Water electrolysis at high current density(1000 mA cm-2 level)with excellent durability especially in neutral electrolyte is the pivotal issue for green hydrogen from experiment to industrialization.In addition to the...Water electrolysis at high current density(1000 mA cm-2 level)with excellent durability especially in neutral electrolyte is the pivotal issue for green hydrogen from experiment to industrialization.In addition to the high intrinsic activity determined by the electronic structure,electrocatalysts are also required to be capable of fast mass transfer(electrolyte recharge and bubble overflow)and high mechanical stability.Herein,the 2D CoOOH sheet-encapsulated Ni2P into tubular arrays electrocatalytic system was proposed and realized 1000 mA cm-2-levelcurrent-density hydrogen evolution over 100 h in neutral water.In designed catalysts,2D stack structure as an adaptive material can buffer the shock of electrolyte convection,hydrogen bubble rupture,and evolution through the release of stress,which insure the long cycle stability.Meanwhile,the rich porosity between stacked units contributed the good infiltration of electrolyte and slippage of hydrogen bubbles,guaranteeing electrolyte fast recharge and bubble evolution at the high-current catalysis.Beyond that,the electron structure modulation induced by interfacial charge transfer is also beneficial to enhance the intrinsic activity.Profoundly,the multiscale coordinated regulation will provide a guide to design high-efficiency industrial electrocatalysts.展开更多
In this study, we determined carbon allocation and carbon stocks in the plant-soil system of different dune ecosystems in northeastern China. We quantified the species composition, above- and below-ground biomasses, a...In this study, we determined carbon allocation and carbon stocks in the plant-soil system of different dune ecosystems in northeastern China. We quantified the species composition, above- and below-ground biomasses, and carbon stocks of three dune types(i.e. active dunes, semi-stabilized dunes and stabilized dunes) and their corresponding inter-dune lowlands(i.e. interdune lowlands of active dunes, interdune lowlands of semi-stabilized dunes and interdune lowlands of stabilized dunes) in the Horqin Sandy Land. The results showed that the succession series on interdune lowlands of the Horqin Sandy Land confirmed differences in species composition of the various dune types. Aboveground carbon(AGC) on the interdune lowlands of semi-stabilized dunes(33.04 g C/m2) was greater(P<0.05) than that on the interdune lowlands of active dunes(10.73 g C/m2). At the same time, the different dune types did not show any significant differences(P>0.05) in belowground plant carbon(BGC). However, the percentage of plant BGC in interdune lowlands of active dunes(81.5%) was significantly higher(P<0.05) than that in the interdune lowlands of semi-stabilized dunes(58.9%). The predominant carbon pool in the study dune ecosystem was in the soil. It accounted for 95% to 99% of total carbon storage. Soil organic carbon(SOC) was at least 55% greater(P<0.05) in the interdunes than in the dunes. Stabilized dunes showed at least a 37% greater(P<0.05) SOC content than active dunes up to a 1-m soil depth. Meanwhile, SOC content of interdune lowlands of semi-stabilized dunes was greater(P<0.05) than that of interdune lowlands of active dunes only up to a 20-cm soil depth. The dune ecosystem showed a great potential to store carbon when interdune lowlands of active dunes were conversed to interdune lowlands of semi-stabilized dunes, which stored up to twice as much carbon per unit volume as interdune lowlands of active dunes.展开更多
An ultrafast fiber laser system comprising two coherently combined amplifier channels is reported.Within this system,each channel incorporates a rod-type fiber power amplifier,with individual operations reaching appro...An ultrafast fiber laser system comprising two coherently combined amplifier channels is reported.Within this system,each channel incorporates a rod-type fiber power amplifier,with individual operations reaching approximately 233 W.The active-locking of these coherently combined channels,followed by compression using gratings,yields an output with a pulse energy of 504μJ and an average power of 403 W.Exceptional stability is maintained,with a 0.3%root mean square(RMS)deviation and a beam quality factor M^(2)<1.2.Notably,precise dispersion management of the front-end seed light effectively compensates for the accumulated high-order dispersion in subsequent amplification stages.This strategic approach results in a significant reduction in the final output pulse duration for the coherently combined laser beam,reducing it from 488 to 260 fs after the gratings compressor,while concurrently enhancing the energy of the primary peak from 65%to 92%.展开更多
The effective separation and migration of photogenerated charge carriers in bulk and on the surface of photocatalysts will significantly promote photocatalytic efficiency.However,the synchronous regulation of photocha...The effective separation and migration of photogenerated charge carriers in bulk and on the surface of photocatalysts will significantly promote photocatalytic efficiency.However,the synchronous regulation of photocharges on both counts is challenging.Herein,the simultaneous separation of bulk and surface photocharges is conducted to enhance photocatalytic activity by coupling the surface defects and lattice engineering of bismuth oxybromide.The depth-modulated Bi_(5)O_(7)Br ultrathin nanosheets with an abundance of bismuth in the crystal structure increased the internal electric field,which propelled the separation and migration of photocharges from bulk to the surface.Creation of oxygen vacancies(OVs)on the nanosheet surface forms local electric fields,which can stimulate the migration of charges to active sites on the catalyst surface.Therefore,the OV-assembled Bi_(5)O_(7)Br nanosheets demonstrated enhanced photocatalytic degradation efficiency under simulated solar-light illumination.This study proved the possibility of charge governing via electric field modulation based on an integrated strategy.展开更多
