Crystal structure of nickel(Ⅱ) complex with a new mesocyclic diamineligand, 3-hydroxy1-1, 5-diazacycloheptane, C10H24N41NiO2Br2. 2H2O, Mr=486. 9 is reported. It crystallizes in monoclinic P21/c with a=7. 167 (1 ), b=...Crystal structure of nickel(Ⅱ) complex with a new mesocyclic diamineligand, 3-hydroxy1-1, 5-diazacycloheptane, C10H24N41NiO2Br2. 2H2O, Mr=486. 9 is reported. It crystallizes in monoclinic P21/c with a=7. 167 (1 ), b=13. 794 (3 ), c =9. 726 (3),β=109.42(2)°, V= 906. 8 (4) , Z= 2, Dc= 1.783g/cm3, μ=5. 477mm-1, F(000) =492. The final R and Rw are 0.045 and 0.045 for 1155 observedreflections with I≥4. 0σ(I). The result of X-ray structure determination shows thatnickel (Ⅱ) forms an octahedral bicyclic complex with 3-hydroxy1-1, 5-diazacycloheptane.展开更多
Crystal structure of copper(Ⅱ) complex with a new mesocyclic diamine ligand 3-hydroxyl-1, 5-diazacyclooctane, Cu [C_(12)H_(28)N_4O_2]Br_2, M_r= 483. 7 is reported. It crystallizes in orthorhombic Pbca with a= 16. 201...Crystal structure of copper(Ⅱ) complex with a new mesocyclic diamine ligand 3-hydroxyl-1, 5-diazacyclooctane, Cu [C_(12)H_(28)N_4O_2]Br_2, M_r= 483. 7 is reported. It crystallizes in orthorhombic Pbca with a= 16. 201 (5), b=10. 513 (4), c=9. 992(4) A, V=1701. 8(7) A￣3, Z=4, D_c=1. 888 g/cm￣3, μ=49. 5 cm￣(-1) (MoKa),F(000) = 972. The final R and Rto are 0. 039 and 0. 047 for 1052 observed reflections with I≥3σ(I). The result of X-ray structure determination shows that 3hydroxyl-1,5-diazacyclooctane forms a 2 :1 complex with CuBr_2 in which the central copper ion is sandwiched between the two ligands.展开更多
文摘Crystal structure of nickel(Ⅱ) complex with a new mesocyclic diamineligand, 3-hydroxy1-1, 5-diazacycloheptane, C10H24N41NiO2Br2. 2H2O, Mr=486. 9 is reported. It crystallizes in monoclinic P21/c with a=7. 167 (1 ), b=13. 794 (3 ), c =9. 726 (3),β=109.42(2)°, V= 906. 8 (4) , Z= 2, Dc= 1.783g/cm3, μ=5. 477mm-1, F(000) =492. The final R and Rw are 0.045 and 0.045 for 1155 observedreflections with I≥4. 0σ(I). The result of X-ray structure determination shows thatnickel (Ⅱ) forms an octahedral bicyclic complex with 3-hydroxy1-1, 5-diazacycloheptane.
文摘Crystal structure of copper(Ⅱ) complex with a new mesocyclic diamine ligand 3-hydroxyl-1, 5-diazacyclooctane, Cu [C_(12)H_(28)N_4O_2]Br_2, M_r= 483. 7 is reported. It crystallizes in orthorhombic Pbca with a= 16. 201 (5), b=10. 513 (4), c=9. 992(4) A, V=1701. 8(7) A￣3, Z=4, D_c=1. 888 g/cm￣3, μ=49. 5 cm￣(-1) (MoKa),F(000) = 972. The final R and Rto are 0. 039 and 0. 047 for 1052 observed reflections with I≥3σ(I). The result of X-ray structure determination shows that 3hydroxyl-1,5-diazacyclooctane forms a 2 :1 complex with CuBr_2 in which the central copper ion is sandwiched between the two ligands.
