Perspectives and challenges of hydrogen storage in solid-state hydrides

Hydrogen has been widely considered as a clean energy carrier that bridges the energy producers and energy consumers in an efficient and safe way for a sustainable society.Hydrogen can be stored in a gas,liquid and solid states and each method has its unique advantage.Though compressed hydrogen and liquefied hydrogen are mature technologies for industrial applications,appropriate measures are necessary to deal with the issues at high pressure up to around 100 MPa and low temperature at around 20 K.Distinct from those technologies,storing hydrogen in solid-state hydrides can realize a more compact and much safer approach that does not require high hydrogen pressure and cryogenic temperature.In this review,we will provide an overview of the majormaterial groups that are capable of absorbing and desorbing hydrogen reversibly.The main features on hydrogen storage properties of each material group are summarized,together with the discussion of the key issues and the guidance of materials design,aiming at providing insights for new material development as well as industrial applications.

Impact of severe plastic deformation on kinetics and thermodynamics of hydrogen storage in magnesium and its alloys

Magnesium and its alloys are the most investigated materials for solid-state hydrogen storage in the form of metal hydrides,but there are still unresolved problems with the kinetics and thermodynamics of hydrogenation and dehydrogenation of this group of materials.Severe plastic deformation(SPD)methods,such as equal-channel angular pressing(ECAP),high-pressure torsion(HPT),intensive rolling,and fast forging,have been widely used to enhance the activation,air resistance,and hydrogenation/dehydrogenation kinetics of Mg-based hydrogen storage materials by introducing ultrafine/nanoscale grains and crystal lattice defects.These severely deformed materials,particularly in the presence of alloying additives or second-phase nanoparticles,can show not only fast hydrogen absorption/desorption kinetics but also good cycling stability.It was shown that some materials that are apparently inert to hydrogen can absorb hydrogen after SPD processing.Moreover,the SPD methods were effectively used for hydrogen binding-energy engineering and synthesizing new magnesium alloys with low thermodynamic stability for reversible low/room-temperature hydrogen storage,such as nanoglasses,high-entropy alloys,and metastable phases including the high-pressureγ-MgH2 polymorph.This work reviews recent advances in the development of Mg-based hydrogen storage materials by SPD processing and discusses their potential in future applications.