Spectral Clustering with Eigenvalue Similarity Metric Method for POL-SAR Image Segmentation of Land Cover

A simple and fast approach based on eigenvalue similarity metric for Polarimetric SAR image segmentation of Land Cover is proposed in this paper. The approach uses eigenvalues of the coherency matrix as to construct similarity metric of clustering algorithm to segment SAR image. The Mahalanobis distance is used to metric pairwise similarity between pixels to avoid the manual scale parameter tuning in previous spectral clustering method. Furthermore, the spatial coherence constraints and spectral clustering ensemble are employed to stabilize and improve the segmentation performance. All experiments are carried out on three sets of Polarimetric SAR data. The experimental results show that the proposed method is superior to other comparison methods.

Amide naphthotubes:Biomimetic macrocycles for selective molecular recognition

Selective molecular recognition in water is routine for bioreceptors,but remains challenging for synthetic hosts.This is principally because noncovalent interactions are usually less efficient in aqueous environments.By mimicking the cavity feature of bioreceptors,Prof.Wei Jiang proposed and clarified the concept of“endo-functionalized cavity”.Through situating polar binding sites into a deep hydrophobic cavity,we designed and synthesized several macrocyclic hosts,among which amide naphthotubes are the most representative.The hosts can selectively recognize various polar molecules including organic micropollutants,drug molecules,and chiral molecules in water by employing the hydrophobic effect and shielded hydrogen bonding.In addition,these biomimetic hosts have been applied in spectroscopic analysis,adsorptive separation and self-assembly.In this review,we provide an overview of recent advances on amide naphthotubes with special emphasis on the efforts of Jiang's group.We are convinced that these biomimetic macrocycles will make further contributions to supramolecular chemistry and beyond.

Ultra-highly selective recognition of nucleosides over nucleotides by rational modification of tetralactam macrocycle and its application in enzyme assay

Artificial macrocycle with high binding selectivity in water is often challenging but urgently needed in various research and application areas.Herein,we report a new water-soluble biomimetic tetralactam macrocycle and realize the ultra-high selectivity to nucleosides over corresponding monophosphate nucleotides by rational modification.The introduction of charged groups at the periphery of endofunctionalized cavity makes the selectivity(guanosine to guanosine 5-monophosphate)increase remarkably from 100 to 1119.Based on the ultra-high selectivity of biomimetic tetralactam macrocycle,the sensitive CD73 enzyme activity assay was then achieved through product-selective fluorescence indicator displacement assay.Furthermore,the capability of the proposed method for inhibitor screening was successfully displayed.