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配合物[Ni(Me_(3)en)(acac)]BPh_(4)合成、分析实验实施结果与讨论——第10届全国大学生化学实验邀请赛无机及分析化学实验试题部分内容实施结果与讨论 被引量:1
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作者 董志强 陈欣 +6 位作者 王凤彬 王庆 陶友荣 阮婵姿 张春艳 章文伟 任艳平 《大学化学》 CAS 2023年第5期325-334,共10页
介绍南京大学为第10届全国大学生化学实验邀请赛设计的无机及分析化学实验试题,即“配合物[Ni(Me_(3)en)(acac)]BPh_(4)的合成及其溶剂/热致变色行为研究”实验中有关合成及组成测定部分实验实施过程、结果及其拓展问题的探讨内容。以... 介绍南京大学为第10届全国大学生化学实验邀请赛设计的无机及分析化学实验试题,即“配合物[Ni(Me_(3)en)(acac)]BPh_(4)的合成及其溶剂/热致变色行为研究”实验中有关合成及组成测定部分实验实施过程、结果及其拓展问题的探讨内容。以所展示的详细直观的合成实验流程为载体,围绕着合成两大目标“质”和“量”,即如何才能得到又“好”又“多”的[Ni(Me_(3)en)(acac)]BPh_(4)配合物的问题为导向,以设问、探讨的方式引导学生认识合成过程中实验条件的控制、实验现象的分析以及中间产物及杂质的分离、分析鉴定等对指导合成的意义,培养学生分析、判断、归纳、总结的能力以及批判性思维能力。 展开更多
关键词 NI(II)配合物 合成 组成测定 问题分析与探讨
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基础化学实验教学的新理念——再议实验教学之本质 被引量:6
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作者 芦昌盛 王凤彬 +2 位作者 刘斌 田笑丛 马海凤 《大学化学》 CAS 2022年第1期6-13,共8页
最近20年以来,国内高校的本科基础化学实验教学从理念、内容、标准,到组织机构和评价方法,都经历了一系列变化和改革。立足于新的历史机遇和时代,有必要深刻理解和厘清本科阶段基础化学实验教学的本质和角色,既不轻视和简慢其地位、也... 最近20年以来,国内高校的本科基础化学实验教学从理念、内容、标准,到组织机构和评价方法,都经历了一系列变化和改革。立足于新的历史机遇和时代,有必要深刻理解和厘清本科阶段基础化学实验教学的本质和角色,既不轻视和简慢其地位、也不夸大和拔高其效用;须还基础实验教学以其本来面目,着重深挖其在传播"第三类知识"(Knowhow)以及培养"元认知"能力当中的不可替代作用,才能在化学实验教学改革大潮中不懈怠、不迷惘。 展开更多
关键词 实验教学 第三类知识 元认知 教学理念 教学改革
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2型糖尿病患者直接支持和间接支持量表的研制与信效度检验 被引量:1
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作者 张旭熙 张幸 +5 位作者 王冯斌 吴士艳 胡康 玛依努尔·于苏甫 孙昕霙 Edwin B.Fisher 《International Journal of Nursing Sciences》 CSCD 2020年第4期453-459,I0007,共8页
目的本研究旨在开发2型糖尿病患者直接支持和间接支持量表,用来测量糖尿病患者获得的直接支持和间接支持以及患者偏好,并评估该量表的信度和效度。方法本研究采用了2015年7月至9月进行的北京市通州区社区诊断项目的横断面调查数据进行分... 目的本研究旨在开发2型糖尿病患者直接支持和间接支持量表,用来测量糖尿病患者获得的直接支持和间接支持以及患者偏好,并评估该量表的信度和效度。方法本研究采用了2015年7月至9月进行的北京市通州区社区诊断项目的横断面调查数据进行分析,共纳入474例2型糖尿病患者。根据已有研究结果和专家建议,设计了关于从家人和朋友那里获得的直接支持和间接支持、包含11个条目的原始量表。原始量表中,5个条目(第1~5条)为间接支持,6个条目(第6~11条)为直接支持。每个条目有两个平行问题,一个用于衡量对支持的偏好(“偏好”部分),另一个用于衡量现实中获得的支持(“现实”部分)。应用探索性因子分析评估原始11条目量表的结构效度并确定最终版量表。应用验证性因子分析评估最终版量表的结构效度。使用Cronbach'sα系数评估量表的内部一致性,进而用于评估最终版量表的信度。结果通过探索性因子分析确定最终版7条目量表,共2个因子,4个条目为间接支持,3个条目为直接支持。验证性因子分析显示7条目量表模型拟合良好,结构效度较好。7条目量表以及间接支持部分条目的内部一致性良好,Cronbach'sα系数≥7.0。结论本研究显示7条目的2型糖尿病患者直接支持和间接支持量表具有较好的信度和效度。未来需要对该量表在不同环境和人群中的应用做进一步研究。 展开更多
关键词 糖尿病 直接支持 间接支持 患者意愿 自我护理 社会支持
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南疆枸杞木虱发生规律及绿色防控技术研究
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作者 刘泽辉 祁臻 +5 位作者 罗琳 熊美军 王奉斌 陈强 余彩虹 孙宁川 《农业科学》 2018年第4期294-299,共6页
随着农业供给侧结构性改革纵深发展,近几年南疆各地枸杞种植面积持续增加,枸杞木虱危害不断加重。枸杞木虱一年发生5代,中后期各种虫态均共存。南疆枸杞木虱3代中期与4代前期叠加,4代末期与5代前中期叠加,形成两次超高峰,引起7月中下旬... 随着农业供给侧结构性改革纵深发展,近几年南疆各地枸杞种植面积持续增加,枸杞木虱危害不断加重。枸杞木虱一年发生5代,中后期各种虫态均共存。南疆枸杞木虱3代中期与4代前期叠加,4代末期与5代前中期叠加,形成两次超高峰,引起7月中下旬与9月中下旬两次叶片全部枯死脱落。木虱在南疆全年危害大,繁殖力强,世代重叠严重,发生量大,呈爆发成灾局势,防治不力会造成毁灭性的危害。笔者通过绿色防控与统防统治相融合、科学合理用药、大面积防治等措施减弱木虱迁飞危害,减少化学农药使用量,为零残留、绿色生态枸杞产业发展提供技术保障。 展开更多
关键词 南疆 枸杞木虱 种群动态 发生危害 绿色防控
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Advances in Research on Drought Resistance in Rice
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作者 Yueming YI Shimei wang +4 位作者 Xinxin CHENG Qian ZHU Yiru LI fengbin wang Minghua ZHANG 《Agricultural Biotechnology》 CAS 2022年第5期26-33,共8页
