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热塑性碳硼烷聚羟基酯醚的合成及热稳定性能
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作者 邹龙 吕子彬 +5 位作者 王方玲 张猛 张孝阿 江盛玲 吕亚非 王成忠 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第3期59-65,共7页
以o-碳硼烷双酚二缩水甘油醚和丁二酸、4,4-二羧基二苯醚为原料,四苯基溴化磷为催化剂,设计合成了2种碳硼烷聚羟基酯醚(P1和P2)。通过红外光谱、核磁共振和凝胶渗透色谱表征了所得聚合物的结构,结果表明得到了预期结构的聚羟基酯醚。通... 以o-碳硼烷双酚二缩水甘油醚和丁二酸、4,4-二羧基二苯醚为原料,四苯基溴化磷为催化剂,设计合成了2种碳硼烷聚羟基酯醚(P1和P2)。通过红外光谱、核磁共振和凝胶渗透色谱表征了所得聚合物的结构,结果表明得到了预期结构的聚羟基酯醚。通过差示扫描量热分析和热重分析(TG)评价其热性能,研究了碳硼烷结构对玻璃化转变温度(Tg)、初始分解温度和残炭率的影响。结果表明,P1和P2的Tg分别为-20.6℃和12.8℃,比不含碳硼烷的聚羟基酯醚(P0)高,表明大体积刚性碳硼烷笼形结构的引入提高了聚羟基酯醚的玻璃化转变温度。TG分析结果显示,碳硼烷笼形结构能在高温下极大地提升聚羟基酯醚的耐烧蚀性能,空气氛围下P1和P2的残炭率高于氮气氛围。 展开更多
关键词 碳硼烷 聚羟基酯醚 热稳定性 热塑性
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Research Progress of Soil Microbiology
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作者 Lide wang Tuo YAO +4 位作者 Chunxiu GUO Fugui HAN fangling wang Tao SUN Yinhua ZHANG 《Agricultural Science & Technology》 CAS 2015年第11期2367-2371,共5页
This paper aims at summarized the research progress of soil microbes,in amount of soil microbes including bacteria,fungi and actinomycetes,soil microbial biomass,including microbial biomass carbon,microbial biomass ni... This paper aims at summarized the research progress of soil microbes,in amount of soil microbes including bacteria,fungi and actinomycetes,soil microbial biomass,including microbial biomass carbon,microbial biomass nitrogen and microbial biomass phosphorus,function of microbial and screening and application of beneficial microorganisms etc.,and future research are discussed combined with our project team for many years of work. 展开更多
关键词 土壤微生物学 土壤微生物生物量 微生物生物量碳 微生物量氮 有益微生物 功能微生物 细菌总数 项目团队
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A modified harmony search algorithm and its applications in weighted fuzzy production rule extraction
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作者 Shaoqiang YE Kaiqing ZHOU +2 位作者 Azlan Mohd ZAIN fangling wang Yusliza YUSOFF 《Frontiers of Information Technology & Electronic Engineering》 SCIE EI CSCD 2023年第11期1574-1590,共17页
Harmony search(HS)is a form of stochastic meta-heuristic inspired by the improvisation process of musicians.In this study,a modified HS with a hybrid cuckoo search(CS)operator,HS-CS,is proposed to enhance global searc... Harmony search(HS)is a form of stochastic meta-heuristic inspired by the improvisation process of musicians.In this study,a modified HS with a hybrid cuckoo search(CS)operator,HS-CS,is proposed to enhance global search ability while avoiding falling into local optima.First,the randomness of the HS pitch disturbance adjusting method is analyzed to generate an adaptive inertia weight according to the quality of solutions in the harmony memory and to reconstruct the fine-tuning bandwidth optimization.This is to improve the efficiency and accuracy of HS algorithm optimization.Second,the CS operator is introduced to expand the scope of the solution space and improve the density of the population,which can quickly jump out of the local optimum in the randomly generated harmony and update stage.Finally,a dynamic parameter adjustment mechanism is set to improve the efficiency of optimization.Three theorems are proved to reveal HS-CS as a global convergence meta-heuristic algorithm.In addition,12 benchmark functions are selected for the optimization solution to verify the performance of HS-CS.The analysis shows that HS-CS is significantly better than other algorithms in optimizing high-dimensional problems with strong robustness,high convergence speed,and high convergence accuracy.For further verification,HS-CS is used to optimize the back propagation neural network(BPNN)to extract weighted fuzzy production rules.Simulation results show that the BPNN optimized by HS-CS can obtain higher classification accuracy of weighted fuzzy production rules.Therefore,the proposed HS-CS is proved to be effective. 展开更多
关键词 Harmony search algorithm Cuckoo search algorithm Global convergence Function optimization Weighted fuzzy production ruleextraction
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Room temperature in-situ preparation of hydrazine-linked covalent organic frameworks coated capillaries for separation and determination of polycyclic aromatic hydrocarbons
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作者 Yanli Zhang Wenjuan Lv +5 位作者 fangling wang Xiao Niu Guoxiu wang Xuequan Wu Xiaoyun Zhang Xingguo Chen 《Frontiers of Chemical Science and Engineering》 SCIE EI CSCD 2023年第5期548-556,共9页
Covalent organic frameworks(COFs)have been increasingly used in capillary electrochromatography due to their excellent characteristics.In this work,hydrazine-linked TFPB-DHzDS(TFPB:1,3,5-tris(4-formylphenyl)benzene;DH... Covalent organic frameworks(COFs)have been increasingly used in capillary electrochromatography due to their excellent characteristics.In this work,hydrazine-linked TFPB-DHzDS(TFPB:1,3,5-tris(4-formylphenyl)benzene;DHzDS:2,5-bis(3-(ethylthio)propoxy)terephthalohydrazide)was first synthesized by a simpler and easier method at room temperature and introduced into capillary electrochromatography as coating material.The TFPB-DHzDS coated capillaries were prepared by an in-situ growth process at room temperature.After optimizing the coating concentration and experimental conditions of capillary electrochromatography,baseline separation of two groups of polycyclic aromatic hydrocarbons was achieved based on the TFPB-DHzDS coated capillary.And the established method was used successfully to determine PAHs in natural water and soil samples.The spiked recoveries of polycyclic aromatic hydrocarbons in these samples ranged from 90.01%to 111.0%,indicating that the method is reliable and could detect polycyclic aromatic hydrocarbons in natural samples.Finally,molecular simulation was applied to study and visualize the interaction between the analytes and coating COF materials to investigate the molecular level separation mechanism further. 展开更多
关键词 hydrazine-linked TFPB-DHzDS in-situ growth method open-tubular capillary electrochromatography molecular simulations
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