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1-(1-Alkylsulfonic)-3-methylimidazolium chloride as a reusable Brφnsted acid catalyst for the regioselective azidolysis of epoxides under solvent-free conditions 被引量:1
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作者 Sobhan Rezayati eshagh rezaee nezhad Rahimeh Hajinasiri 《Chinese Chemical Letters》 SCIE CAS CSCD 2016年第6期974-978,共5页
In this study, 1-(1-alkylsulfonic)-3-methylimidazolium chloride as a new, green, and reusable Br?nsted acid catalyst was prepared. In this protocol, we used for the regioselective ring-opening reactions of various ... In this study, 1-(1-alkylsulfonic)-3-methylimidazolium chloride as a new, green, and reusable Br?nsted acid catalyst was prepared. In this protocol, we used for the regioselective ring-opening reactions of various epoxiodes with sodium azide to afford the corresponding b-azido alcohols in excellent yields and short reaction time under mild and neutral reaction conditions. This method offers several advantages including excellent regioselectivity, clean reactions, simple work-up procedure, a recyclable catalyst,and use of an eco-friendly catalyst. 展开更多
关键词 Ionic liquids(ILs) β-Azido alcohols Ring opening REGIOSELECTIVE Br?nsted acid
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