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Studies on Solid State Reactions of Coordination Compounds(LXXI)──Solid State Reactions of o-Aminobenzoic Acid with Copper(Ⅱ) Acetate and Formate at Room Temperature
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作者 ZHENG Li-min LIN Jian-jun fu yan and xin xin-quan (department of chemistry , manjing university , naiijing , 210008) 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 1995年第1期45-49,共5页
olid state reactions of o-aminobenzoic acid (HOAB) with Cu (OAc)_2·H_2O,Cu(HCOO)_2 · 4H_2O, anhydrous Cu (OAc)_2 and Cu (HCOO)_2 at room or close toroom temperature have been investigated. The product Cu(OAB... olid state reactions of o-aminobenzoic acid (HOAB) with Cu (OAc)_2·H_2O,Cu(HCOO)_2 · 4H_2O, anhydrous Cu (OAc)_2 and Cu (HCOO)_2 at room or close toroom temperature have been investigated. The product Cu(OAB)_2 with a high yieldwas synthesized very conveniently compared witb the solution phase method. Thekinetic behavior was studied by means of the isothermal electrical conductivity mea-surement. The reactivity was found to decrease in the order : Cu(OAc)_2· H_2O>Cu(OAc)_2>Cu (HCOO)_2 ·4H_2O>Cu (HCOO)_2, which was attributable to the crystalstructures of the copper salts. 展开更多
关键词 Solid state reaction o-Aminobenzoic acid Copper acetate Copper formate Electrical conductivity
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