1,3,3-tnmethyl-spiro[mdolino-2,3’-[2H]naphtho[2,1-b] [1,4]oxazine(SP1) and 1,3,3-trimen-thyl-9-methoxy-spiro[indolino2,3’-[2H]naphtho[2,1-b] [ 1,4]oxazine] (SP2) react with hydrochloric acid to form the complex SP H...1,3,3-tnmethyl-spiro[mdolino-2,3’-[2H]naphtho[2,1-b] [1,4]oxazine(SP1) and 1,3,3-trimen-thyl-9-methoxy-spiro[indolino2,3’-[2H]naphtho[2,1-b] [ 1,4]oxazine] (SP2) react with hydrochloric acid to form the complex SP HCl in isopropanol solution at room temperature The absorption maxima of these complexes are 440 and 463 nm respectively In acidic media,the opening form of spirooxazine can react with hydrochloric acid to form the complex PMC HCl via zwittenon form The absorption spectra of PMC HCl are obviously hypsochromic shifted compared with the reported spectra of the complex in neutral media In the mean time,the thermal stability of the complex is increased.The first order kinetics for the decoloration process of the acidichromic product of the opening form was determined and the lifetimes of these products are 180 and 200 s,respectively.展开更多
基金Project supported by the National Natural Science Foundation of Chinathe Chinese Academy of Sciences
文摘1,3,3-tnmethyl-spiro[mdolino-2,3’-[2H]naphtho[2,1-b] [1,4]oxazine(SP1) and 1,3,3-trimen-thyl-9-methoxy-spiro[indolino2,3’-[2H]naphtho[2,1-b] [ 1,4]oxazine] (SP2) react with hydrochloric acid to form the complex SP HCl in isopropanol solution at room temperature The absorption maxima of these complexes are 440 and 463 nm respectively In acidic media,the opening form of spirooxazine can react with hydrochloric acid to form the complex PMC HCl via zwittenon form The absorption spectra of PMC HCl are obviously hypsochromic shifted compared with the reported spectra of the complex in neutral media In the mean time,the thermal stability of the complex is increased.The first order kinetics for the decoloration process of the acidichromic product of the opening form was determined and the lifetimes of these products are 180 and 200 s,respectively.