Rice is the main grain crop in China. With global warming, drought and water shortage have become one of the important factors limiting rice production. Improving the drought resistance of rice can effectively allevia... Rice is the main grain crop in China. With global warming, drought and water shortage have become one of the important factors limiting rice production. Improving the drought resistance of rice can effectively alleviate the loss of rice yield caused by drought. In this paper, the research progress on rice drought resistance and its evaluation methods, mapping of QTLs for drought resistance-related traits, and mining for drought resistance genes were reviewed, and molecular breeding for drought resistance in rice was prospected. 展开更多
关键词 RICE Drought resistance Methods of identification and evaluation QTL mapping
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Characterization and prediction of tailpipe ammonia emissions from in-use China 5/6 light-duty gasoline vehicles
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作者 Lewei Zeng fengbin wang +8 位作者 Shupei Xiao Xuan Zheng Xintong Li Qiyuan Xie Xiaoyang Yu Cheng Huang Qingyao Hu Yan You Ye Wu 《Frontiers of Environmental Science & Engineering》 SCIE EI CSCD 2024年第1期71-81,共11页
On-road tailpipe ammonia (NH3) emissions contribute to urban secondary organic aerosol formation and have direct or indirect adverse impacts on the environment and human health. To understand the tailpipe NH3 emission... On-road tailpipe ammonia (NH3) emissions contribute to urban secondary organic aerosol formation and have direct or indirect adverse impacts on the environment and human health. To understand the tailpipe NH3 emission characteristics, we performed comprehensive chassis dynamometer measurements of NH3 emission from two China 5 and two China 6 light-duty gasoline vehicles (LDGVs) equipped with three-way catalytic converters (TWCs). The results showed that the distance-based emission factors (EFs) were 12.72 ± 2.68 and 3.18 ± 1.37 mg/km for China 5 and China 6 LDGVs, respectively. Upgrades in emission standards were associated with a reduction in tailpipe NH3 emission. In addition, high NH3 EFs were observed during the engine warm-up period in cold-start cases owing to the intensive emissions of incomplete combustion products and suitable catalytic temperature in the TWCs. Notably, based on the instantaneous NH3 emission rate, distinct NH3–emitting events were detected under high/extra high velocity or rapid acceleration. Furthermore, NH3 emission rates correlated well with engine speed, vehicle specific power, and modified combustion efficiency, which were more easily accessible. These strong correlations were applied to reproduce NH3 emissions from China 5/6 LDGVs. The predicted NH3 EFs under different dynamometer and real-world cycles agreed well with existing measurement and prediction results, revealing that the NH3 EFs of LDGVs in urban routes were within 8.55–11.62 mg/km. The results presented here substantially contribute to improving the NH3 emission inventory for LDGVs and predicting on-road NH3 emissions in China. 展开更多
关键词 NH3 instantaneous emissions Catalytic temperature Vehicle specific power Combustion efficiency Emission prediction
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The dual role of ubiquitin-like protein Urm1 as a protein modifier and sulfur carrier
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作者 fengbin wang Meiruo Liu +1 位作者 Rui Qiu Chaoneng Ji 《Protein & Cell》 SCIE CSCD 2011年第8期612-619,共8页
