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镧改性木槿皮吸附剂制备及对废水中磷的吸附 被引量:8
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作者 倪琳洁 邱欢 +6 位作者 刘晓玲 雷燕 张可 罗鸿兵 程琳 范良千 陈伟 《生态与农村环境学报》 CAS CSCD 北大核心 2021年第2期234-241,共8页
以木槿皮作为原料,利用氯化镧对其进行改性,制备一种新的磷吸附材料。采用单因素法确定吸附剂的最佳改性条件,研究pH值、吸附剂投加量、吸附时间、吸附温度对磷的吸附性能的影响,结果表明:(1)木槿皮的最佳改性条件为:w(氯化镧)为7%、焙... 以木槿皮作为原料,利用氯化镧对其进行改性,制备一种新的磷吸附材料。采用单因素法确定吸附剂的最佳改性条件,研究pH值、吸附剂投加量、吸附时间、吸附温度对磷的吸附性能的影响,结果表明:(1)木槿皮的最佳改性条件为:w(氯化镧)为7%、焙烧温度300℃、焙烧时间2.5 h;(2)初始ρ(磷)为5 mg·L^(-1),pH值为7,投加量为0.35 g时吸附效果最好,磷去除率达到94.99%;(3)吸附时间为130 min时改性木槿皮对磷的吸附达到饱和,不同温度下镧改性木槿皮对磷的吸附方式均符合伪二级动力学方程;(4)Langmuir等温方程拟合效果更佳,吸附反应为单分子层吸附,温度为288、298和308 K时镧改性木槿皮吸附剂对磷的最大吸附量分别为1.54、1.55和1.63 mg·g^(-1);(5)吸附热力学结果显示自由能变(ΔG^(θ))<0、焓变(ΔH^(θ))>0、熵变(ΔS^(θ))>0,镧改性木槿皮对磷的吸附是一个自发熵增的吸热过程,升温有利于反应进行,属于化学吸附。 展开更多
关键词 木槿皮 镧改性 吸附 磷去除
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Assessment of Economic Loss Caused by Agricultural Non-point Source Nutrient Loss
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作者 fan liang-qian CHEN Feng-hui 《Asian Agricultural Research》 2012年第9期67-70,77,共5页
Taking Zhejiang Province as an example, we use the JOHNES export coefficient model to estimate the total nitrogen (TN) and total phosphorus (TP) load of agricultural planting, livestock and poultry breeding and rural ... Taking Zhejiang Province as an example, we use the JOHNES export coefficient model to estimate the total nitrogen (TN) and total phosphorus (TP) load of agricultural planting, livestock and poultry breeding and rural living non-point source in 2009. Based on the protection cost method in environmental economics, we quantitatively assess the economic loss caused by these three types of non-point source nutrient loss. The results show that in TN non-point source load, the load of land for planting accounts for 57.48%, the load of rural living accounts for 30.22%, and the load of livestock and poultry breeding accounts for 12.30%; in TP non-point source load, the load of rural living accounts for 46.18%, the load of livestock and poultry breeding accounts for 29.00%, and the load of land for planting accounts for 24.82%. The economic loss arising from the agricultural non-point source nutrient loss is equivalent to 2.329 424 7 billion yuan per year (the loss from land for planting accounts for 55.46%; the loss from rural living accounts for 31.21%; the loss from livestock and poultry breeding accounts for 13.33%). It indicates that in order to reduce the loss arising from agricultural non-point source nutrient loss, we should pay attention to controlling the land for planting and rural living source. 展开更多
关键词 AGRICULTURAL non-point SOURCE Water ENVIRONMENT EC
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