Moreover the stability of this non-equilibrium stationary state is discussed using dissipative structure theory and it is concluded theoretically that this non-equilibrium stationary state for welding chemical reaction is of stability.
文摘In this paper,the influence of microelements yttrium(Y)and tellurium(Te)on the diffusible hydrogen in weld bead has been investigated in a systemic way by means of alloying addition in the molten pool(AAMP).The results indicate that AAMP can notably reduce the diffusible hydrogen,economize the precious microelements microelements and improve the technological properties.Thus the microelements will play an important role in further developing the welding materials.This paper lays emphasis on the discussion of the mechanism of reducing hydrogen by microelements Y and Te.It is considered from the results that both Y and Te belong to surface active elements and can reduce the diffusible hydrogen in weld bead because they can change the surface properlies of molten pool metal and reduce the absorption of hydrogen atom in arc space of liquid metal surface.This research has a great significance in the development and utilization of microelements in welding.
文摘全球变暖的背景下,百年尺度上的区域气温变化规律,近年来已成为气候变化研究的热点。本文基于1901-2016年英国东英吉利(East Anglia)大学气候研究中心(Climatic Research Unit,CRU)提供的高分辨率、逐月气温数据集,采用一元线性回归法、滑动平均法和Mann-Kendall突变检验法分析了116年来山西气温的时空分布特征。结果表明:百年来山西年平均气温和各季节气温均呈波动上升趋势,年均和各季节气温倾向率分别为0.13℃·(10a)-1(年平均)、0.16℃·(10a)-1(春季)、0.05℃·(10a)-1(夏季)、0.09℃·(10a)-1(秋季)、0.22℃·(10a)-1(冬季),其中冬季气温增幅最大,对年均温增长的贡献最大,贡献率为42.31%,夏季气温增幅最小,贡献率也最小(9.62%)。研究时段内,山西各季节气温均发生突变,春季季均温突变开始于1993年,夏季在1917年和1996年都发生了气温突变,秋季、冬季出现突变的年份分别为2001年、1984年。空间上,山西多年平均气温和季均温均以南高北低的纬度变化规律为主,同时受到地形的影响,分别形成不同气温中心,其中冬季受地形影响最小,尤其是最冷月。
文摘Trivalen t Cr layers are studied by direct current brush- plating and pulse current brush-plating. Under the SEM,the appearence,the morphology of cross sections and normal sec- tions of the layers are observed and analysed,the hardness, bond intensities and corrosion- resis- tance are measured. Then, the election- probe and X ray diffraction instruments are used to study the bond and harden mechanism of lavers,The result of research shows that: the harden ef- fect of the layers is caused by the extra- fine grains and internal stress in the layers. And the lay- ers and basis are joined by mechanical bond,metal bond and diffuse bond. All these kinds of bonds lie on different places of interface, they make the layers and base metal unit well.