The ubiquitin-related modifier Urm1 can be covalently conjugated to lysine residues of other proteins,such as yeast Ahp1 and human MOCS3,through a mechanism involving the E1-like protein Uba4(MOCS3 in humans).Similar ... The ubiquitin-related modifier Urm1 can be covalently conjugated to lysine residues of other proteins,such as yeast Ahp1 and human MOCS3,through a mechanism involving the E1-like protein Uba4(MOCS3 in humans).Similar to ubiquitination,urmylation requires a thioester intermediate and forms isopeptide bonds between Urm1 and its substrates.In addition,the urmylation process can be significantly enhanced by oxidative stress.Recent findings have demonstrated that Urm1 also acts as a sulfur carrier in the thiolation of eukaryotic tRNA via a mechanism that requires the formation of a thiocarboxylated Urm1.This role is very similar to that of prokaryotic sulfur carriers such as MoaD and ThiS.Evidence strongly supports the hypothesis that Urm1 is the molecular fossil in the evolutionary link between prokaryotic sulfur carriers and eukaryotic ubiquitin-like proteins.In the present review,we discuss the dual role of Urm1 in protein and tRNA modification. 展开更多
关键词 Urm1 system tRNA modification Ub-like protein modification
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Microstructures and dynamic processes within the five-phase system:Regarding COVID-19 as a complex system
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作者 fengbin wang Xue Zhang 《Frontiers of Business Research in China》 2020年第3期303-323,共21页
The research uses the development of 2019 novel coronavirus disease(COVID-19)in the human body as an example to explore the microstructures and dynamic processes of a concise complex system from the lens of the five-p... The research uses the development of 2019 novel coronavirus disease(COVID-19)in the human body as an example to explore the microstructures and dynamic processes of a concise complex system from the lens of the five-phase system.Based on the structural balance theory and system dynamics,the research finds that Iransitive triads and cyclic triads in the fivephase system are both imbalanced.The integration of these differentiated triads comprises of a balaneed intermediate form in the shape of quadrangular cycles.These cycles serve as microstructures of the five-phase system,due to the inherent balancing feedback mechanism,and support the generation of resultants.The alter nation of quadra ngular cycles drives the spirali ng development of the whole system.By orderly and regular in terweaving of sig ned directed links,the research provides a holistic,process-oriented demonstrati on for the developme nt processes of COVID-19.It clarifies that the esse nee of the five-phase system is phase-tra nsition processes with the quadrangular cycle as carrier and supporter,rather than the static aggregati on of five elements.The research deep ens the understanding of system non linearity by visualizi ng the circular causality and promotes the academic dialogue between the Western process theory and the Chinese inherited notion of the fivephase system. 展开更多
关键词 Five-phase system 2019 novel coronavirus disease(COVID-19) Balancing feedback Microstructure Spiraling process
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Compari ng the con figured causal antecedents of exploration and exploitation: a fuzzy set qualitative comparative analysis
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作者 Lulu Liu fengbin wang Xiukun Li 《Frontiers of Business Research in China》 2019年第1期53-77,共25页
