碳点增敏的流动注射化学发光法测定食品中二氧化硫的含量

二氧化硫的检测对于食品安全保障具有重要意义。采用酸性高锰酸钾-亚硫酸盐化学发光体系,以碳点(Carbon Dots,CDs)为增敏剂,结合流动注射技术(Flow Injection Analysis,FIA)建立了一种用于检测食品中二氧化硫含量的简便方法。在优化的实验条件下,该方法的线性范围为1.0×10^(-5)–3.0×10^(-4) mol·L^(-1),检出限为7.79×10^(-6) mol·L^(-1)。该实验适合作为本科生仪器分析课程的教学实验,帮助学生掌握化学发光、流动注射分析技术的原理及应用,学习科学研究的基本方法,提高思考能力。

Effect Mechanisms of Hygrothermal Environments on Failure of Single-Lap and Double-Lap CFRP-Aluminum Bolted Joints

The high demands for load-carrying capability and structural efficiency of composite-metal bolted joints trigger in-depth investigations on failure mechanisms of the joints in hygrothermal environments.However,few studies have been presented to exhaustively reveal hygrothermal effects on the failure of CFRP-metal bolted joints,which differ from CFRP-CFRP or metal-metal bolted joints because of the remarkably different material properties of CFRPs and metals.In this paper,hygrothermal effects on tensile failures of single-lap and double-lap CFRP-aluminum bolted joints were experimentally and numerically investigated.A novel numerical model,in which a hygrothermal-included progressive damage model of composites was established and elastic-plastic models of metals were built,was proposed to predict the failures of the CFRP-metal bolted joints in hygrothermal environments and validated by corresponding experiments.Different failure mechanisms of single-lap and double-lap CFRP-aluminum bolted joints,under 23°C/Dry and 70°C/Wet conditions,were revealed,respectively.It follows that both the collapse failures of the single-lap and double-lap bolted joints were dominated by the bearing failure of the CFRP hole laminate in the two conditions,indicating that the hygrothermal environment did not change the macro failure modes of the joints.However,the hygrothermal environment considerably shortened the damage propagation processes and reduced the strength of the joints.Besides,the hygrothermal environment weakened the load-transfer capability of the single-lap joint more severely than the double-lap joint because it aggravated the secondary bending effects of the single-lap joint obviously.

Bearing Failure Optimization of Composite Double-Lap Bolted Joints Based on a Three-Step Strategy Marked By Feasible Region Reduction and Model Decoupling

To minimize the mass and increase the bearing failure load of composite double-lap bolted joints,a three-step optimization strategy including feasible region reduction,optimization model decoupling and optimization was presented.In feasible region reduction,the dimensions of the feasible design region were reduced by selecting dominant design variables from numerous multilevel parameters by sensitivity analyses,and the feasible regions of variables were reduced by influence mechanism analyses.In model decoupling,the optimization model with a large number of variables was divided into various sub-models with fewer variables by variance analysis.In the third step,the optimization sub-models were solved one by one using a genetic algorithm,and the modified characteristic curve method was adopted as the failure prediction method.Based on the proposed optimization method,optimization of a double-lap single-bolt joint was performed using the ANSYS®code.The results show that the bearing failure load increased by 13.5%and that the mass decreased by 8.7%compared with those of the initial design of the joint,which validated the effectiveness of the three-step optimization strategy.

Nonlinear dynamic analysis of a photonic crystal nanocavity resonator

A nonlinear dynamic model of a one-dimensional photonic crystal nanocavity resonator is presented. It considers the internal tensile stress and the geometric characteristics of a photonic crystal with rectangular(and circular) holes. The solution of the dynamic model shows that the internal tensile stress can suppress the hardening and softening behaviors of the resonator. However, the stress can reduce the amplitude, which is not conducive to an improvement of the sensitivity of the sensor. It is demonstrated that with an optimized beam length, the normalized frequency drift of the beam can be stabilized within 1% when the optical power increases from 2 mW to 6 mW. When the hole size of the resonator beam is close to the beam width, its increase can lead to a sharp rise of the resonant frequency and the promotion of hardening behavior. Moreover,the increase in the optical power initially leads to the softening behavior of the resonator followed by an intensification of the hardening behavior. These theoretical and numerical results are helpful in understanding the intrinsic mechanism of the nonlinear response of an optomechanical resonator, with the objective of avoiding the nonlinear phenomena by optimizing key parameters.

Model of CEL for 3D Elements in PDMs of Unidirectional Composite Structures

Progressive damage models(PDMs)have been increasingly used to simulate the failure process of composite material structures.To accurately simulate the damage in each ply,3D PDMs of composite materials have received more attention recently.A characteristic element length(CEL),which is an important dimensional parameter of PDMs for composite materials,is quite difficult to obtain for 3D elements,especially considering the crack directions during damage propagation.In this paper,CEL models for 3D elements in PDMs of unidirectional composite structures are presented,and their approximate formulae are deduced.The damage in unidirectional composite materials can be divided into fiber cracks and inter-fiber cracks.The fiber crack and inter-fiber crack directions are considered in the CEL derivations,and thus,the CELs of 3D elements that have various damage modes and damage directions could be obtained relatively precisely.Static tensile and compressive tests of open-hole laminates were conducted,and the corresponding numerical analyses by the progressive damage method,including the proposed CEL models and those models from the literature,were performed.The numerical results are in good agreement with the experimental results,which proves the fidelity and effectiveness of the proposed CEL models.In addition,the proposed CEL models have better performance in improving the mesh independence of the numerical models.

