Poly <span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><spa...Poly <span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:Verdana;"> (PLA) is a biodegradable polymer which originates from natural resources such as corn</span><span style="font-family:Verdana;"> and</span><span style="font-family:Verdana;"> starch</span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> offering excellent strength, biode</span><span style="font-family:Verdana;">gradability</span></span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;"> nevertheless its inherent brittleness and low impact resistance</span><span style="font-family:Verdana;"> properties ha</span><span style="font-family:Verdana;">ve</span><span style="font-family:Verdana;"> limited its application. On the other hand</span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> Thermoplastic Polyu</span><span style="font-family:Verdana;">rethane (TPU) has high toughness, durability and flexibility</span></span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;"> which </span><span style="font-family:Verdana;">is</span><span style="font-family:Verdana;"> one of</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> the </span><span style="font-family:Verdana;">most potential alternatives for enhancing the flexibility and mechanical</span><span style="font-family:Verdana;"> strength of Poly </span></span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> (PLA) by blending it with a compati</span><span style="font-family:Verdana;">bilizer. With the aim to improve the mechanical and thermal properties of</span><span style="font-family:Verdana;"> Poly </span></span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> (PLA) </span><span style="font-family:Verdana;">meltblown nonwovens, The Thermoplastic Polyurethane (TPU) was melt</span><span style="font-family:Verdana;"> blend</span></span><span style="font-family:Verdana;">ed with Poly </span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:Verdana;"> (PLA) at the different corresponding proportions for toughening the Poly </span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:Verdana;"> and the corresponding PLA/TPU MBs (meltblown nonwovens) were also manufactured. Joncryl ADR 4400 </span><span style="font-family:Verdana;">is</span><span style="font-family:Verdana;"> mixed </span><span style="font-family:Verdana;">in</span><span style="font-family:Verdana;">to the PLA matrix during processing. It was found that Joncryl had </span><span style="font-family:Verdana;">a </span><span style="font-family:;" "=""><span style="font-family:Verdana;">much higher chain extension that substantially in</span><span style="font-family:Verdana;">creased the molecular weight of the PLA matrix. SEM study revealed that Joncryl ADR 4400 is a good compatibi</span><span style="font-family:Verdana;">lizer</span></span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> Moreover, in this study</span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> the crystallization, thermal and rheological behaviors </span><span style="font-family:Verdana;">of the corresponding PLA and TPU blends were also investigated. PLA/TPU</span><span style="font-family:Verdana;"> MBs were also characterized by</span> <span style="font-family:Verdana;">morphology and mechanical properties. The rheological property of the</span><span style="font-family:Verdana;"> PLA/TPU meltblown nonwoven revealed that the viscosity </span><span style="font-family:Verdana;">is increasing as the amount of TPU is increasing in the blend, PLA/TPU</span><span style="font-family:Verdana;"> melt</span></span><span style="font-family:Verdana;">blown nonwovens exhibited excellent mechanical properties;they are soft, </span><span style="font-family:;" "=""><span style="font-family:Verdana;">elas</span><span style="font-family:Verdana;">tic, and have certain tensile strength. New materials have potential applica</span><span style="font-family:Verdana;">tions in the medical and agri</span><span style="font-family:Verdana;">cultural field</span></span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;">. Joncryl ADR 4400 compatibilized blends showed higher</span><span style="font-family:Verdana;"> strength than simple PLA/TPU blends at the same PLA/TPU ratio.</span>展开更多
Metal-organic frameworks(MOFs)are attractive for promising applications but plagued by difficult recovery and deployment due to their intrinsic nano/micro powder nature.Although significant efforts have been made to d...Metal-organic frameworks(MOFs)are attractive for promising applications but plagued by difficult recovery and deployment due to their intrinsic nano/micro powder nature.Although significant efforts have been made to develop separable solid matrixes for MOF supporting,the poor loading stability and durability of MOFs still challenge their engineering applications.Here,we present a facile and effective approach to fabricate MOF-based melamine foams(MFs)(denoted as MOFiths)with ultrahigh loading stability and operation stability,easy separation,and high-efficient performance for versatile robust applications.By adopting our approach,numbers of typical fragile MOFs characterized with wide ranges of particle size(from~nm to~μm)can be precisely incorporated into MFs with controllable loading ratios(up to~1,600%).Particularly,the produced MOFiths show excellent capacities for the highly effective and durable water purifications and acetalization reactions.100%of organic pollutants can be rapidly destructed within 10 min by MOFiths initiated Fenton or catalytic ozonation processes under five successive cycles while the maximum adsorption capacity of MOFiths toward Pb(II),Cd(II),and Cu(II)reaches to 422,222,and 105 mg·g^(-1),respectively.This study provides a critical solution to substantially facilitate the engineering applications of MOFs for long-term use in practice.展开更多
