The Mg-Gd-Y-Zn-Zr alloys are representational and potential age-hardening systems as reported in the past ten years,but their mechanical properties are still dependent on the grain size and its distribution.The effect...The Mg-Gd-Y-Zn-Zr alloys are representational and potential age-hardening systems as reported in the past ten years,but their mechanical properties are still dependent on the grain size and its distribution.The effect of bimodal structure on mechanical properties of Mg-8Gd-3Y-0.5Zr alloy with bimodal grain size distributions was investigated.The results suggested that the volume fraction of fine grain(FG)and coarse grain(CG)could be controlled by combined processes of hot forging,extrusion and annealing.And for the present alloys with bimodal grain size distribution,the improvement of strength is still attributed to the grain refinement.The morphology of bimodal grain size distribution has a marked impact on the ductility of the alloy,i.e.with the increase of coarse grain volume fraction,the elongation to failure increases at the beginning and then decreases.The mechanism of the toughening effect of bimodal grain size distribution on the Mg-Gd-Y-Zn-Zr alloys with bimodal grain size structure has been discussed.展开更多
A low-diffusion Ni Re Pt Al coating((Ni,Pt)Al outer layer in addition to a Re-rich diffusion barrier layer)was prepared on a Ni_(3)Al-base single crystal(SC)superalloy via electroplating and gaseous aluminizing treatm...A low-diffusion Ni Re Pt Al coating((Ni,Pt)Al outer layer in addition to a Re-rich diffusion barrier layer)was prepared on a Ni_(3)Al-base single crystal(SC)superalloy via electroplating and gaseous aluminizing treatments,wherein the electroplating procedures consisted of the composite deposition of Ni-Re followed by electroplating of Pt.In order to perform a comparison with conventional Ni Al and(Ni,Pt)Al coatings,the cyclic oxidation performance of the Ni Re Pt Al coating was evaluated at 1100 and 1150℃.We observed that the oxidation resistance of the Ni Re Pt Al coating was significantly improved by the greater presence of the residualβ-Ni Al phase in the outer layer and the lesser outward-diffusion of Mo from the substrate.In addition,the coating with the Re-rich diffusion barrier demonstrated a lower extent of interdiffusion into the substrate,where the thickness of the second reaction zone(SRZ)in the substrate alloy decreased by 25%.The mechanisms responsible for improving the oxidation resistance and decreasing the extent of SRZ formation are discussed,in which a particular attention is paid to the inhibition of the outward diffusion of Mo by the Re-based diffusion barrier.展开更多
Initial oxidation behavior of NiCoCrAlY coating prepared by arc-ion plating has been studied in air at 900, 1000 and 1100 ℃. The results showed that phase transformation from transient θ-Al_(2)O_(3) to α-Al_(2)O_(3...Initial oxidation behavior of NiCoCrAlY coating prepared by arc-ion plating has been studied in air at 900, 1000 and 1100 ℃. The results showed that phase transformation from transient θ-Al_(2)O_(3) to α-Al_(2)O_(3) was highly related to the temperature and oxidation time. The oxide scale in the initial stage was mainly composed of θ-Al_(2)O_(3) at 900 ℃. Instead, more amount of α-Al_(2)O_(3) emerged out with increasing oxidation temperature. The elemental distribution after oxidation confirmed that faster chromium diffusion to the oxide scale played an important role in the speedy transformation from θ-Al_(2)O_(3) to α-Al_(2)O_(3). Y segregation at scale/coating interface resulted in less cavity formation and hence improved the oxide scale adherence.展开更多
基金supports of the National Key Research and Development Plan(Grant Nos.2016YFB0701201 and 2016YFB0301103)the National Natural Science Foundation of China(Grant Nos.51771109 and 51631006).
文摘The Mg-Gd-Y-Zn-Zr alloys are representational and potential age-hardening systems as reported in the past ten years,but their mechanical properties are still dependent on the grain size and its distribution.The effect of bimodal structure on mechanical properties of Mg-8Gd-3Y-0.5Zr alloy with bimodal grain size distributions was investigated.The results suggested that the volume fraction of fine grain(FG)and coarse grain(CG)could be controlled by combined processes of hot forging,extrusion and annealing.And for the present alloys with bimodal grain size distribution,the improvement of strength is still attributed to the grain refinement.The morphology of bimodal grain size distribution has a marked impact on the ductility of the alloy,i.e.with the increase of coarse grain volume fraction,the elongation to failure increases at the beginning and then decreases.The mechanism of the toughening effect of bimodal grain size distribution on the Mg-Gd-Y-Zn-Zr alloys with bimodal grain size structure has been discussed.
基金the Key-Area Research and Development Program of Guangdong Province(2019B010936001)financially supported by the National Natural Science Foundation of China(Grant Nos.51671202 and 51301184)。
文摘A low-diffusion Ni Re Pt Al coating((Ni,Pt)Al outer layer in addition to a Re-rich diffusion barrier layer)was prepared on a Ni_(3)Al-base single crystal(SC)superalloy via electroplating and gaseous aluminizing treatments,wherein the electroplating procedures consisted of the composite deposition of Ni-Re followed by electroplating of Pt.In order to perform a comparison with conventional Ni Al and(Ni,Pt)Al coatings,the cyclic oxidation performance of the Ni Re Pt Al coating was evaluated at 1100 and 1150℃.We observed that the oxidation resistance of the Ni Re Pt Al coating was significantly improved by the greater presence of the residualβ-Ni Al phase in the outer layer and the lesser outward-diffusion of Mo from the substrate.In addition,the coating with the Re-rich diffusion barrier demonstrated a lower extent of interdiffusion into the substrate,where the thickness of the second reaction zone(SRZ)in the substrate alloy decreased by 25%.The mechanisms responsible for improving the oxidation resistance and decreasing the extent of SRZ formation are discussed,in which a particular attention is paid to the inhibition of the outward diffusion of Mo by the Re-based diffusion barrier.
基金sponsored by the R&D Program in Key Fields of Guangdong Province(No.2019B010936001)the National Natural Science Foundation of China(Grant No.51671202)+1 种基金supported by the National Engineering Laboratory for Marine and Ocean Engineering Power System-Laboratory for Ocean Engineering Gas Turbine。
文摘Initial oxidation behavior of NiCoCrAlY coating prepared by arc-ion plating has been studied in air at 900, 1000 and 1100 ℃. The results showed that phase transformation from transient θ-Al_(2)O_(3) to α-Al_(2)O_(3) was highly related to the temperature and oxidation time. The oxide scale in the initial stage was mainly composed of θ-Al_(2)O_(3) at 900 ℃. Instead, more amount of α-Al_(2)O_(3) emerged out with increasing oxidation temperature. The elemental distribution after oxidation confirmed that faster chromium diffusion to the oxide scale played an important role in the speedy transformation from θ-Al_(2)O_(3) to α-Al_(2)O_(3). Y segregation at scale/coating interface resulted in less cavity formation and hence improved the oxide scale adherence.