A series of novel low band gap donor-acceptor （D-A） type organic co-polymers （BT-F-TPA, BT-CZ-TPA and BT-SI-TPA） consisting of electron-deficient acceptor blocks both in main chains （M1） and at the pendant （M2...A series of novel low band gap donor-acceptor （D-A） type organic co-polymers （BT-F-TPA, BT-CZ-TPA and BT-SI-TPA） consisting of electron-deficient acceptor blocks both in main chains （M1） and at the pendant （M2） were polymerized with different electron rich donor （M3-M5） blocks, i.e., 9,9-dihexyl-9H-fluorene, N-alkyl-2,7-carbazole, and 2,6-dithinosilole, respectively, via Suzuki method. These polymers exhibited relatively low band gaps （1.65-1.88 eV） and broad absorption ranges （680-740 nm）. Bulk heterojunction （BHJ） solar cells incorporating these polymers as electron donors, blended with [6,6]-phenyl-C61-butyric acid methyl ester （PC61BM） or [6,6]-phenyl-Cvl-butyric acid methyl ester （PC71BM） as electron-acceptors in different weight ratios were fabricated and tested under 100 mW/cm2 of AM 1.5 with white-light illumination. The photovoltaic device containing donor BT-SI-TPA and acceptor PC71BM in 1：2 weight ratio showed the best power conversion efficiency （PCE） value of 1.88%, with open circuit voltage （Voc） = 0.75 V, short circuit current density （Jsc） = 7.60 mA/cm2, and fill factor （FF） = 33.0%.展开更多
基金This work wasfinancially supported bythe National Institute of Science and Technology,Berhampur,Odisha,India
文摘A series of novel low band gap donor-acceptor （D-A） type organic co-polymers （BT-F-TPA, BT-CZ-TPA and BT-SI-TPA） consisting of electron-deficient acceptor blocks both in main chains （M1） and at the pendant （M2） were polymerized with different electron rich donor （M3-M5） blocks, i.e., 9,9-dihexyl-9H-fluorene, N-alkyl-2,7-carbazole, and 2,6-dithinosilole, respectively, via Suzuki method. These polymers exhibited relatively low band gaps （1.65-1.88 eV） and broad absorption ranges （680-740 nm）. Bulk heterojunction （BHJ） solar cells incorporating these polymers as electron donors, blended with [6,6]-phenyl-C61-butyric acid methyl ester （PC61BM） or [6,6]-phenyl-Cvl-butyric acid methyl ester （PC71BM） as electron-acceptors in different weight ratios were fabricated and tested under 100 mW/cm2 of AM 1.5 with white-light illumination. The photovoltaic device containing donor BT-SI-TPA and acceptor PC71BM in 1：2 weight ratio showed the best power conversion efficiency （PCE） value of 1.88%, with open circuit voltage （Voc） = 0.75 V, short circuit current density （Jsc） = 7.60 mA/cm2, and fill factor （FF） = 33.0%.