文摘Poly <span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:Verdana;"> (PLA) is a biodegradable polymer which originates from natural resources such as corn</span><span style="font-family:Verdana;"> and</span><span style="font-family:Verdana;"> starch</span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> offering excellent strength, biode</span><span style="font-family:Verdana;">gradability</span></span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;"> nevertheless its inherent brittleness and low impact resistance</span><span style="font-family:Verdana;"> properties ha</span><span style="font-family:Verdana;">ve</span><span style="font-family:Verdana;"> limited its application. On the other hand</span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> Thermoplastic Polyu</span><span style="font-family:Verdana;">rethane (TPU) has high toughness, durability and flexibility</span></span><span style="font-family:Verdana;">,</span><span style="font-family:Verdana;"> which </span><span style="font-family:Verdana;">is</span><span style="font-family:Verdana;"> one of</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> the </span><span style="font-family:Verdana;">most potential alternatives for enhancing the flexibility and mechanical</span><span style="font-family:Verdana;"> strength of Poly </span></span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> (PLA) by blending it with a compati</span><span style="font-family:Verdana;">bilizer. With the aim to improve the mechanical and thermal properties of</span><span style="font-family:Verdana;"> Poly </span></span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> (PLA) </span><span style="font-family:Verdana;">meltblown nonwovens, The Thermoplastic Polyurethane (TPU) was melt</span><span style="font-family:Verdana;"> blend</span></span><span style="font-family:Verdana;">ed with Poly </span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:Verdana;"> (PLA) at the different corresponding proportions for toughening the Poly </span><span style="font-family:Verdana;">(</span><span style="font-family:Verdana;">Lactic Acid</span><span style="font-family:Verdana;">)</span><span style="font-family:Verdana;"> and the corresponding PLA/TPU MBs (meltblown nonwovens) were also manufactured. Joncryl ADR 4400 </span><span style="font-family:Verdana;">is</span><span style="font-family:Verdana;"> mixed </span><span style="font-family:Verdana;">in</span><span style="font-family:Verdana;">to the PLA matrix during processing. It was found that Joncryl had </span><span style="font-family:Verdana;">a </span><span style="font-family:;" "=""><span style="font-family:Verdana;">much higher chain extension that substantially in</span><span style="font-family:Verdana;">creased the molecular weight of the PLA matrix. SEM study revealed that Joncryl ADR 4400 is a good compatibi</span><span style="font-family:Verdana;">lizer</span></span><span style="font-family:Verdana;">.</span><span style="font-family:Verdana;"> Moreover, in this study</span><span style="font-family:Verdana;">,</span><span style="font-family:;" "=""><span style="font-family:Verdana;"> the crystallization, thermal and rheological behaviors </span><span style="font-family:Verdana;">of the corresponding PLA and TPU blends were also investigated. PLA/TPU</span><span style="font-family:Verdana;"> MBs were also characterized by</span> <span style="font-family:Verdana;">morphology and mechanical properties. The rheological property of the</span><span style="font-family:Verdana;"> PLA/TPU meltblown nonwoven revealed that the viscosity </span><span style="font-family:Verdana;">is increasing as the amount of TPU is increasing in the blend, PLA/TPU</span><span style="font-family:Verdana;"> melt</span></span><span style="font-family:Verdana;">blown nonwovens exhibited excellent mechanical properties;they are soft, </span><span style="font-family:;" "=""><span style="font-family:Verdana;">elas</span><span style="font-family:Verdana;">tic, and have certain tensile strength. New materials have potential applica</span><span style="font-family:Verdana;">tions in the medical and agri</span><span style="font-family:Verdana;">cultural field</span></span><span style="font-family:Verdana;">s</span><span style="font-family:Verdana;">. Joncryl ADR 4400 compatibilized blends showed higher</span><span style="font-family:Verdana;"> strength than simple PLA/TPU blends at the same PLA/TPU ratio.</span>
基金This work was supported by the National Natural Science Foundation of China(No.22106141)the Key Research and Development Program of Zhejiang Province(No.2018C03004)+1 种基金the Scientific Launching Funding of Zhejiang Sci-Tech University and the Postdoctoral Program(No.TYY202103)of Zhejiang Sci-Tech University Tongxiang Research InstituteThe authors also acknowledge the support by the Brook Byers Institute for Sustainable Systems,Hightower Chair and the Georgia Research Alliance at the Georgia Institute of Technology.The views and ideas expressed herein are solely those of the authors’and do not represent the ideas of the funding agencies in any form。
文摘Metal-organic frameworks(MOFs)are attractive for promising applications but plagued by difficult recovery and deployment due to their intrinsic nano/micro powder nature.Although significant efforts have been made to develop separable solid matrixes for MOF supporting,the poor loading stability and durability of MOFs still challenge their engineering applications.Here,we present a facile and effective approach to fabricate MOF-based melamine foams(MFs)(denoted as MOFiths)with ultrahigh loading stability and operation stability,easy separation,and high-efficient performance for versatile robust applications.By adopting our approach,numbers of typical fragile MOFs characterized with wide ranges of particle size(from~nm to~μm)can be precisely incorporated into MFs with controllable loading ratios(up to~1,600%).Particularly,the produced MOFiths show excellent capacities for the highly effective and durable water purifications and acetalization reactions.100%of organic pollutants can be rapidly destructed within 10 min by MOFiths initiated Fenton or catalytic ozonation processes under five successive cycles while the maximum adsorption capacity of MOFiths toward Pb(II),Cd(II),and Cu(II)reaches to 422,222,and 105 mg·g^(-1),respectively.This study provides a critical solution to substantially facilitate the engineering applications of MOFs for long-term use in practice.