Although exploration and exploitation, as a pair of paradoxical organizational outcomes, are generated by different causal conditions, the conjunction of their respective causal antecedents has yet to be fully examine... Although exploration and exploitation, as a pair of paradoxical organizational outcomes, are generated by different causal conditions, the conjunction of their respective causal antecedents has yet to be fully examined. Combining environmental uncertainty, unit interdependence, entrepreneurial bricolage and firm life cycle stage in a qualitative comparative analysis (QCA), the distinct causal configurations of exploration and exploitation are formalized and compared based on a survey of founders or high-level managers in 63 small firms. Results show that contrasted relationships between entrepreneurial bricolage and unit interdependenee exist in that the two antecedents are partial substitutes in exploration whereas they are complements in exploitation when combined with other conditions. This study provides empirical evidence on the causal configurations of exploration and exploitation and deepens our current understanding of ambidexterity. 展开更多
关键词 Exploration Exploitation AMBIDEXTERITY Configuration Qualitative comparative analysis (QCA) Environmental uncertainty ENTREPRENEURIAL BRICOLAGE Unit interdepe ndence
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Midea's Re-adoption of M-form Structure
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作者 fengbin wang Chi Zhang +1 位作者 Zhexiong Tao Chunyan Sun 《Frontiers of Business Research in China》 2016年第2期324-362,共39页
With a focus on the alignment between business strategies and organization design, this illustrative case study describes and analyzes the evolution and reform of Midea's organizational structure when confronting bot... With a focus on the alignment between business strategies and organization design, this illustrative case study describes and analyzes the evolution and reform of Midea's organizational structure when confronting both internal and external changes. As one of China's biggest and fastest-growing household appliance enterprises, Midea adopted, discarded and readopted an M-form~ organizational structure within a five-year period from 1997. This case study first investigates the reasons behind Midea's reform toward decentralization and the formation of governing rules to balance centralization and decentralization. Different decentralized structures are then contrasted basing on product segments, business streams or even key subsidiaries acting as second-tier group companies. After its trial transformation into an H-form company that holds majority shares in several incorporated subsidiaries, Midea chose to switch to a group company incorporated structure soon after its leadership transition in 2012. Preceding the shortening of the group's ownership chain was the construction, refinement, and evolution of its 9+2+4 divisional structure. This case study is prepared to provoke discussion and thoughts on the (re)design of a properly decentralized structure suitable for large-sized companies with multiple businesses and the links with external and internal factors. 展开更多
关键词 M-form structure organizational design structural evolution
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