光纤分布式声波传感技术在石油行业的研究进展

基于相位敏感光时域反射的光纤分布式声波传感技术(DAS)具有长距离、高灵敏、高空间分辨率、低成本、无源、抗电磁干扰等显著优势,非常契合石油行业中的地震勘探和管道监测等需求。从石油行业的应用需求出发,介绍了光纤DAS技术的基本原理和解调技术,并阐述了近年来该研究领域在信噪比增强、探测距离扩展和采样率提升等方面所取得的最新研究成果。此外,重点总结了国内外在光纤DAS技术商用化方面的研究进展,分析比较了不同企业和机构研发的DAS产品的特点、性能和应用潜力。同时,重点针对光纤DAS技术在VSP测井、微地震探测和管道泛感知监测等领域的应用案列进行了阐述,展现出极强的市场竞争力。光纤DAS技术在未来石油行业中的应用研究方面,应加强数据超保真和多分量检波DAS的进一步研究。

Synergistic Effect between Zr-MOF and Phosphotungstic Acid for Oxidative Desulfurization

PTA/UiO-66 composites were successfully synthesized by the hydrothermal method.The results showed that the synergistic effect between phosphotungstic acid(PTA)and UiO-66 could enhance the oxidative desulfurization(ODS)activity.The XRD results proved that UiO-66 retained its structure in the PTA/UiO-66 composites.The SEM results showed that the PTA/UiO-66 catalysts exhibited regular octahedral shape.The Raman spectra revealed that PTA in the composites retained the Keggin structure.The XPS results showed that the electron transfer occurred from Zr-MOF to PTA.The ODS reaction mechanism was discussed.Electrons transfer from Zr-MOF to PTA can promote the generation of active species(·OH)and thus enhance the ODS activity.This explanation can be confirmed by the formation of oxygen vacancy and W0 as revealed by the XPS analysis.

Effect of Doped Vanadium Dioxide on Oxidative Desulfurization Reaction

VO2(M) doped with different metals(Ti, Ce, Nb, Zr, W, and Mo) was successfully synthesized by the hydrothermal reduction process using oxalic acid as the reductant. The results showed that doping metals in the VO2(M) lattice could enhance the oxidative desulfurization(ODS) activity. The DSC and Raman spectra revealed that VO2(M) retained its monoclinic structure after doping. Mechanism for the improvement of ODS activity by doping was investigated. Electron transfer to V(V) atom occurs upon doping, and then V(V) changes into V(IV), which can promote the ODS reaction. This explanation can be confirmed by the fact that doping can promote the proportion of V(Ⅳ) after doping as revealed by the XPS analysis.

散射增强微结构光纤及其分布式传感技术研究进展

分布式光纤传感器以光纤作为传输和传感融合的介质,具有高灵敏、全分布、大尺度、高分辨的独特优势,近年来受到多个应用领域研究人员的关注并逐步进入产业化。然而,现有普通单模光纤在传感信噪比与稳定性等方面仍存在局限性。以散射增强微结构特种光纤为传感载体,研究其分布式传感增效机理,介绍了其自动化、高效率刻写制备技术,并重点阐述了其分布式光纤传感技术研究进展与相关应用。进一步对散射增强微结构传感光纤的未来发展潜力及应用方向进行了展望。

基于散射增强光纤的分布式声波传感研究进展

基于相位敏感光时域反射技术的分布式声波传感(DAS)系统可实现大范围分布式的声波探测,近年来,在油气勘探、地质成像、管道安全、周界安防等应用领域受到研究关注。本文论述了光纤DAS技术的传感原理,分析了单模光纤的衰落机理和性能瓶颈。针对此问题,分别介绍了多种散射增强光纤的增效机理与声波传感性能。进一步,围绕微结构散射增强光纤DAS系统,综述了其近年来的技术与应用进展,并展望了其未来可能的发展方向。