Hybrid materials constructed from a visible-light-absorbing semiconductor and a functional metal complex have attracted attention as efficient photocatalysts for CO_(2) reduction with high selectivity to a desired pro...Hybrid materials constructed from a visible-light-absorbing semiconductor and a functional metal complex have attracted attention as efficient photocatalysts for CO_(2) reduction with high selectivity to a desired product.In this work,defect fluorite-type Ln-Ta oxynitrides LnTaO_(x)N_(y)(Ln=Nd,Sm,Gd,Tb,Dy and Ho)were examined as the semiconductor component in a hybrid photocatalyst system combined with known Ag nanoparticle promoter and binuclear ruthenium(Ⅱ)complex(RuRu’).Among the LnTaO_(x)N_(y) examined,TbTaO_(x)N_(y) gave the highest performance for CO_(2) reduction under visible light(k>400 nm),with a Ru Ru0-based turnover number of 18 and high selectivity to formate(>99%).Physicochemical analyses indicated that high crystallinity and more negative conduction band potential of Ln Ta O_(x)N_(y)with the absence of Ln-4 f states in the band gap structure contributed to higher activity of the hybrid photocatalyst.展开更多
Eu2＋-doped oxyapatite SrxLalo-x （SiO4）6O3-x/2 phosphors are prepared by sofid-state reaction at high temper- atures under reducing atmosphere. Their crystal structures and photoluminescenee are investigated by x-ra...Eu2＋-doped oxyapatite SrxLalo-x （SiO4）6O3-x/2 phosphors are prepared by sofid-state reaction at high temper- atures under reducing atmosphere. Their crystal structures and photoluminescenee are investigated by x-ray diffraction （XRD） and fluorescence spectroscopy, respectively. The XlZtD results indicate that the samples are pure oxyapatite phase （P63/m space group）. The fluorescence spectra show two peaks corresponding to two sites （4f and 6h sites） for Eu2＋ in the host lattice. As the Eu2＋ content influences the intensity ratio of the two observed emission peaks, the photoluminescence mechanism is discussed.展开更多
基金supported by a Grant-in-Aid for Scientific Research on Innovative Area “Mixed Anion(Projects JP16K21724 and JP16H06441)”from the Japan Society for the Promotion of Science(JSPS)a CREST program(Project JPMJCR13L1)from the Japan Science and Technology Agency(JST)a JSPS Fellowship for Young Scientists(Project JP17J06914)。
文摘Hybrid materials constructed from a visible-light-absorbing semiconductor and a functional metal complex have attracted attention as efficient photocatalysts for CO_(2) reduction with high selectivity to a desired product.In this work,defect fluorite-type Ln-Ta oxynitrides LnTaO_(x)N_(y)(Ln=Nd,Sm,Gd,Tb,Dy and Ho)were examined as the semiconductor component in a hybrid photocatalyst system combined with known Ag nanoparticle promoter and binuclear ruthenium(Ⅱ)complex(RuRu’).Among the LnTaO_(x)N_(y) examined,TbTaO_(x)N_(y) gave the highest performance for CO_(2) reduction under visible light(k>400 nm),with a Ru Ru0-based turnover number of 18 and high selectivity to formate(>99%).Physicochemical analyses indicated that high crystallinity and more negative conduction band potential of Ln Ta O_(x)N_(y)with the absence of Ln-4 f states in the band gap structure contributed to higher activity of the hybrid photocatalyst.
文摘Eu2＋-doped oxyapatite SrxLalo-x （SiO4）6O3-x/2 phosphors are prepared by sofid-state reaction at high temper- atures under reducing atmosphere. Their crystal structures and photoluminescenee are investigated by x-ray diffraction （XRD） and fluorescence spectroscopy, respectively. The XlZtD results indicate that the samples are pure oxyapatite phase （P63/m space group）. The fluorescence spectra show two peaks corresponding to two sites （4f and 6h sites） for Eu2＋ in the host lattice. As the Eu2＋ content influences the intensity ratio of the two observed emission peaks, the photoluminescence mechanism is discussed.