Although tremendous efforts have been paid on electrocatalysts toward efficient electrochemical hydrogen generation,breakthrough is still highly needed in the design and synthesis of wonderful non-precious-metal elect...Although tremendous efforts have been paid on electrocatalysts toward efficient electrochemical hydrogen generation,breakthrough is still highly needed in the design and synthesis of wonderful non-precious-metal electrocatalyst.Herein,a nanovilli Ni2P electrode,which with superaerophobic and superhydropholic can significantly facilitate the mass and electron transfer was constructed via a facial morphology control strategy.Meanwhile,the substitution of sluggish oxygen evolution with urea oxidation,lowering the two-electrode cell voltage to only 1.48 volts to achieve a current density of 10 mA·cm^(-2).Thus,the as-constructed electrode achieves the operation of hydrogen generation by an AA battery.This work sheds new light on the exploration of other high-efficient electrocatalysts for hydrogen generation by using intermittent clean energy.展开更多
基金financially supported by the National Natural Science Foundation of China(21761004,21805102,21701035 and 21825103)the Hubei Provincial Natural Science Foundation of China(2019CFA002)+2 种基金the specific research project of Guangxi for research bases and talents(AD18126005)the Fundamental Research Funds for the Central University(Grant No.2019kfyXMBZ018)the training program for thousands of backbone young teachers in Guangxi universities。
文摘Water electrolysis at high current density(1000 mA cm-2 level)with excellent durability especially in neutral electrolyte is the pivotal issue for green hydrogen from experiment to industrialization.In addition to the high intrinsic activity determined by the electronic structure,electrocatalysts are also required to be capable of fast mass transfer(electrolyte recharge and bubble overflow)and high mechanical stability.Herein,the 2D CoOOH sheet-encapsulated Ni2P into tubular arrays electrocatalytic system was proposed and realized 1000 mA cm-2-levelcurrent-density hydrogen evolution over 100 h in neutral water.In designed catalysts,2D stack structure as an adaptive material can buffer the shock of electrolyte convection,hydrogen bubble rupture,and evolution through the release of stress,which insure the long cycle stability.Meanwhile,the rich porosity between stacked units contributed the good infiltration of electrolyte and slippage of hydrogen bubbles,guaranteeing electrolyte fast recharge and bubble evolution at the high-current catalysis.Beyond that,the electron structure modulation induced by interfacial charge transfer is also beneficial to enhance the intrinsic activity.Profoundly,the multiscale coordinated regulation will provide a guide to design high-efficiency industrial electrocatalysts.
基金financially supported by the National Basic Research Program of China (2013CB429905-01)the sabbatical leave given by Agronomy Department, National University of the South and CERZOS (CONICET)+1 种基金the associateship awarded by the Third World Academy of Sciences (TWAS)- UNESCOhousing, facilities and financial support from the Institute of Applied Ecology, Chinese Academy of Sciences
文摘In this study, we determined carbon allocation and carbon stocks in the plant-soil system of different dune ecosystems in northeastern China. We quantified the species composition, above- and below-ground biomasses, and carbon stocks of three dune types(i.e. active dunes, semi-stabilized dunes and stabilized dunes) and their corresponding inter-dune lowlands(i.e. interdune lowlands of active dunes, interdune lowlands of semi-stabilized dunes and interdune lowlands of stabilized dunes) in the Horqin Sandy Land. The results showed that the succession series on interdune lowlands of the Horqin Sandy Land confirmed differences in species composition of the various dune types. Aboveground carbon(AGC) on the interdune lowlands of semi-stabilized dunes(33.04 g C/m2) was greater(P<0.05) than that on the interdune lowlands of active dunes(10.73 g C/m2). At the same time, the different dune types did not show any significant differences(P>0.05) in belowground plant carbon(BGC). However, the percentage of plant BGC in interdune lowlands of active dunes(81.5%) was significantly higher(P<0.05) than that in the interdune lowlands of semi-stabilized dunes(58.9%). The predominant carbon pool in the study dune ecosystem was in the soil. It accounted for 95% to 99% of total carbon storage. Soil organic carbon(SOC) was at least 55% greater(P<0.05) in the interdunes than in the dunes. Stabilized dunes showed at least a 37% greater(P<0.05) SOC content than active dunes up to a 1-m soil depth. Meanwhile, SOC content of interdune lowlands of semi-stabilized dunes was greater(P<0.05) than that of interdune lowlands of active dunes only up to a 20-cm soil depth. The dune ecosystem showed a great potential to store carbon when interdune lowlands of active dunes were conversed to interdune lowlands of semi-stabilized dunes, which stored up to twice as much carbon per unit volume as interdune lowlands of active dunes.
