0.14 at%Mn-doped 0.95(Na1/2Bi1/2)TiO3-0.05BaTiO3(0.95NBT-0.05BT)lead-free single crystals were grown by a top-seeded solution growth method(TSSG).X-ray powder diffraction measurement showed that the as-grown single cr...0.14 at%Mn-doped 0.95(Na1/2Bi1/2)TiO3-0.05BaTiO3(0.95NBT-0.05BT)lead-free single crystals were grown by a top-seeded solution growth method(TSSG).X-ray powder diffraction measurement showed that the as-grown single crystals exhibit rhombohedral perovskite structure with apparent distortion.With the increase of temperature,successive structural phase transitions occur in the Mn-doped 0.95NBT-0.05BT single crystals.After poling,apparent dielectric anomaly is induced accompanied by the increase of the character of diffuse phase transition and the decrease of the value of dielectric constant.The Mn-doped0.95NBT-0.05BT single crystals exhibit complex domain structure,in which micro and macro domains coexist with statistically 4mm symmetry.The Mn-doped 0.95NBT-0.05BT lead-free single crystals exhibit excellent piezoelectric and pyroelectric properties,which will lead to promising advance in piezoelectric and pyroelectric applications.The infrared-absorption band occurred around 630.6 cm 1can be assigned to the"stretching"normal vibration of[Na1/2Bi1/2]/Ti-O group.The three diffused Raman bands centered around 300,560 and 800 cm 1can be attributed to F2g[TiO6]bending vibration,A1g[TiO6]stretching vibration and"soft mode"mixed by bending and stretching vibrations.展开更多
基金supported by the National Natural Science Foundation of China(51242006)the Qing Lan Project,the Key Laboratory of Inorganic Function Material and Device,Chinese Academy of Sciences(KLIFMD-2011-02)the Priority Academic Program Development of Jiangsu Higher Education Institutions
文摘0.14 at%Mn-doped 0.95(Na1/2Bi1/2)TiO3-0.05BaTiO3(0.95NBT-0.05BT)lead-free single crystals were grown by a top-seeded solution growth method(TSSG).X-ray powder diffraction measurement showed that the as-grown single crystals exhibit rhombohedral perovskite structure with apparent distortion.With the increase of temperature,successive structural phase transitions occur in the Mn-doped 0.95NBT-0.05BT single crystals.After poling,apparent dielectric anomaly is induced accompanied by the increase of the character of diffuse phase transition and the decrease of the value of dielectric constant.The Mn-doped0.95NBT-0.05BT single crystals exhibit complex domain structure,in which micro and macro domains coexist with statistically 4mm symmetry.The Mn-doped 0.95NBT-0.05BT lead-free single crystals exhibit excellent piezoelectric and pyroelectric properties,which will lead to promising advance in piezoelectric and pyroelectric applications.The infrared-absorption band occurred around 630.6 cm 1can be assigned to the"stretching"normal vibration of[Na1/2Bi1/2]/Ti-O group.The three diffused Raman bands centered around 300,560 and 800 cm 1can be attributed to F2g[TiO6]bending vibration,A1g[TiO6]stretching vibration and"soft mode"mixed by bending and stretching vibrations.