With the current trend of increasing efforts to develop non-isocyanate-based polyurethanes(NIPUs),this study aimed to check the feasibility of the development of a method using cyclic carbonate modified catechin and a...With the current trend of increasing efforts to develop non-isocyanate-based polyurethanes(NIPUs),this study aimed to check the feasibility of the development of a method using cyclic carbonate modified catechin and amine to synthesis non-isocyanate urethane with the objective to further extend these results to polyurethane synthesis.The methods used in this study consist of four steps:glycidilation of catechin,hydrolysis of epoxide,cyclic carbonate synthesis,and carbamate synthesis through condensation of butylamine.The resulting products were analyzed using FTIR(Fourier transform infrared)spectroscopy and NMR(nuclear magnetic resonance)spectroscopy.The results showed that carbamate could be successfully obtained through this four-steps synthesis,opening the possibility to further developments for the synthesis of polyurethanes starting from catechin and condensed tannins.展开更多
基金LERMAB is supported by a grant overseen by the French National Research Agency(ANR)as part of the“Investissements d’Avenir”Program(ANR-11-LABX-0002-01.Lab of Excellence ARBRE)by the“Impact Biomolecules”Project of the“Lorraine Universitéd’Excellence”“Investissements d’avenir–ANR 15-004”by the French Ministry of Agriculture and the Lorraine-FEDER for the support of“EXTRAFOREST”Project.
文摘With the current trend of increasing efforts to develop non-isocyanate-based polyurethanes(NIPUs),this study aimed to check the feasibility of the development of a method using cyclic carbonate modified catechin and amine to synthesis non-isocyanate urethane with the objective to further extend these results to polyurethane synthesis.The methods used in this study consist of four steps:glycidilation of catechin,hydrolysis of epoxide,cyclic carbonate synthesis,and carbamate synthesis through condensation of butylamine.The resulting products were analyzed using FTIR(Fourier transform infrared)spectroscopy and NMR(nuclear magnetic resonance)spectroscopy.The results showed that carbamate could be successfully obtained through this four-steps synthesis,opening the possibility to further developments for the synthesis of polyurethanes starting from catechin and condensed tannins.