基金supported by the National Natural Science Foundation of China(NSFC)(Grant Nos.9215010612021004,and 11934006)the Innovation Project of Optics Valley Laboratory(No.OVL2021ZD001),the Major Program(JD)of Hubei Province(No.203BAA015)the Cross Research Support Program of Huazhong University of Science and Technology(No.2023JCYJ041).
文摘An ultrafast fiber laser system comprising two coherently combined amplifier channels is reported.Within this system,each channel incorporates a rod-type fiber power amplifier,with individual operations reaching approximately 233 W.The active-locking of these coherently combined channels,followed by compression using gratings,yields an output with a pulse energy of 504μJ and an average power of 403 W.Exceptional stability is maintained,with a 0.3%root mean square(RMS)deviation and a beam quality factor M^(2)<1.2.Notably,precise dispersion management of the front-end seed light effectively compensates for the accumulated high-order dispersion in subsequent amplification stages.This strategic approach results in a significant reduction in the final output pulse duration for the coherently combined laser beam,reducing it from 488 to 260 fs after the gratings compressor,while concurrently enhancing the energy of the primary peak from 65%to 92%.
基金This work was supported by the National Natural Science Foundation of China(No.52002089)the innovation team of Xiangsi Lake Young Scholars of Guangxi Minzu University(No.2020RSCXSHQN06)the training program for thousands of backbone young teachers in Guangxi universities,and the undergraduate innovation and entrepreneurship project of Guangxi Minzu University(No.202110608002).
文摘The effective separation and migration of photogenerated charge carriers in bulk and on the surface of photocatalysts will significantly promote photocatalytic efficiency.However,the synchronous regulation of photocharges on both counts is challenging.Herein,the simultaneous separation of bulk and surface photocharges is conducted to enhance photocatalytic activity by coupling the surface defects and lattice engineering of bismuth oxybromide.The depth-modulated Bi_(5)O_(7)Br ultrathin nanosheets with an abundance of bismuth in the crystal structure increased the internal electric field,which propelled the separation and migration of photocharges from bulk to the surface.Creation of oxygen vacancies(OVs)on the nanosheet surface forms local electric fields,which can stimulate the migration of charges to active sites on the catalyst surface.Therefore,the OV-assembled Bi_(5)O_(7)Br nanosheets demonstrated enhanced photocatalytic degradation efficiency under simulated solar-light illumination.This study proved the possibility of charge governing via electric field modulation based on an integrated strategy.
基金the National Natural Science Foundation of China(Nos.21761004,21701035)the Natural Science Foundation of Guangxi(Nos.2018GXNSFBA281085,2018GXNSFAA138126)+3 种基金Specific research project of Guangxi for research bases and talents(Nos.AD18126002,AD18126005)the foundation ability enhancement project of young teachers in Guangxi universities(No.2018KY0163)the Guangxi University for Nationalities Graduate Education Innovation Project(No.gxun-chxzs201916)the 100 Talents Program for Introducing Overseas High-level Talents into Universities of Guangxi and the training program for thousands of backbone young teachers in Guangxi universities.
文摘Although tremendous efforts have been paid on electrocatalysts toward efficient electrochemical hydrogen generation,breakthrough is still highly needed in the design and synthesis of wonderful non-precious-metal electrocatalyst.Herein,a nanovilli Ni2P electrode,which with superaerophobic and superhydropholic can significantly facilitate the mass and electron transfer was constructed via a facial morphology control strategy.Meanwhile,the substitution of sluggish oxygen evolution with urea oxidation,lowering the two-electrode cell voltage to only 1.48 volts to achieve a current density of 10 mA·cm^(-2).Thus,the as-constructed electrode achieves the operation of hydrogen generation by an AA battery.This work sheds new light on the exploration of other high-efficient electrocatalysts for hydrogen generation by using intermittent clean energy.
