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负载型贵金属催化剂的臭氧分解性能 被引量:2
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作者 王婷 王胜 +2 位作者 符启军 邢德风 王树东 《工业催化》 CAS 2022年第1期30-38,共9页
通过浸渍法和乙二醇还原法制得γ-Al_(2)O_(3)负载钯催化剂,在30℃、600000 mL·(gcat·h)^(-1)和不同相对湿度(RH<5%和RH>90%)条件下,研究其臭氧催化分解性能。结果表明,Pd负载质量分数1.5%和贵金属粒径约2.8 nm的Pd/γ-... 通过浸渍法和乙二醇还原法制得γ-Al_(2)O_(3)负载钯催化剂,在30℃、600000 mL·(gcat·h)^(-1)和不同相对湿度(RH<5%和RH>90%)条件下,研究其臭氧催化分解性能。结果表明,Pd负载质量分数1.5%和贵金属粒径约2.8 nm的Pd/γ-Al_(2)O_(3)催化剂催化活性最佳。采用XRD、XPS、TEM、SEM-EDS、O_(2)-TPD和H_(2)O-TPD等手段,揭示其优良臭氧分解性能可能是由于较小的Pd粒径改善了催化剂中Pd^(0)相对含量和氧物种迁移能力。此外,Pd催化剂对于水的吸附量和吸附强度的调变,改善了其耐水性能,这些研究为高效Pd基臭氧分解催化剂开发提供了指导。 展开更多
关键词 催化化学 臭氧 催化分解 贵金属 耐水性
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Broadband radio spectral observations of the solar eclipse on 2008-08-01 and its implications on the quiet Sun atmospheric model 被引量:2
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作者 TAN BaoLin YAN YiHua +8 位作者 ZHANG Yin TAN ChengMin HUANG Jing LIU YuYing fu qijun CHEN ZhiJun LIU Fei CHEN LinJie JI GuoShu 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2009年第11期1765-1772,共8页
Based on the joint-observations of the radio broadband spectral emissions of the solar eclipse on August 1, 2008 at Jiuquan (total eclipse) and Huairou (partial eclipse) at the frequencies of 2.00-5.60 GHz (Jiuquan), ... Based on the joint-observations of the radio broadband spectral emissions of the solar eclipse on August 1, 2008 at Jiuquan (total eclipse) and Huairou (partial eclipse) at the frequencies of 2.00-5.60 GHz (Jiuquan), 2.60-3.80 GHz (Chinese solar broadband radiospectrometer, SBRS/Huairou), and 5.20-7.60 GHz (SBRS/Huairou), the authors assemble a successive series of broadband spectra with a frequency of 2.60-7.60 GHz to observe the solar eclipse synchronously. This is the first attempt to analyze the solar eclipse radio emission under the two telescopes located at different places with broadband frequencies in the periods of total and partial eclipses. With these analyses, the authors made a semiempirical model of the coronal plasma density of the quiet Sun, which can be expressed as ne 1.42×109(r-2+1.93r-5) (cm-3), in the space range of r=1.039-1.212 R , and made a comparison with the classic model. 展开更多
关键词 ATMOSPHERIC model ECLIPSE QUIET SUN RADIO emission plasma
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