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Anderson型多金属氧簇DNA嵌入剂
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作者 尹方方 李豹 吴立新 《中国科学:化学》 CAS CSCD 北大核心 2023年第7期1247-1256,共10页
DNA嵌入剂通过非共价作用进入到DNA碱基对,可改变DNA的二级结构,影响DNA的性质.已有DNA嵌入剂多为有机分子,而具有丰富功能性的多金属氧簇DNA嵌入剂尚未报道.本文通过共价修饰将三种具有DNA嵌入能力的有机基团连接到Anderson型多金属氧... DNA嵌入剂通过非共价作用进入到DNA碱基对,可改变DNA的二级结构,影响DNA的性质.已有DNA嵌入剂多为有机分子,而具有丰富功能性的多金属氧簇DNA嵌入剂尚未报道.本文通过共价修饰将三种具有DNA嵌入能力的有机基团连接到Anderson型多金属氧簇上,并用紫外-可见吸收光谱、荧光光谱和圆二色光谱对其与DNA的作用强度进行评估.研究表明,在空间位阻和嵌入作用的共同影响下,含有苯并菲咯啉四酮的多金属氧簇杂化物与DNA具有最强的结合能力,结合常数达到10~4L mol^(-1).透射电子显微镜和原子力显微镜结果表明嵌入结合对多金属氧簇杂化物和DNA的形貌都有显著影响.本文的工作将DNA嵌入剂研究扩展到了多金属氧簇领域,为更多功能性DNA嵌入剂的开发提供了新思路. 展开更多
关键词 多金属氧簇 DNA嵌入剂 非共价作用 有机共价修饰
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Anoxic phosphorus removal in a pilot scale anaerobic-anoxic oxidation ditch process 被引量:4
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作者 Hongxun HOU Shuying WANG +3 位作者 Yongzhen PENG Zhiguo YUAN fangfang yin Wang GAN 《Frontiers of Environmental Science & Engineering》 SCIE EI CSCD 2009年第1期106-111,共6页
The anaerobic-anoxic oxidation ditch(A^(2)/O OD)process is popularly used to eliminate nutrients from domestic wastewater.In order to identify the existence of denitrifying phosphorus removing bacteria(DPB),evaluate t... The anaerobic-anoxic oxidation ditch(A^(2)/O OD)process is popularly used to eliminate nutrients from domestic wastewater.In order to identify the existence of denitrifying phosphorus removing bacteria(DPB),evaluate the contribution of DPB to biological nutrient removal,and enhance the denitrifying phosphorus removal in the A^(2)/O OD process,a pilot-scale A^(2)/O OD plant(375 L)was conducted.At the same time batch tests using sequence batch reactors(12 L and 4 L)were operated to reveal the significance of anoxic phosphorus removal.The results indicated that:The average removal efficiency of COD,NH^(+)_(4),PO^(3–)_(4),and TN were 88.2%,92.6%,87.8%,and 73.1%,respectively,when the steady state of the pilotscale A^(2)/O OD plant was reached during 31–73 d,demonstrating a good denitrifying phosphorus removal performance.Phosphorus uptake took place in the anoxic zone by poly-phosphorus accumulating organisms NO^(-)_(2) could be used as electron receptors in denitrifying phosphorus removal,and the phosphorus uptake rate with NO^(-)_(2) as the electron receptor was higher than that with NO^(–)_(3) when the initial concentration of either NO^(-)_(2) or NO^(–)_(3) was 40 mg/L. 展开更多
关键词 wastewater treatment anaerobic-anoxic(A^(2)/O) oxidation ditch(OD) biological phosphorus removal denitrifying phosphorus removal
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Mechanical and thermal properties of mesogen-jacketed liquid crystalline polymer/epoxy resin composites 被引量:4
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作者 Chunpeng Chai fangfang yin +1 位作者 Guoping Li Yunjun Luo 《Science China Chemistry》 SCIE EI CAS CSCD 2015年第6期1021-1026,共6页
The effects of mesogen-jacketed liquid crystalline polymer poly(dipropyl vinylterephthalate)(PDPVT) on the mechanical and thermal properties of diglycidyl ether of bisphenol-A(DGEBA) epoxy resin were investigated by i... The effects of mesogen-jacketed liquid crystalline polymer poly(dipropyl vinylterephthalate)(PDPVT) on the mechanical and thermal properties of diglycidyl ether of bisphenol-A(DGEBA) epoxy resin were investigated by impact test, tensile test and thermogravimetric analysis(TGA). The mechanism underlying the enhancement of mechanical properties of epoxy resin was studied using 1D wide-angle X-ray diffraction(WAXD) and scanning electron microscope(SEM). It was found that the mechanical properties of 1 wt%–5 wt% PDPVT/DGEBA composites were significantly improved compared to neat epoxy resin. Especially, the epoxy resin with 3 wt% PDPVT had the greatest increase in mechanical properties, with the impact strength, tensile strength and elongation while breaking increased by 87%, 59% and 174%, respectively. The increased mechanical strength was due to the fact that PDPVT maintained liquid crystalline phase in cured PDPVT/DGEBA composites, which would blunt the crack tip and prevent crack propagation. Moreover, PDPVT had slight effect on the thermal stability properties of epoxy resin. 展开更多
关键词 mesogen-jacketed liquid crystalline polymer epoxy resin mechanical properties thermal stability properties
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