A Ply-By-Ply Discretized 2D FEA Approach with the Integrated XFEM-CE Strategy for Predicting Multiple Failures in Laminated Composite Structures

Delamination and matrix cracking are two common failure mechanisms in composite structures,and are usually coupled with each other,leading to multiple failures pattern.This paper proposed a fast damage prediction methodology for composite laminated structures based on the ply-by-ply 2D(two dimensional)FE model of composite laminates in the transverse plane.The layer-wise 2D FE model was firstly used in conjunction with the integrated XFEM/CE strategy,which simulated the interface delamination with cohesive elements and the intra-ply matrix crack with XFEM(extended finite element method).To realize ply-by-ply 2D FE(finite element)modeling of composite laminates,two 2D material models were developed based on the plane stress assumption and plane strain assumption,respectively.A general crack propagation scheme was developed in the framework of the integrated XFEM-CE method.Adopting the 2D material model based on the plane strain assumption,a ply-by-ply discretized 2D FEA procedure was conducted for an out-of-plane composite Pi joint under the static tensile load.The predicted load-displacement response and damage evolution process showed good agreement with the experimental results,which verified the proposed approach.

Formulation Mechanism of Mailuo Shutong Pills in the Treatment of Varicocele

Varicocele is a common disease in male urology clinic,mainly manifested as testicular pendent distension discomfort,scrotal moisture,less weak semen and other symptoms.There is no specific drug in clinical treatment of modern medicine and traditional Chinese medicine.Mailuo Shutong Pills was created by TANG Zuxuan,a Chinese medical master,for the treatment of damp and heat stasis type thrombotic superficial phlebitis and other vascular diseases.In clinical application,it was found to have a good clinical effect on the treatment of symptoms caused by varicose vein.This paper analyzed the formulation mechanism of Mailuo Shutong Pills in the treatment of varicocele from the perspective of traditional Chinese and western medicine,and provides theoretical basis for clinical application.

A characteristic curve-based numerical framework for predicting strength of multi-bolted composite joints subjected to hygrothermal condition

Many works have been made for predicting the failure of composite joints.However,there is still lack of method for multi-bolted composite joints subjected to the hygrothermal environment.In this work,a characteristic curve-based numerical framework is proposed,which includes two main steps and shows low computational cost.Firstly,a 3D finite element model considering hygrothermal effects is established to analyze the bolt-load distribution of multi-bolted joints.Secondly,a new characteristic curve considering the hygrothermal influence is used to obtain the failure pattern and strength of composite joints.The two-,three-and four-bolted composite joints with-55℃/dry(CTD),23℃/dry(RTD)and 70℃/wet(ETW)conditions are investigated.The test outcomes present good agreement with predicted results,which illustrates the effectiveness and applicability of the proposed method.Meanwhile,it is shown that the environmental condition affects the bolt-load ratio slightly,but does not change the location of the key loaded hole.Furthermore,deviations of the strengths in CTD and ETW conditions are about 5%and-16%from that in the RTD condition,respectively.The environmental condition does not affect the failure modes of two-and three-bolted joints,whereas changes the failure mode of the four-bolted joint.The proposed method is efficient,reliable and needs only linear elastic FE analysis,making it applicable for engineering practice.

Uncertainty evaluation for bearing fatigue property of CFRP double-lap,single-bolt joints

The considerable uncertainty in mechanical properties of composite bolted joints not only prevents advanced composite materials from efficient applications,but also threatens the safety and reliability of the aircraft structures.In this paper,the uncertainty in bearing fatigue properties of a CFRP double-lap,single-bolt joint was evaluated by combing a Progressive Fatigue Damage Model(PFDM)with the interval analysis method.In the PFDM,a residualstrain-based gradual material degradation model and a strain-based fatigue failure criterion were combined with a micromechanics-based sudden material degradation model to predict fatigue properties of the joint.Based on the interval analysis,the key uncertain parameters,which were firstly picked out from eighteen structural parameters of the joint,were described by estimated intervals,and the envelope cases were determined to estimate the lower and upper bounds of fatigue properties of the joint.The predicted results have the same tendency with the experimental results in literatures,which indicates that the PFDM combined with the interval analysis shows potential in efficiently evaluating the fatigue reliability of the complex bolted joints with an adequate accuracy.

Nonlinear characterization and performance optimization for broadband bistable energy harvester

As two crucial indicators of bistable energy harvesting performance,band width and power amplitude are simultaneously investigated for obtaining the synergy effect.Toward this goal,a nonlinear electromechanical-coupled distributed-parameter model of the bistable piezoelectric energy harvester is established.Based on the electromechanical decoupled method,approximate higher-order analytical solutions of the beam displacement,harvested power and effective bandwidth are derived.The cubic-function discriminant of the analytical solution is introduced to determine the nonlinear excitation-frequency boundaries of multiple solutions and power peak.The stability of the multiple solutions is analyzed through Jacobi matrix of the modulation equation.Superharmonic resonance is notified.Upward and downward sweep experiments and numerical solutions of time history curves,phase portraits and power spectra confirm the analytical findings.To realize optimized broadband energy harvesting,the parametric study on the coefficients of the linear and cubic elastic external forces with the corresponding optimal load resistance is performed.For the nonlinear hardening case,more positive linear coefficient is preferred.For the nonlinear softening case,the cubic coefficient slightly larger than its optimal value is recommended at each given linear coefficient.By tuning the load resistance and linear and cubic coefficients of the external force,broadband bistable energy harvesting with optimized power is realized.